ChemicalBook > CAS DataBase List > (DHQD)2PHAL

(DHQD)2PHAL

Product Name
(DHQD)2PHAL
CAS No.
140853-10-7
Chemical Name
(DHQD)2PHAL
Synonyms
(DHQD)PHAL;1,4-bis(9-O-dihydroquinidinyl)phthalazine;Hydroquinidine 1,4-phthalazinediyl ether;HYDROQUINIDINE 1,4-PHTHALAZINEDIYL DIETHER;1,4-Bis((S)-((1S,2R,4S,5R)-5-ethylquinuclidin-2-yl)(6-methoxyquinolin-4-yl)methoxy)phthalazine;1,4-bis[(S)-[(2R,4S,5R)-5-ethyl-1-azabicyclo[2.2.2]octan-2-yl]-(6-methoxyquinolin-4-yl)methoxy]phthalazine;(DHQD)2PHAL;DHQD)2 PHAL;DHQD)2PHAL (DH;(S,S)-(DHQ)2PHAL
CBNumber
CB0672988
Molecular Formula
C48H54N6O4
Formula Weight
778.98
MOL File
140853-10-7.mol
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(DHQD)2PHAL Property

Melting point:
160 °C (dec.)(lit.)
alpha 
-262 º (C=1.2 IN MEOH)
Density 
1.3
storage temp. 
Inert atmosphere,Room Temperature
solubility 
Chloroform (Slightly), DMSO (Slightly), Methanol (Sparingly)
pka
9.61±0.70(Predicted)
form 
Solid
color 
White to Pale Yellow
optical activity
[α]22/D 262°, c = 1.2 in methanol
BRN 
5475678
InChIKey
YUCBLVFHJWOYDN-SOBQURILSA-N
CAS DataBase Reference
140853-10-7(CAS DataBase Reference)
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Safety

Safety Statements 
22-24/25
WGK Germany 
3
9
HS Code 
29392000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H303May be harmfulif swallowed

H313May be harmful in contact with skin

H320Causes eye irritation

H333May be harmful if inhaled

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
392731
Product name
(DHQD)2PHAL
Purity
≥95%
Packaging
1g
Price
$178
Updated
2025/07/31
TCI Chemical
Product number
H1114
Product name
Hydroquinidine 1,4-Phthalazinediyl Diether
Packaging
1G
Price
$168
Updated
2025/07/31
TRC
Product number
D299905
Product name
(DHQD)2PHAL
Packaging
5g
Price
$375
Updated
2021/12/16
Biosynth Carbosynth
Product number
FD40586
Product name
(DHQD)2PHAL
Packaging
10g
Price
$460
Updated
2021/12/16
ChemScene
Product number
CS-W008033
Product name
(DHQD)2PHAL
Purity
99.59%
Packaging
25g
Price
$564
Updated
2021/12/16
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(DHQD)2PHAL Chemical Properties,Usage,Production

Uses

(DHQD)2PHAL is a monomeric cinchona alkaloid dimer used as a catalyst for asymmetric halogenations.

Uses

(DHQD)2PHAL may be used as ligand for:

  • Osmium trioxide catalyzed asymmetric dihydroxylation of olefins.
  • Palladium catalyzed Suzuki-Miyaura coupling of aryl/heteroaryl halides with aryl boronic acids in aqueous medium and in the absence of phosphine/organic solvent.
  • Copper(I)-catalyzed azide-alkyne cycloaddition reaction to synthesize 1,2,3-triazoles in water.

General Description

(DHQD)2PHAL is a modified cinchona alkaloid derivative mainly used as a ligand for enantioselective catalysis.

(DHQD)2PHAL Preparation Products And Raw materials

Raw materials

Preparation Products

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(DHQD)2PHAL Suppliers

Shanghai Goyic Pharmaceutical & Chemical Co., Ltd.
Tel
021-50689757 15618953996
Fax
021-60275964
Email
sales@goyic.com
Country
China
ProdList
310
Advantage
58
Aikon International Limited
Tel
025-58859352 18068836627
Fax
02557626880
Email
sales01@aikonchem.com
Country
China
ProdList
16027
Advantage
58
Unibest Pharmaceutical Technology Co., Ltd.
Tel
13735578103
Email
jzyz@unibestpharma.com
Country
China
ProdList
122
Advantage
58
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
4006356688 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44801
Advantage
61
Beijing Ouhe Technology Co., Ltd
Tel
010-010-82967028 13522913783
Fax
+86-10-82967029
Email
2355560935@qq.com
Country
China
ProdList
12000
Advantage
60
Jia Xing Isenchem Co.,Ltd
Tel
0573-85285100 18627885956
Fax
0573-85285100
Email
isenchem@163.com
Country
China
ProdList
9310
Advantage
66
Pure Chemistry Scientific Inc.
Tel
001-857-928-2050 or 1-888-588-9418
Fax
001-617-206-9595
Email
sales@chemreagents.com
Country
United States
ProdList
10186
Advantage
62
Accela ChemBio Co.,Ltd.
Tel
021-50795510 4000665055
Fax
021-50795055
Email
sales@accelachem.com
Country
China
ProdList
11035
Advantage
64
Nanjing Chemlin Chemical Co., Ltd
Tel
025-83697070
Fax
+86-25-83453306
Email
info@chemlin.com.cn
Country
China
ProdList
15883
Advantage
64
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View Lastest Price from (DHQD)2PHAL manufacturers

Zhuozhou Wenxi import and Export Co., Ltd
Product
(DHQD)2PHAL 140853-10-7
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-08-11
Zhuozhou Wenxi import and Export Co., Ltd
Product
(DHQD)2-PHAL 140853-10-7
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-10
Zhuozhou Wenxi import and Export Co., Ltd
Product
(DHQD)2-PHAL 140853-10-7
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-09

140853-10-7, (DHQD)2PHALRelated Search:


  • SHARPLESS CATALYST
  • (DHQD)2PHAL
  • HYDROQUINIDINE 1,4-PHTHALAZINEDIYL DIETHER
  • DHQD)2 PHAL
  • (DHQD)2 PHAL, 95+%
  • HYDROQUININE-1,4-PHTHALOZINEDIYL DIETHER
  • Hydroquinidine 1,4-phthalazinediyl diether((DHQD)2PHAL)
  • (DHQD)2PHAL,Hydroquinidine 1,4-phthalazinediyl diether
  • Hydroquinidine 1,4-phthalazinediyl ether
  • DHQD)2PHAL (DH
  • 1,4-bis[(S)-[(2R,4S,5R)-5-ethyl-1-azabicyclo[2.2.2]octan-2-yl]-(6-methoxyquinolin-4-yl)methoxy]phthalazine
  • 1,4-bis(9-O-dihydroquinidinyl)phthalazine
  • (DHQD)2PHAL,99%e.e.
  • (DHQD)PHAL
  • 1,4-Bis(dihydroquinidine)phthalazine
  • Hydroquinidine 1,4-phthalazinediyl diether, 98%, for synthesis
  • Cinchonan, 9,9''-[1,4-phthalazinediylbis(oxy)]bis[10,11-dihydro-6'-methoxy-, (9S)-(9''S)-
  • 1,4-Bis((S)-((1S,2R,4S,5R)-5-ethylquinuclidin-2-yl)(6-methoxyquinolin-4-yl)methoxy)phthalazine
  • (S,S)-(DHQ)2PHAL
  • (DHQD)<sub>2</sub>PHAL
  • 140853-10-7
  • 40853-10-7
  • C48H54N6O4
  • Chiral Catalysts, Ligands, and Reagents
  • Asymmetric Synthesis
  • Dihydroxylation
  • Cinchona Alkaloids
  • Privileged Ligands