ChemicalBook > CAS DataBase List > METHYL 5-METHOXYSALICYLATE

METHYL 5-METHOXYSALICYLATE

Product Name: METHYL 5-METHOXYSALICYLATE
CAS No.: 2905-82-0
Chemical Name: METHYL 5-METHOXYSALICYLATE
Synonyms: RARECHEM AL BF 0042;METHYL 5-METHOXYSALICYLATE;Methyl5-Methoxysalicylate>Methyl 5-Methoxy Salicylicate;METHYL 2-HYDROXY-5-METHOXY-BENZOATE;5-METHOXYSALICYLIC ACID METHYL ESTER;2-HYDROXY-5-METHOXYBENZOIC ACID METHYL ESTER;Benzoic acid, 2-hydroxy-5-methoxy-, methyl ester;5-Methoxysalicylic Acid Methyl Ester Methyl 2-Hydroxy-5-methoxybenzoate 2-Hydroxy-5-methoxybenzoic Acid Methyl Ester
CBNumber: CB6461876
Molecular Formula: C9H10O4
Formula Weight: 182.17
MOL File: 2905-82-0.mol

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METHYL 5-METHOXYSALICYLATE Property

Boiling point:: 235-240 °C (lit.)
Density: 1.223 g/mL at 25 °C (lit.)
refractive index: n20/D 1.544(lit.)
Flash point:: >230 °F
storage temp.: Storage temp. 2-8°C
pka: 10.24±0.18(Predicted)
form: clear liquid
color: Colorless to Light yellow
λmax: 334nm(CH3CN)(lit.)
CAS DataBase Reference: 2905-82-0(CAS DataBase Reference)

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-36
WGK Germany: 3
HS Code: 2918999090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 456683
Product name: Methyl 5-methoxysalicylate
Purity: 98%
Packaging: 5ml
Price: $89.1
Updated: 2023/01/07

Sigma-Aldrich

Product number: 456683
Product name: Methyl 5-methoxysalicylate
Purity: 98%
Packaging: 25ml
Price: $283
Updated: 2023/01/07

TCI Chemical

Product number: M2127
Product name: Methyl 5-Methoxysalicylate
Purity: >98.0%(GC)
Packaging: 5g
Price: $39
Updated: 2025/07/31

TCI Chemical

Product number: M2127
Product name: Methyl 5-Methoxysalicylate
Purity: >98.0%(GC)
Packaging: 25g
Price: $153
Updated: 2025/07/31

TRC

Product number: M327118
Product name: Methyl2-Hydroxy-5-methoxybenzoate
Packaging: 10mg
Price: $45
Updated: 2021/12/16

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METHYL 5-METHOXYSALICYLATE Chemical Properties,Usage,Production

Synthesis

2612-02-4

74-88-4

2905-82-0

To a solution of N,N-dimethylformamide (80 mL) of 2-hydroxy-5-methoxybenzoic acid (6.0 g, 35.68 mmol) was sequentially added sodium bicarbonate (3.15 g, 37.46 mmol) and iodomethane (2.33 mL, 37.46 mmol). The reaction mixture was stirred at 80 °C for 3 hours. Upon completion of the reaction, ice water was added to the mixture, followed by extraction with ether. The combined organic phases were washed sequentially with water and saturated brine and then dried with anhydrous magnesium sulfate. The solvent was removed by distillation under reduced pressure to give the brown oily product methyl 2-hydroxy-5-methoxybenzoate (5.38 g, 82.8% yield).

References

[1] Patent: US2004/242615, 2004, A1. Location in patent: Page/Page column 13
[2] ChemMedChem, 2016, vol. 11, # 1, p. 108 - 118
[3] Bioorganic and Medicinal Chemistry, 2006, vol. 14, # 2, p. 334 - 343
[4] Organic Letters, 2018, vol. 20, # 5, p. 1316 - 1319

METHYL 5-METHOXYSALICYLATE Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from METHYL 5-METHOXYSALICYLATE manufacturers

Career Henan Chemical Co

Product: METHYL 5-METHOXYSALICYLATE 2905-82-0
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 100KG
Release date: 2019-12-25

2905-82-0, METHYL 5-METHOXYSALICYLATERelated Search:

Methyl 2,5-bis(2,2,2-trifluoroethoxy)benzoate MOLLUGIN CHARTREUSIN Elsamitrucin METHYL 5-METHOXYSALICYLATE methyl 2-hydroxy-6-methoxybenzoic acid Methyl 5-allyl-3-methoxysalicylate METHYL 3-METHOXYSALICYLATE METHYL 4-METHOXYSALICYLATE,Methyl P-Methoxysalicylate Methyl salicylate 5-Methoxysalicylic acid ETHYL 5-ETHOXY-2-HYDROXYBENZOATE 2-HYDROXY-5-METHOXY-BENZOIC ACID ETHYL ESTER STICTIC ACID GANGALEOIDIN METHYL 2,5-DIMETHOXYBENZOATE ETHYL 2 4 5-TRIETHOXYBENZOATE 97 BRYOPOGONIC ACID

METHYL 5-METHOXYSALICYLATE

METHYL 2-HYDROXY-5-METHOXY-BENZOATE

2-HYDROXY-5-METHOXYBENZOIC ACID METHYL ESTER

5-METHOXYSALICYLIC ACID METHYL ESTER

RARECHEM AL BF 0042

5-Methoxysalicylic Acid Methyl Ester Methyl 2-Hydroxy-5-methoxybenzoate 2-Hydroxy-5-methoxybenzoic Acid Methyl Ester

Methyl 5-Methoxy Salicylicate

Methyl5-Methoxysalicylate&gt

Benzoic acid, 2-hydroxy-5-methoxy-, methyl ester

2905-82-0

CH3OC6H3OHCO2CH3

Organic Building Blocks

Esters

C8 to C9

Carbonyl Compounds

Building Blocks

Aromatic Esters

Acids and Derivatives

Alcohols and Derivatives