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Poly(caprolactone) diol

Product Name
Poly(caprolactone) diol
CAS No.
36890-68-3
Chemical Name
Poly(caprolactone) diol
Synonyms
CAPA 215;Polycaprolactone glycol;3,3-Dihydroxyoxepan-2-one;average Mn 10,000;caprolactone homopolymer diol;POLYCAPROLACTONE DIOL, M.W. 530;POLYCAPROLACTONE DIOL, M.W. 2000;POLYCAPROLACTONE DIOL, M.W. 1250;Polycaprolactone diol(88cs(55°c));Polycaprolactone diol(167cs(55°c))
CBNumber
CB6501802
Molecular Formula
(C6H10O2·C4H10O3)x
Formula Weight
0
MOL File
Mol file
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Poly(caprolactone) diol Property

Density 
1.073 g/mL at 25 °C
vapor pressure 
0Pa at 25℃
storage temp. 
2-8°C
form 
solid (waxy)
color 
White
Water Solubility 
9g/L at 20℃
LogP
1.8 at 25℃
EPA Substance Registry System
2-Oxepanone, polymer with 2,2'-oxybis[ethanol] (36890-68-3)
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Safety

Hazard Codes 
Xi
Risk Statements 
36
Safety Statements 
26
WGK Germany 
3
HS Code 
39079999
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P337+P313IF eye irritation persists: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
189405
Product name
Polycaprolactone diol
Purity
average Mn ~530
Packaging
250g
Price
$319
Updated
2024/03/01
Sigma-Aldrich
Product number
189405
Product name
Polycaprolactone diol
Purity
average Mn ~530
Packaging
500g
Price
$587
Updated
2024/03/01
Sigma-Aldrich
Product number
900625
Product name
Polycaprolactone diol
Purity
average Mn 10,000
Packaging
5G
Price
$326
Updated
2023/06/20
Sigma-Aldrich
Product number
189421
Product name
Polycaprolactone diol
Purity
average Mn ~2,000
Packaging
250g
Price
$200
Updated
2024/03/01
Sigma-Aldrich
Product number
189421
Product name
Polycaprolactone diol
Purity
average Mn ~2,000
Packaging
500g
Price
$270
Updated
2024/03/01
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Poly(caprolactone) diol Chemical Properties,Usage,Production

Description

Polycaprolactone is a biodegradable synthetic polymer that has been shown to have antimicrobial properties. Polycaprolactone has been used in wastewater treatment and has been shown to inhibit the growth of histological analysis, vivo model, vitro assays, polyvinyl, collagen, carcinoma cell lines, tissue culture, ethylene diamine, water vapor, cell culture, and hydrogen bond. It can be used to prepare biodegradable active packaging films. Since its ester-functionalized backbone structure can assist the adhesive performance, it can be used as the soft phase in the preparation of high-clarity polyurethane adhesive. Polycaprolactone (PCL) and PCL‐based materials are widely applied in the biomedical field[1]. It biodegrades slowly, which makes it more suitable for hard tissues that take longer to heal. Its mixing with other biodegradable materials regulates its degradation rate, making it also suitable for soft tissues[2]. In studies with wild-type strains of bacteria such as Escherichia coli and Staphylococcus aureus, it showed activity against both Gram-positive and Gram-negative bacteria. It also showed activity against the bacterium that causes tuberculosis.

Chemical Properties

white waxy solid

Uses

Poly(caprolactone) diol (PCL-diol), along with polytetrahydrofuran diol (PTHF-diol) and ceric ammonium nitrate may be used to polymerize methyl methacrylate (MMA). The product may be used to prepare biocompatible poly(ester urethane)urea (PEUU) and as a precursor for polyurethane (PU) thermoplastic polymer.

Uses

Poly(caprolactone) diol is a biodegradable, ε-caprolactone-based polymer for use in biomedical research applications. Due to the synthetic method used, this material features two terminal hydroxyl units, allowing it to be readily functionalized or used in the synthesis of more complex polymers (e.g. polyurethanes) for applications such as shape-memory materials. Due to the high aliphatic content and molecular weight, polycaprolactone diol features increased stability in vivo and high Tg, respectively.

References

[1] Erceg T, et al. Characterization of Films Based on Cellulose Acetate/Poly(caprolactone diol) Intended for Active Packaging Prepared by Green Chemistry Principles. ACS Sustainable Chemistry Engineering, 2022; 10: 9141–9154.
[2] Cernadas T, et al. Preparation of functionalized poly(caprolactone diol)/castor oils blends to be applied as photocrosslinkable tissue adhesives. Journal of Applied Polymer Science, 2020; 137: 49092.

Poly(caprolactone) diol Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Poly(caprolactone) diol manufacturers

Hebei Saisier Technology Co., LTD
Product
POLY(CAPROLACTONE) DIOL, AVERAGE M.N. 2000 36890-68-3
Price
US $6.00/KG
Min. Order
1KG
Purity
More than 99%
Supply Ability
500KG/Month
Release date
2024-03-25
Hebei Jingbo New Material Technology Co., Ltd
Product
Poly(caprolactone) diol 36890-68-3
Price
US $0.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
1000000
Release date
2023-12-13
Wuhan Senwayer Century Chemical Co.,Ltd
Product
POLY(CAPROLACTONE) DIOL, AVERAGE M.N. 2000 36890-68-3
Price
US $0.00/g
Min. Order
10g
Purity
99%
Supply Ability
50kg
Release date
2023-02-08

36890-68-3, Poly(caprolactone) diolRelated Search:


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  • average M<SUB>n</SUB> 10,000
  • 3,3-Dihydroxyoxepan-2-one
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