ChemicalBook > CAS DataBase List > (DHQD)2PHAL

(DHQD)2PHAL

Product Name
(DHQD)2PHAL
CAS No.
140853-10-7
Chemical Name
(DHQD)2PHAL
Synonyms
(DHQD)PHAL;1,4-bis(9-O-dihydroquinidinyl)phthalazine;Hydroquinidine 1,4-phthalazinediyl ether;HYDROQUINIDINE 1,4-PHTHALAZINEDIYL DIETHER;1,4-Bis((S)-((1S,2R,4S,5R)-5-ethylquinuclidin-2-yl)(6-methoxyquinolin-4-yl)methoxy)phthalazine;1,4-bis[(S)-[(2R,4S,5R)-5-ethyl-1-azabicyclo[2.2.2]octan-2-yl]-(6-methoxyquinolin-4-yl)methoxy]phthalazine;(DHQD)2PHAL;DHQD)2 PHAL;DHQD)2PHAL (DH;(S,S)-(DHQ)2PHAL
CBNumber
CB0672988
Molecular Formula
C48H54N6O4
Formula Weight
778.98
MOL File
140853-10-7.mol
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(DHQD)2PHAL Property

Melting point:
160 °C (dec.)(lit.)
alpha 
-262 º (C=1.2 IN MEOH)
Density 
1.3
storage temp. 
Inert atmosphere,Room Temperature
solubility 
Chloroform (Slightly), DMSO (Slightly), Methanol (Sparingly)
pka
9.61±0.70(Predicted)
form 
Solid
color 
White to Pale Yellow
optical activity
[α]22/D 262°, c = 1.2 in methanol
BRN 
5475678
InChIKey
YUCBLVFHJWOYDN-SOBQURILSA-N
CAS DataBase Reference
140853-10-7(CAS DataBase Reference)
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Safety

Safety Statements 
22-24/25
WGK Germany 
3
9
HS Code 
29392000
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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
392731
Product name
(DHQD)2PHAL
Purity
≥95%
Packaging
1g
Price
$173
Updated
2024/03/01
TRC
Product number
D299905
Product name
(DHQD)2PHAL
Packaging
5g
Price
$375
Updated
2021/12/16
Biosynth Carbosynth
Product number
FD40586
Product name
(DHQD)2PHAL
Packaging
10g
Price
$460
Updated
2021/12/16
ChemScene
Product number
CS-W008033
Product name
(DHQD)2PHAL
Purity
99.59%
Packaging
25g
Price
$564
Updated
2021/12/16
ChemScene
Product number
CS-W008033
Product name
(DHQD)2PHAL
Purity
99.59%
Packaging
10g
Price
$306
Updated
2021/12/16
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(DHQD)2PHAL Chemical Properties,Usage,Production

Uses

(DHQD)2PHAL is a monomeric cinchona alkaloid dimer used as a catalyst for asymmetric halogenations.

Uses

(DHQD)2PHAL may be used as ligand for:

  • Osmium trioxide catalyzed asymmetric dihydroxylation of olefins.
  • Palladium catalyzed Suzuki-Miyaura coupling of aryl/heteroaryl halides with aryl boronic acids in aqueous medium and in the absence of phosphine/organic solvent.
  • Copper(I)-catalyzed azide-alkyne cycloaddition reaction to synthesize 1,2,3-triazoles in water.

General Description

(DHQD)2PHAL is a modified cinchona alkaloid derivative mainly used as a ligand for enantioselective catalysis.

(DHQD)2PHAL Preparation Products And Raw materials

Raw materials

Preparation Products

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(DHQD)2PHAL Suppliers

Shanghai Goyic Pharmaceutical & Chemical Co., Ltd.
Tel
021-50689757 15618953996
Fax
021-60275964
Email
sales@goyic.com
Country
China
ProdList
291
Advantage
58
Aikon International Limited
Tel
025-66113011 18112977050
Fax
02557626880
Email
sales01@aikonchem.com
Country
China
ProdList
16028
Advantage
58
Unibest Pharmaceutical Technology Co., Ltd.
Tel
13735578103
Email
postmaster@unibestpharma.com
Country
China
ProdList
126
Advantage
58
Suzhou Guide Fine Material Co.Ltd.
Tel
136-16210669 13914021065
Fax
0512-66627360
Email
sales@guide-chemicals.com
Country
China
ProdList
294
Advantage
60
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
4006608290; 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40241
Advantage
62
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44751
Advantage
61
Jia Xing Isenchem Co.,Ltd
Tel
0573-85285100 18627885956
Fax
0573-85285100
Email
isenchem@163.com
Country
China
ProdList
9551
Advantage
66
Pure Chemistry Scientific Inc.
Tel
001-857-928-2050 or 1-888-588-9418
Fax
001-617-206-9595
Email
sales@chemreagents.com
Country
United States
ProdList
10194
Advantage
62
Accela ChemBio Co.,Ltd.
Tel
021-50795510 4000665055
Fax
021-50795055
Email
sales@accelachem.com
Country
China
ProdList
11660
Advantage
64
Nanjing Chemlin Chemical Co., Ltd
Tel
025-83697070
Fax
+86-25-83453306
Email
info@chemlin.com.cn
Country
China
ProdList
17988
Advantage
64
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View Lastest Price from (DHQD)2PHAL manufacturers

Zhuozhou Wenxi import and Export Co., Ltd
Product
(DHQD)2PHAL 140853-10-7
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-08-11
Zhuozhou Wenxi import and Export Co., Ltd
Product
(DHQD)2-PHAL 140853-10-7
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-10
Zhuozhou Wenxi import and Export Co., Ltd
Product
(DHQD)2-PHAL 140853-10-7
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-09

140853-10-7, (DHQD)2PHALRelated Search:


  • SHARPLESS CATALYST
  • (DHQD)2PHAL
  • HYDROQUINIDINE 1,4-PHTHALAZINEDIYL DIETHER
  • DHQD)2 PHAL
  • (DHQD)2 PHAL, 95+%
  • HYDROQUININE-1,4-PHTHALOZINEDIYL DIETHER
  • Hydroquinidine 1,4-phthalazinediyl diether((DHQD)2PHAL)
  • (DHQD)2PHAL,Hydroquinidine 1,4-phthalazinediyl diether
  • Hydroquinidine 1,4-phthalazinediyl ether
  • DHQD)2PHAL (DH
  • 1,4-bis[(S)-[(2R,4S,5R)-5-ethyl-1-azabicyclo[2.2.2]octan-2-yl]-(6-methoxyquinolin-4-yl)methoxy]phthalazine
  • 1,4-bis(9-O-dihydroquinidinyl)phthalazine
  • (DHQD)2PHAL,99%e.e.
  • (DHQD)PHAL
  • 1,4-Bis(dihydroquinidine)phthalazine
  • Hydroquinidine 1,4-phthalazinediyl diether, 98%, for synthesis
  • Cinchonan, 9,9''-[1,4-phthalazinediylbis(oxy)]bis[10,11-dihydro-6'-methoxy-, (9S)-(9''S)-
  • 1,4-Bis((S)-((1S,2R,4S,5R)-5-ethylquinuclidin-2-yl)(6-methoxyquinolin-4-yl)methoxy)phthalazine
  • (S,S)-(DHQ)2PHAL
  • 140853-10-7
  • 40853-10-7
  • C48H54N6O4
  • Chiral Catalysts, Ligands, and Reagents
  • Asymmetric Synthesis
  • Dihydroxylation
  • Cinchona Alkaloids
  • Privileged Ligands