2,6-Dichlorophenol
- Product Name
- 2,6-Dichlorophenol
- CAS No.
- 87-65-0
- Chemical Name
- 2,6-Dichlorophenol
- Synonyms
- 2,6-DCP;JACS-87-65-0;2.6-Dichloroph;6-Dichlorophenol;2,6-Dichlorfenol;2,6-Dichlorofenol;2,6-Dichlorphenol;dichloro-2,6phenol;2,6-dichloro-pheno;2,6-DICHLOROPHENOL
- CBNumber
- CB6450775
- Molecular Formula
- C6H4Cl2O
- Formula Weight
- 163
- MOL File
- 87-65-0.mol
2,6-Dichlorophenol Property
- Melting point:
- 64-66 °C (lit.)
- Boiling point:
- 218-220 °C (lit.)
- Density
- 1.6530
- refractive index
- 1.4430 (estimate)
- Flash point:
- 218-220°C
- storage temp.
- 2-8°C
- solubility
- 1.9g/l
- form
- Crystals or Crystalline Powder
- pka
- pK1:6.78 (25°C)
- color
- White to yellow
- Water Solubility
- <0.1 g/100 mL at 20 ºC
- Merck
- 14,3073
- BRN
- 1447806
- Stability:
- Stable. Combustible. Incompatible with strong oxidizing agents, acid chlorides, acid anhydrides.
- CAS DataBase Reference
- 87-65-0(CAS DataBase Reference)
- NIST Chemistry Reference
- Phenol, 2,6-dichloro-(87-65-0)
- EPA Substance Registry System
- 2,6-Dichlorophenol (87-65-0)
Safety
- Hazard Codes
- C,Xi,T,F
- Risk Statements
- 34-36/38-39/23/24/25-23/24/25-11
- Safety Statements
- 26-27-36/37/39-37/39-45-36/37-16-7
- RIDADR
- UN 2020 6.1/PG 3
- WGK Germany
- 2
- RTECS
- SK8750000
- Hazard Note
- Harmful/Corrosive
- TSCA
- Yes
- HazardClass
- 6.1
- PackingGroup
- III
- HS Code
- 29081990
- Hazardous Substances Data
- 87-65-0(Hazardous Substances Data)
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H314Causes severe skin burns and eye damage
- Precautionary statements
-
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P363Wash contaminated clothing before reuse.
N-Bromosuccinimide Price
- Product number
- D70201
- Product name
- 2,6-Dichlorophenol
- Purity
- 99%
- Packaging
- 25g
- Price
- $40.6
- Updated
- 2024/03/01
- Product number
- D70201
- Product name
- 2,6-Dichlorophenol
- Purity
- 99%
- Packaging
- 100g
- Price
- $95.5
- Updated
- 2024/03/01
- Product number
- 40302
- Product name
- 2,6-Dichlorophenol solution
- Purity
- certified reference material, 5000?μg/mL in methanol
- Packaging
- 1mL
- Price
- $62.3
- Updated
- 2024/03/01
- Product number
- 31102
- Product name
- 2,6-Dichlorophenol
- Purity
- PESTANAL?, analytical standard
- Packaging
- 100MG
- Price
- $29.9
- Updated
- 2024/03/01
- Product number
- D0394
- Product name
- 2,6-Dichlorophenol
- Purity
- >99.0%(GC)
- Packaging
- 25g
- Price
- $59
- Updated
- 2024/03/01
2,6-Dichlorophenol Chemical Properties,Usage,Production
Description
2,6-Dichlorophenol is a white crystalline solidhaving a strong odor similar to o-chlorophenol; Molecularweight=163.00; Boiling point=219.5℃; Freezing/Melting point=68-69℃. Hazard Identification (based onNFPA-704 M Rating System): Health 3, Flammability 0,Reactivity 0.
Chemical Properties
2,6-Dichlorophenol is a white crystalline solid having a strong odor similar to o-chlorophenol. Freely soluble in ethanol and ether, soluble in benzene and petroleum ether.
Uses
It is used primarily as a starting material for the manufacture of trichlorophenols, tetrachlorophenols, and pentachlorophenols. It also acts as a sex pheromone for the Lone Star tick.
Preparation
2,6-Dichlorophenol has been prepared by the chlorination of phenol with chlorine gas in the presence of nitrobenzene and fuming sulfuric acid, by the decomposition of the diazotate of 2,6-dichloro-4-aminophenol, and by the decarboxylation of 3,5-dichloro-4-hydroxybenzoic acid in quinoline or dimethylaniline.
Definition
ChEBI: 2,6-dichlorophenol is a dichlorophenol with the chloro substituents at positions 2 and 6. It is used as a chemical intermediate for 2,4,6-trichlorophenol and in the production of dehydro-l-ascorbic acid.
Synthesis Reference(s)
Journal of the American Chemical Society, 73, p. 2723, 1951 DOI: 10.1021/ja01150a084
Organic Syntheses, Coll. Vol. 3, p. 267, 1955
General Description
2,6-dichlorophenol is a white crystalline solid with a strong odor. Odor threshold concentration: 0.003 mg/L at 86°F; 200 micrograms/liter at 68-72°F. Taste threshold concentration: 0.0002 mg/L. (NTP, 1992)
Air & Water Reactions
Insoluble in water.
Reactivity Profile
2,6-Dichlorophenol is incompatible with acid chlorides, acid anhydrides and oxidizing agents .
Fire Hazard
Flash point data for 2,6-Dichlorophenol are not available; however, 2,6-Dichlorophenol is probably combustible.
Safety Profile
Poison by intraperitoneal route. Moderately toxic by ingestion. A severe skin and eye irritant. When heated to decomposition it emits toxic fumes of Cl-. See also CHLOROPHENOLS.
Potential Exposure
2,6-Dichlorophenol is produced as aby-product from the direct chlorination of phenol. It is usedprimarily as a starting material for the manufacture of trichlorophenols, tetrachlorophenols, and pentachlorophenols.It also acts as a sex pheromone for lone star tick.
First aid
If this chemical gets into the eyes, remove anycontact lenses at once and irrigate immediately for at least15 min, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts theskin, remove contaminated clothing and wash immediatelywith soap and water. Seek medical attention immediately. Ifthis chemical has been inhaled, remove from exposure,begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPRif heart action has stopped. Transfer promptly to a medicalfacility. When this chemical has been swallowed, getmedical attention. Give large quantities of water andinduce vomiting. Do not make an unconscious personvomit.
storage
Color Code—Blue: Health Hazard/Poison: Storein a secure poison location. Prior to working with 2,6-DCPyou should be trained on its proper handling and storage.Store in tightly closed containers in a refrigerator awayfrom oxidizers and other incompatible materials listedabove.
Shipping
UN2020 Chlorophenols, solid, Hazard Class: 6.1; Labels: 6.1-Poisonous materials.
Incompatibilities
Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides, acid fumes, acid anhyrides and acid chlorides
Waste Disposal
Dissolve in a combustible solvent and incinerate in a furnace equipped with afterburner and scrubber. In accordance with 40CFR165, follow recommendations for the disposal of pesticides and pesticide containers. Must be disposed properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office. Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≥100 kg/mo) must conform with EPA regulations governing storage, transportation, treatment, and waste disposal
2,6-Dichlorophenol Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 2,6-Dichlorophenol manufacturers
- Product
- 2,6-Dichlorophenol 87-65-0
- Price
- US $1.00/PCS
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 10 mt
- Release date
- 2021-01-27
- Product
- 2,6-Dichlorophenol 87-65-0
- Price
- US $1.20/kg
- Min. Order
- 1kg
- Purity
- 99%HPLC
- Supply Ability
- 20tons
- Release date
- 2023-03-14
- Product
- 2,6-Dichlorophenol 87-65-0
- Price
- US $100.00-1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- g-kg-tons, free sample is available
- Release date
- 2023-12-24