ChemicalBook > CAS DataBase List > 3-Fluorobenzotrifluoride

3-Fluorobenzotrifluoride

Product Name: 3-Fluorobenzotrifluoride
CAS No.: 401-80-9
Chemical Name: 3-Fluorobenzotrifluoride
Synonyms: 1-FLUORO-3-(TRIFLUOROMETHYL)BENZENE;CL052;NSC 10315;3-Fluorobenzotrifluo;3-tetrafluorotoluene;3-Fluorobezotrifluoride;-Fluorobenzotrifluoride;m-fluorotrifluorotoluene;3-Flourobenzo trifluride;M-FLUOROBENZOTRIFLUORIDE
CBNumber: CB6489111
Molecular Formula: C7H4F4
Formula Weight: 164.1
MOL File: 401-80-9.mol

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3-Fluorobenzotrifluoride Property

Melting point:: -81.5°C
Boiling point:: 101-102 °C(lit.)
Density: 1.302 g/mL at 25 °C(lit.)
refractive index: n20/D 1.4(lit.)
Flash point:: 45 °F
storage temp.: Sealed in dry,2-8°C
solubility: Chloroform
form: Oil
color: Clear Colourless
Specific Gravity: 1.302
BRN: 2045664
InChI: InChI=1S/C7H4F4/c8-6-3-1-2-5(4-6)7(9,10)11/h1-4H
InChIKey: GBOWGKOVMBDPJF-UHFFFAOYSA-N
SMILES: C1(F)=CC=CC(C(F)(F)F)=C1
CAS DataBase Reference: 401-80-9(CAS DataBase Reference)
NIST Chemistry Reference: 1-Fluoro-3-(trifluoro-methyl)benzene(401-80-9)

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Safety

Hazard Codes: F,Xi
Risk Statements: 11-36/37/38
Safety Statements: 16-26-36-24/25-33-7/9
RIDADR: UN 1993 3/PG 2
WGK Germany: 3
Hazard Note: Flammable/Irritant
HazardClass: 3
PackingGroup: II
HS Code: 29039990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H225Highly Flammable liquid and vapour

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 219371
Product name: 3-Fluorobenzotrifluoride
Purity: 99%
Packaging: 25g
Price: $29.95
Updated: 2025/07/31

TCI Chemical

Product number: F0390
Product name: 3-Fluorobenzotrifluoride
Purity: >98.0%(GC)
Packaging: 25g
Price: $54
Updated: 2025/07/31

TCI Chemical

Product number: F0390
Product name: 3-Fluorobenzotrifluoride
Purity: >98.0%(GC)
Packaging: 250g
Price: $401
Updated: 2025/07/31

TRC

Product number: F588400
Product name: 3-Fluorobenzotrifluoride
Packaging: 50g
Price: $90
Updated: 2021/12/16

AK Scientific

Product number: X8282
Product name: 3-Fluorobenzotrifluoride
Packaging: 100g
Price: $54
Updated: 2021/12/16

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3-Fluorobenzotrifluoride Chemical Properties,Usage,Production

Chemical Properties

Clear colourless to light yellow liquid

Uses

3-Fluorobenzotrifluoride is a fluorniated toluene used in photochemical reactions with aliphatic amines as well as in photocycloaddition reactions.

Uses

3-Fluorobenzotrifluoride was used:

as fluorinated aromatic solvent to investigate electrogenerated chemiluminescence of 9,10-diphenylanthracene, rubrene and anthracene
used to preparae 2-nitro-5-fluorobenzotrifluoride via nitration reaction

Synthesis

98-16-8

401-80-9

The general procedure for the synthesis of 3-fluorobenzotrifluoride (3-FBT) from m-aminobenzotrifluoride is as follows: in a three-necked round-bottomed flask equipped with a reflux condenser, thermocouples, and a stirring system, m-aminobenzotrifluoride is dissolved in o-dichlorobenzene or benzylnitrile and the reaction temperature is maintained at a temperature lower than 0 °C. Subsequently, 1.4-1.5 molar equivalents of BF3.Et2O or BF3.2H2O were slowly added. tert-butyl nitrite dissolved in the same solvent was added to the reaction mixture at ambient temperature. Next, the reaction medium was heated according to the temperature and time specified in Table (I). The reaction results were recorded in Table (I).

References

[1] Tetrahedron, 1996, vol. 52, # 1, p. 23 - 36
[2] Tetrahedron Letters, 2006, vol. 47, # 32, p. 5705 - 5708
[3] Patent: US2007/276168, 2007, A1. Location in patent: Page/Page column 8
[4] Journal de Chimie Physique et de Physico-Chimie Biologique, 1923, vol. 20, p. 60
[5] Chem. Zentralbl., 1923, vol. 94, # III, p. 918

3-Fluorobenzotrifluoride Preparation Products And Raw materials

Raw materials

m-Toluidine Sodium nitrite

Preparation Products

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3-Fluorobenzotrifluoride Suppliers

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View Lastest Price from 3-Fluorobenzotrifluoride manufacturers

Shaanxi Dideu New Materials Co. Ltd

Product: 3-Fluorobenzotrifluoride 401-80-9
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 99.0%
Supply Ability: 10000KGS
Release date: 2025-07-01

Hebei Chuanghai Biotechnology Co., Ltd

Product: 3-Fluorobenzotrifluoride 401-80-9
Price: US $10.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10 mt
Release date: 2024-12-02

Hebei Chuanghai Biotechnology Co., Ltd

Product: 3-Fluorobenzotrifluoride 401-80-9
Price: US $30.00-10.00/KG
Min. Order: 50KG
Purity: 99%
Supply Ability: 500000kg
Release date: 2024-10-31

401-80-9, 3-FluorobenzotrifluorideRelated Search:

Mesitylene Xylene 1,4-Bis(trifluoromethyl)-benzene 2-Methylbenzotrifluoride 1,2,4-Trimethylbenzene Tosufloxacin tosylate Benzotrifluoride 3,4-Dichlorobenzotrifluoride m-Xylene Thiophanate-methyl Benzene Methyl 2-FLUOROBENZOTRIFLUORIDE,O-FLUOROBENZOTRIFLUORIDE 2,4,6-Trinitrotoluene Methyl bromide 5-BROMO-2-FLUOROBENZOTRIFLUORIDE 2-FLUORO-4-(TRIFLUOROMETHYL)BENZOIC ACID 2-FLUORO-6-(TRIFLUOROMETHYL)BENZOIC ACID

3-Flourobenzo trifluride

3-(Trifluoromethyl)phenyl fluoride

3-Fluoro-1-(trifluoromethyl)benzene

benzene,1-fluoro-3-(trifluoromethy

3-Fluorobenzotrifluo

Between the fluorine Benzotrifluoride

3-Fluorobezotrifluoride

Between three fluorine fluorine toluene

m-fluorotrifluorotoluene

M-(TrifluoroMethyl)fluorobenzene

M-Fluoro(trifluoroMethyl)benzene

NSC 10315

1-Fluoro-3-(trifluoromethyl)benzene alpha,alpha,alpha,3-Tetrafluorotoluene

M-FLUOROBENZOTRIFLUORIDE

1-FLUORO-3-(TRIFLUOROMETHYL)BENZENE

1-(Trifluoromethyl)-3-fluorobenzene

3-tetrafluorotoluene

Benzene, 1-fluoro-3-(trifluoromethyl)-

benzene,1-fluoro-3-(trifluoromethyl)-

m,alpha,alpha,alpha-Tetrafluorotoluene

à,à,à,3-tetrafluorotoluene

3-Fluorobenzotrifluoride 99%

3-(trifluoromethyl)fluorobenzene,1-fluoro-3-(trifluoromethyl)benzene

m,a,a,a-Tetrafluorotoluene

m,α,α,α-tetrafluorotoluene

Toluene, alpha,alpha,alpha-m-tetrafluoro-

Toluene, m,alpha,alpha,alpha-tetrafluoro-

toluene,m,α,α,α-tetrafluoro-

Trifluoromethyl-3-fluorobenzene

3-Fluorotrifluoromethylbenzene

3-Fluorobenzotrifluoride,99%

ALPHA,ALPHA,ALPHA,3-TETRAFLUOROTOLUENE

3-FLUOROBENZOTRIFLUORIDE

CL052

M-Fluorotrifluoromethyl Benzol

1-(4-methoxyphenyl)-5-tetrazolamine

-Fluorobenzotrifluoride

3-Fluorobenzotrifluoride&gt

3-(Trifluoromethyl)fluorobenzene

-Fluorobenzotrifluoride

3- fluorobenzene trifluoro

TIANFU-CHEM 3-Fluorobenzotrifluoride

3- fluorotrifluorotoluene

3-Fluorobenezotrifluoride

α,α,α,3-tetrafluorotoluene

401-80-9

409-80-9

C7H4F4

FC6H4CF3

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Aryl

Halogenated Hydrocarbons

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Aromatic Hydrocarbons (substituted) & Derivatives

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