(DHQ)2PYR

ChemicalBook > CAS DataBase List > (DHQ)2PYR

Product Name: (DHQ)2PYR
CAS No.: 149820-65-5
Chemical Name: (DHQ)2PYR
Synonyms: (DHQ)2PYR;(DHQ)2Pyr 97%;Quinine Impurity 9;Aficamten Impurity 47;2,5-Diphenyl-4,6-bis(dihydroquinine)pyrimidine;2,5-Diphenyl-4,6-bis(9-O-dihydroquinyl)pyrimidine;2,5-Diphenyl-4,6-bis(9-O-dihydroquininyl)pyrimidine;HYDROQUININE 2,5-DIPHENYL-4,6-PYRIMIDINEDIYL DIETHER;Hydroquinine 2,5-diphenyl-4,6-pyrimidinediyl Diether,99%e.e.;(DHQ)2-PYR/2,5-diphenyl-4,6-bis(9-O-dihydroquinyl)pyrimidine
CBNumber: CB6465692
Molecular Formula: C56H60N6O4
Formula Weight: 881.11
MOL File: 149820-65-5.mol

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(DHQ)2PYR Property

Melting point:: 245-248 °C(lit.)
Density: 1.29±0.1 g/cm3(Predicted)
storage temp.: Sealed in dry,Room Temperature
pka: 9.50±0.70(Predicted)
optical activity: [α]20/D +455°, c = 1.2 in methanol
InChIKey: SWKRDCRSJPRVNF-CVCJRGCISA-N

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-36
WGK Germany: 3

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 418978
Product name: (DHQ)2Pyr
Purity: 97%
Packaging: 1g
Price: $153.6
Updated: 2024/03/01

Biosynth Carbosynth

Product number: FD162040
Product name: 2,5-Diphenyl-4,6-bis(dihydroquinine)pyrimidine
Packaging: 500mg
Price: $160
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FD162040
Product name: 2,5-Diphenyl-4,6-bis(dihydroquinine)pyrimidine
Packaging: 100mg
Price: $60
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FD162040
Product name: 2,5-Diphenyl-4,6-bis(dihydroquinine)pyrimidine
Packaging: 1g
Price: $250
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FD162040
Product name: 2,5-Diphenyl-4,6-bis(dihydroquinine)pyrimidine
Packaging: 2g
Price: $380
Updated: 2021/12/16

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(DHQ)2PYR Chemical Properties,Usage,Production

Uses

(DHQ)2Pyr is a bis-Cinchona alkaloid ligand used in enantioselective synthesis applications. Cinchona alkaloids catalyze many useful processes with high enantioselectivities. Cinchona alkaloids can be used as bases to deprotonate substrates with relatively acidic protons forming a contact ion pair between the resulting anion and protonated amine. This interaction leads to a chiral environment around the anion and permits enantioselective reactions with electrophiles. Amination with diimides at the remote γ-position can be carried out using (DHQ)2Pyr to form a diverse range of highly functionalized amine compounds.

(DHQ)2PYR Preparation Products And Raw materials

Raw materials

HYDROQUININE Ethanol Toluene Sodium Phosphorus oxychloride Benzeneacetonitrile Diethyl ether Acetic acid Cyclohexylamine N,N-Dimethylbenzamide Diethyl carbonate

Preparation Products

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View Lastest Price from (DHQ)2PYR manufacturers

Zhuozhou Wenxi import and Export Co., Ltd

Product: (DHQ)2Pyr 97% 149820-65-5
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-06-27

Career Henan Chemical Co

Product: (DHQ)2PYR 149820-65-5
Price: US $3.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 100KG
Release date: 2020-01-29

149820-65-5, (DHQ)2PYRRelated Search:

(DHQ)2PHAL HYDROQUINIDINE (ANTHRAQUINONE-1,4-DIYL) DIETHER (DHQD)2PHAL HYDROQUININE 4(1H)-Pyrimidinone, 6-hydroxy-5-methyl- (8CI,9CI) 4,6-Dimethoxy-2-methylpyrimidine 5-PHENYL-PYRIMIDINE 4,6-Dihydroxy-2-methylpyrimidine 4,6-Dimethoxypyrimidine 4-(3-METHOXYPROPYL)PIPERIDINE (DHQ)2PYR 4-Pyrimidinol, 2,5-dimethyl- (7CI,9CI) 4-METHOXY-2-PHENYLPYRIMIDINE Pyrimidine, 4-methoxy-2-methyl- (6CI,7CI,8CI,9CI) 4-HEPTYLPYRIDINE 4,6-Dihydroxy-2-phenylpyrimidine 2,5-DIPHENYL-4,6-PYRIMIDINEDIOL (2S,4S,5R)-2-HYDROXYMETHYL-5-ETHYLQUINUCLIDINE

(DHQ)2PYR

HYDROQUININE 2,5-DIPHENYL-4,6-PYRIMIDINEDIYL DIETHER

2,5-Diphenyl-4,6-bis(9-O-dihydroquininyl)pyrimidine

2,5-Diphenyl-4,6-bis(9-O-dihydroquinyl)pyrimidine

2,5-Diphenyl-4,6-bis(dihydroquinine)pyrimidine

(DHQ)2Pyr,Hydroquinine 2,5-diphenyl-4,6-pyrimidinediyl diether

(DHQ)2Pyr 97%

(DHQ)2-PYR/2,5-diphenyl-4,6-bis(9-O-dihydroquinyl)pyrimidine

Hydroquinine 2,5-diphenyl-4,6-pyrimidinediyl Diether,99%e.e.

5-ethyl-1-azabicyclo[2.2.2]octan-2-yl](6-methoxyquinolin-4-yl)methoxy]-2,5-diphenylpyrimidin-4-yl}oxy)methyl]-6-methoxyquinoline

4-[(R)-[(4R)-5-ethyl-1-azabicyclo[2.2.2]octan-2-yl]-[6-[(R)-[(5R)-5-ethyl-1-azabicyclo[2.2.2]octan-2-yl]-(6-methoxyquinolin-4-yl)methoxy]-2,5-diphenylpyrimidin-4-yl]oxymethyl]-6-methoxyquinoline

(1S,1’S,3R,3’R,4S,4’S,6S,6’S)-6,6’-[(1R,1’R)-[(2,5-Diphenylpyrimidine-4,6-diyl)bis(oxy)]bis[(6-methoxy-4-quinolyl)methylene]]bis(3-ethylquinuclidine)

Cinchonan, 9,9''-[(2,5-diphenyl-4,6-pyrimidinediyl)bis(oxy)]bis[10,11-dihydro-6'-methoxy-, (8α,9R)-(8''α,9''R)-

Quinine Impurity 9

Aficamten Impurity 47

149820-65-5

C56H60N6O4

Asymmetric Synthesis

Chiral Catalysts, Ligands, and Reagents

Dihydroxylation