ChemicalBook > CAS DataBase List > Phenylphosphinic acid

Phenylphosphinic acid

Product Name
Phenylphosphinic acid
CAS No.
1779-48-2
Chemical Name
Phenylphosphinic acid
Synonyms
NSC2670;phosphenous acid;phenylphospho acid;phenyl-phosphinicaci;Coproporphyrin I-15N4;PHENYLPHOSPHINIC ACID;Benzolphosphonigsαure;PHENYLPHOSPHONOUS ACID;Phosphinicacid,phenyl-;BENZENEPHOSPHINIC ACID
CBNumber
CB6430092
Molecular Formula
C6H7O2P
Formula Weight
142.09
MOL File
1779-48-2.mol
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Phenylphosphinic acid Property

Melting point:
83-85 °C(lit.)
Boiling point:
180 °C
Density 
1.376
storage temp. 
Sealed in dry,Room Temperature
solubility 
DMSO (Slightly), Water (Slightly, Heated)
pka
pK1:2.1 (17°C)
form 
Crystalline Solid
color 
White
Water Solubility 
7.7 g/100 mL (25 ºC)
BRN 
2802244
InChI
InChI=1S/C6H7O2P/c7-9(8)6-4-2-1-3-5-6/h1-5,9H,(H,7,8)
InChIKey
MLCHBQKMVKNBOV-UHFFFAOYSA-N
SMILES
P(C1=CC=CC=C1)(O)=O
CAS DataBase Reference
1779-48-2(CAS DataBase Reference)
NIST Chemistry Reference
Phosphinic acid, phenyl-(1779-48-2)
EPA Substance Registry System
Phosphinic acid, phenyl- (1779-48-2)
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Safety

Hazard Codes 
C,Xn
Risk Statements 
22-34-41-37/38
Safety Statements 
26-36/37/39-45
RIDADR 
UN 3261 8/PG 3
WGK Germany 
3
RTECS 
SZ5462500
TSCA 
Yes
HazardClass 
8
PackingGroup 
III
HS Code 
29309099
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H302Harmful if swallowed

H314Causes severe skin burns and eye damage

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P270Do not eat, drink or smoke when using this product.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
P28808
Product name
Phenylphosphinic acid
Purity
99%
Packaging
100g
Price
$29.34
Updated
2024/03/01
Sigma-Aldrich
Product number
P28808
Product name
Phenylphosphinic acid
Purity
99%
Packaging
500g
Price
$55.2
Updated
2024/03/01
TCI Chemical
Product number
B0025
Product name
Phenylphosphinic Acid
Purity
>99.0%(T)
Packaging
25g
Price
$19
Updated
2024/03/01
TCI Chemical
Product number
B0025
Product name
Phenylphosphinic Acid
Purity
>99.0%(T)
Packaging
500g
Price
$133
Updated
2024/03/01
Alfa Aesar
Product number
A17453
Product name
Phenylphosphinic acid, 98%
Packaging
500g
Price
$107.65
Updated
2024/03/01
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Phenylphosphinic acid Chemical Properties,Usage,Production

Chemical Properties

white crystals or crystalline powder

Uses

Antioxidant, intermediate for metallic-salt formation, accelerator for organic peroxide catalysts.

Uses

Coproporphyrin I-15N4 is an intermediate in the synthesis of Coproporphyrin I-15N4 Sodium BIsulfate Salt (C685402). Labelled Coproporphyrin I. Coproporphyrin I is a porphyrin, a naturally occuring aromatic heterocyclic marcomolecule. The ratio of Coproporphyrin I and Coproporphyrin III provides a useful biochemical marker for distinguishing familial and sporadic porphyria cutanea tarda. Coproporphyrin I also serve as a biomarker of environmental toxicity and susceptibility in autism.

General Description

Phenylphosphinic acid is also known as phenylphosphonous acid. Kinetics of oxidation of phenylphosphinic acid by metal and non metal oxidants was investigated in a study.2

Purification Methods

Crystallise it from H2O (solubility is 7.7% at 25o). Also purify it by placing the solid in a flask covered with dry Et2O, and allowed it to stand for 1day with intermittent shaking. Et2O is decanted off and the process repeated. After filtration, excess Et2O is removed in a vacuum. It has also been recrystallised from *C6H6. [Michaelis Justus Liebigs Ann Chem 181 265 1876, Banks & Skoog Anal Chem 29 109 1957, NMR: Van Wazer et al. J Am Chem Soc 78 5715 1956, Beilstein 16 IV 1033.]

Phenylphosphinic acid Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Phenylphosphinic acid manufacturers

Hebei Zhuanglai Chemical Trading Co.,Ltd
Product
Phenylphosphinic acid 1779-48-2
Price
US $55.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
5000kg/week
Release date
2024-06-03
Shanghai Xin Cheng Yue Chemical Co.,Ltd
Product
Phenylphosphinic acid 1779-48-2
Price
US $0.00-0.00/kg
Min. Order
1000kg
Purity
99.8%
Supply Ability
100000ton
Release date
2024-01-26
airuikechemical co., ltd.
Product
Phenylphosphinic acid 1779-48-2
Price
US $0.00-0.00/Kg
Min. Order
1Kg
Purity
99.9%
Supply Ability
200tons
Release date
2024-04-08

1779-48-2, Phenylphosphinic acidRelated Search:


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