ChemicalBook > CAS DataBase List > R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-&
R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-&
- Product Name
- R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-&
- CAS No.
- 133545-16-1
- Chemical Name
- R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-&
- Synonyms
- SL-A101-1;97% (R)-MeO-BIPHEP;(R)-(+)-MeO-BIPHEP;(R)-(6,6'-Dimethoxy-[1,1'-biphenyl];R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-&;R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-&;R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-&R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-&(6,6'-Dimethoxy-2,2'-biphenyldiyl)bis(diphenylphosphine);(R)-2,2'-Bis(diphenylphosphino)-6,6'-dimethoxy-1,1'- bipheny
- CBNumber
- CB6502935
- Molecular Formula
- C38H32O2P2
- Formula Weight
- 582.62
- MOL File
- 133545-16-1.mol
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R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-& Property
- Melting point:
- 213-216 °C
- alpha
- 101 º (C=0.3 IN TOLUENE)
- Boiling point:
- 651.1±55.0 °C(Predicted)
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- form
- crystal
- color
- off-white
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Safety
- WGK Germany
- 3
- F
- 8-10-23
- HS Code
- 29319090
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N-Bromosuccinimide Price
Strem Chemicals
- Product number
- 15-0178
- Product name
- (R)-(+)-2,2'-Bis(diphenylphosphino)-6,6'-dimethoxy-1,1'-biphenyl, min. 97% (R)-MeO-BIPHEP
- Packaging
- 100mg
- Price
- $96
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 15-0178
- Product name
- (R)-(+)-2,2'-Bis(diphenylphosphino)-6,6'-dimethoxy-1,1'-biphenyl, min. 97% (R)-MeO-BIPHEP
- Packaging
- 500mg
- Price
- $355
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 15-0178
- Product name
- (R)-(+)-2,2'-Bis(diphenylphosphino)-6,6'-dimethoxy-1,1'-biphenyl, min. 97% (R)-MeO-BIPHEP
- Packaging
- 2g
- Price
- $1207
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 15-0178
- Product name
- (R)-(+)-2,2'-Bis(diphenylphosphino)-6,6'-dimethoxy-1,1'-biphenyl, min. 97% (R)-MeO-BIPHEP
- Packaging
- 10g
- Price
- $4824
- Updated
- 2024/03/01
BLDpharm
- Product number
- BD256651
- Product name
- (R)-(6,6'-Dimethoxy-[1,1'-biphenyl]-2,2'-diyl)bis(diphenylphosphine)
- Purity
- 98+%
- Packaging
- 5g
- Price
- $1377
- Updated
- 2021/12/16
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R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-& Chemical Properties,Usage,Production
Chemical Properties
White powder
Uses
Ligand for ruthenium-catalyzed greener amine synthesis by enamine reduction with hydrogen gas.
Asymmetric Synthesis of (S)-3-Amino-4-methoxy-butan-1-ol by Way of Reductive Amination
Reactions
In many respects the catalytic profile of the MeOBIPHEP ligands is similar to that of other atropisomeric diphosphines such as binap and its many analogs. The nature of the PR2 group strongly influences the catalytic performance of the metal complexes. The rhodium and ruthenium MeO-BIPHEP catalysts are highly effective for the hydrogenation of various C=O, C=C and C=N bonds and several synthetically useful C-C coupling reactions.
Ru and Ir catalyzed dynamic kinetic resolution for the synthesis of hydroxy, amino acid derivatives.
- 1.Ru-catalyzed asymmetric hydrogenation of ketones and alkenes.
- Ir catalyzed enantioselective hydrogenation of heteroaromatic compounds.
- Conjugate addition using 2-heteroaryl titanates and zinc reagents.
- Enantio- and regioselective heck-type reaction of aryl boronic acids with 2,3-dihydrofuran
- Rhodium-catalyzed carbonyl Z-dienylation.
- Rhodium-catalyzed asymmetric 1,4 addition of arylboronic acids to maleimides and enones.
General Description
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.
R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-& Preparation Products And Raw materials
Raw materials
Preparation Products
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R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-& Suppliers
- Tel
- --
- Fax
- --
- Country
- Switzerland
- ProdList
- 6896
- Advantage
- 91
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View Lastest Price from R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-& manufacturers
WUHAN FORTUNA CHEMICAL CO., LTD
- Product
- (R)-(6,6'-Dimethoxy-[1,1'-biphenyl]-2,2'-diyl)bis(diphenylphosphine) 133545-16-1
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 98%min
- Supply Ability
- 30tons/month
- Release date
- 2023-01-30
Career Henan Chemical Co
- Product
- R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-& 133545-16-1
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 98%
- Supply Ability
- 1kg,5kg,100kg
- Release date
- 2019-08-08
133545-16-1, R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-&Related Search:
R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-&
(R)-DIFLUORPHOS(TM)
(S)-(-)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole,min.98%(S)-SEGPHOS
(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxypheny
(R)-CYCLOHEXYL SONIPHOS
(R)-C3-TUNEPHOS-RUTHENIUM COMPLEX
(R)-(+)-2,2'-Bis(di-p-tolylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%
R-(+)-N,N'-DIMETHYL-7,7'-BIS(DI(3,5-XYLYL)PHOSPHINO)-3,3',4,4'-TETRAHYDRO-8,8'-BI-2H-1,4-BENZOXAZINE ISOPROPANOL ADDUCT
(R)-(+)-5,5'-DICHLORO-6,6'-DIMETHOXY-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL
(S)-(-)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97%
(R)-C3-TUNEPHOS
(S)-(+)-5,5'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole,min.98%(S)-DTBM-SEGPHOS
(S)-(-)-2,2'-Bis[di(3,4,5-trimethoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97%
R-(+)-6,6'-BIS(DIPHENYLPHOSPHINO)-2,2',3,3'-TETRAHYDRO-5,5'-BI-1,4-BENZODIOXIN
SOLPHOS SL-A001-1
(R)-METHYL SONIPHOS
CHLORO[(R)-(+)-5,5'-DICHLORO-6,6'-DIMETHOXY-2,2'-BIS(DIPHENYL-PHOSPHINO)-1,1'-BIPHENYL](P-CYMENE)RUTHENIUM(II) CHLORIDE CH2CL2 ADDUCT
(S)-(-)-2,2'-BIS[3'',4''-METHYLENEOXYPHENYLPHOSPHINO]-5,6-5',6'-DIMETHYLENEOXY-BIPHENYL