ChemicalBook > CAS DataBase List > R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-&

R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-&

Product Name: R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-&
CAS No.: 133545-16-1
Chemical Name: R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-&
Synonyms: SL-A101-1;97% (R)-MeO-BIPHEP;(R)-(+)-MeO-BIPHEP;(R)-(6,6'-Dimethoxy-[1,1'-biphenyl];R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-&;R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-&(6,6'-Dimethoxy-2,2'-biphenyldiyl)bis(diphenylphosphine);(R)-2,2'-Bis(diphenylphosphino)-6,6'-dimethoxy-1,1'- bipheny;(R)-(+)-(6,6'-dimethoxybiphenyl-2,2'-yl)bis(diphenylphosphine);(R)-(+)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis(diphenylphosph...
CBNumber: CB6502935
Molecular Formula: C38H32O2P2
Formula Weight: 582.62
MOL File: 133545-16-1.mol

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R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-& Property

Melting point:: 213-216 °C
alpha: 101 º (C=0.3 IN TOLUENE)
Boiling point:: 651.1±55.0 °C(Predicted)
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
form: crystal
color: off-white
InChIKey: KRJVQCZJJSUHHO-UHFFFAOYSA-N
SMILES: P(C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=C(OC)C=1C1C(=CC=CC=1P(C1C=CC=CC=1)C1C=CC=CC=1)OC

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Safety

WGK Germany: 3
F: 8-10-23
HS Code: 29319090

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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

TCI Chemical

Product number: M3596
Product name: (R)-MeO-BIPHEP
Packaging: 250MG
Price: $140
Updated: 2025/07/31

Strem Chemicals

Product number: 15-0178
Product name: (R)-(+)-2,2'-Bis(diphenylphosphino)-6,6'-dimethoxy-1,1'-biphenyl, min. 97% (R)-MeO-BIPHEP
Packaging: 100mg
Price: $96
Updated: 2024/03/01

Strem Chemicals

Product number: 15-0178
Product name: (R)-(+)-2,2'-Bis(diphenylphosphino)-6,6'-dimethoxy-1,1'-biphenyl, min. 97% (R)-MeO-BIPHEP
Packaging: 500mg
Price: $355
Updated: 2024/03/01

Strem Chemicals

Product number: 15-0178
Product name: (R)-(+)-2,2'-Bis(diphenylphosphino)-6,6'-dimethoxy-1,1'-biphenyl, min. 97% (R)-MeO-BIPHEP
Packaging: 2g
Price: $1207
Updated: 2024/03/01

Strem Chemicals

Product number: 15-0178
Product name: (R)-(+)-2,2'-Bis(diphenylphosphino)-6,6'-dimethoxy-1,1'-biphenyl, min. 97% (R)-MeO-BIPHEP
Packaging: 10g
Price: $4824
Updated: 2024/03/01

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R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-& Chemical Properties,Usage,Production

Chemical Properties

White powder

Uses

Ligand for ruthenium-catalyzed greener amine synthesis by enamine reduction with hydrogen gas.

Asymmetric Synthesis of (S)-3-Amino-4-methoxy-butan-1-ol by Way of Reductive Amination

Reactions

In many respects the catalytic profile of the MeOBIPHEP ligands is similar to that of other atropisomeric diphosphines such as binap and its many analogs. The nature of the PR2 group strongly influences the catalytic performance of the metal complexes. The rhodium and ruthenium MeO-BIPHEP catalysts are highly effective for the hydrogenation of various C=O, C=C and C=N bonds and several synthetically useful C-C coupling reactions.
Ru and Ir catalyzed dynamic kinetic resolution for the synthesis of hydroxy, amino acid derivatives.

1.Ru-catalyzed asymmetric hydrogenation of ketones and alkenes.
Ir catalyzed enantioselective hydrogenation of heteroaromatic compounds.
Conjugate addition using 2-heteroaryl titanates and zinc reagents.
Enantio- and regioselective heck-type reaction of aryl boronic acids with 2,3-dihydrofuran
Rhodium-catalyzed carbonyl Z-dienylation.
Rhodium-catalyzed asymmetric 1,4 addition of arylboronic acids to maleimides and enones.

General Description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-& Preparation Products And Raw materials

Raw materials

Preparation Products

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R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-& Suppliers

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View Lastest Price from R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-& manufacturers

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD

Product: R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-& 133545-16-1
Price: US $2.00-5.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 100kg
Release date: 2025-06-17

WUHAN FORTUNA CHEMICAL CO., LTD

Product: (R)-(6,6'-Dimethoxy-[1,1'-biphenyl]-2,2'-diyl)bis(diphenylphosphine) 133545-16-1
Price: US $0.00/KG
Min. Order: 1KG
Purity: 98%min
Supply Ability: 30tons/month
Release date: 2023-01-30

Career Henan Chemical Co

Product: R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-& 133545-16-1
Price: US $1.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 1kg,5kg,100kg
Release date: 2019-08-08

133545-16-1, R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-&Related Search:

R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-& (S)-(-)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole,min.98%(S)-SEGPHOS (R)-5,5'-Bis(diphenylphosphino)-2,2,2',2'-tetrafluoro-4,4'-bi-1,3-benzodioxole (R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxypheny (R)-CYCLOHEXYL SONIPHOS (R)-C3-TUNEPHOS-RUTHENIUM COMPLEX (R)-(+)-2,2'-Bis(di-p-tolylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% R-(+)-N,N'-DIMETHYL-7,7'-BIS(DI(3,5-XYLYL)PHOSPHINO)-3,3',4,4'-TETRAHYDRO-8,8'-BI-2H-1,4-BENZOXAZINE ISOPROPANOL ADDUCT (R)-(+)-5,5'-DICHLORO-6,6'-DIMETHOXY-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL (S)-(-)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97% (R)-C3-TUNEPHOS (S)-(+)-5,5'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole,min.98%(S)-DTBM-SEGPHOS (S)-(-)-2,2'-Bis[di(3,4,5-trimethoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97% R-(+)-6,6'-BIS(DIPHENYLPHOSPHINO)-2,2',3,3'-TETRAHYDRO-5,5'-BI-1,4-BENZODIOXIN SOLPHOS SL-A001-1 (R)-METHYL SONIPHOS CHLORO[(R)-(+)-5,5'-DICHLORO-6,6'-DIMETHOXY-2,2'-BIS(DIPHENYL-PHOSPHINO)-1,1'-BIPHENYL](P-CYMENE)RUTHENIUM(II) CHLORIDE CH2CL2 ADDUCT (S)-(-)-2,2'-BIS[3'',4''-METHYLENEOXYPHENYLPHOSPHINO]-5,6-5',6'-DIMETHYLENEOXY-BIPHENYL

(6,6'-Dimethoxy-2,2'-biphenyldiyl)bis(diphenylphosphine)

R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-&

(R)-(+)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis(diphenylphosphine)

(R)-(+)-2,2'-Bis(diphenylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%(R)-MeO-BIPHEP

(R)-(+)-MeO-BIPHEP, SL-A101-1, (R)-(+)-2,2μ-Bis(diphenylphosphino)-6,6μ-dimethoxy-1,1μ-biphenyl

97% (R)-MeO-BIPHEP

(R)-(+)-2,2'-Bis(diphenylphosphino)-6,6'-diMethoxy-1,1'-biphenyl,(R)-MeO-BIPHEP

(R)-(+)-MeO-BIPHEP

SL-A101-1

(R)-(+)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis(diphenylphosphine) >=97%, optical purity ee: >=99%

(S)-(6,6,-dimethoxy-[1,1,-biphenyl]-2,2,-diyl)bis(diphenylphosphine)

(R)-(+)-2,2'-Bis(diphenylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,97% (R)-MeO-BIPHEP

1,1'-[(1R)-6,6'-Dimethoxy[1,1'-biphenyl]-2,2'-diyl]bis(1,1-diphenyl)-phosphine

Phosphine, 1,1'-[(1R)-6,6'-dimethoxy[1,1'-biphenyl]-2,2'-diyl]bis[1,1-diphenyl-

(R)-2,2'-Bis(diphenylphosphino)-6,6'-dimethoxy-1,1'- bipheny

(R)-(+)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis(diphenylphosph...

R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-&amp

(R)-(+)-2,2'-Bis(diphenylphosphino)-6,6'-dimethoxy-1,1'-biphenyl

(R)-(+)-(6,6’-Dimethoxybiphenyl-2,2’-diyl)bis(diphenylphosphine)

(R)-(6,6'-Dimethoxy-[1,1'-biphenyl]-2,2'-diyl)bis(diphenylphosphine)

(6,6'-dimethoxy-[1,1'-biphenyl]-2,2'-diyl)bis(diphenylphosphine)

(R)-(6,6'-Dimethoxy-[1,1'-biphenyl]

(<i>R</i>)-(+)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis(diphenylphosphine)

(R)-(+)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis(diphenylphosphine), CAS 133545-16-1

(6,6'-dimethoxy-[1,1'-biphenyl]-2,2'-diyl)bis(diphenylphosphine)

(R)-(+)-(6,6'-dimethoxybiphenyl-2,2'-yl)bis(diphenylphosphine)

(R)-MeO-BIPHEP, (R)-(+)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis(diphenylphosphine)

(R)-MeO-BIPHEP / (R)-(+)-2,2'-Bis(diphenylphosphino)-6,6'-dimethoxy-1,1'-biphenyl

133545-16-1

C38H32O2P2

Chiral Phosphine

MeOBIPHEP Series