2-METHOXY-N-METHYLBENZYLAMINE 97
- Product Name
- 2-METHOXY-N-METHYLBENZYLAMINE 97
- CAS No.
- 6851-80-5
- Chemical Name
- 2-METHOXY-N-METHYLBENZYLAMINE 97
- Synonyms
- 2-METHOXY-N-METHYLBE;(2-methoxybenzyl)methylamine;2-Methoxy-N-methylbenzylamine;N-methyl-o-methoxybenzylamine;(2-methoxybenzyl)-methyl-amine;2-Methoxy-N-methylbenzylamine 97%;N-(2-METHOXYBENZYL)-N-METHYLAMINE;2-METHOXY-N-METHYLBENZYLAMINE 97;2-Methoxy-N-methylbenzylamine;BENZENEMETHANAMINE, 2-METHOXY-N-METHYL-
- CBNumber
- CB6505204
- Molecular Formula
- C9H13NO
- Formula Weight
- 151.21
- MOL File
- 6851-80-5.mol
2-METHOXY-N-METHYLBENZYLAMINE 97 Property
- Boiling point:
- 234-235 °C(lit.)
- Density
- 1.015 g/mL at 25 °C(lit.)
- refractive index
- n20/D 1.5325(lit.)
- Flash point:
- 222 °F
- storage temp.
- 2-8°C(protect from light)
- form
- Liquid
- color
- Colorless
Safety
- Hazard Codes
- Xn
- Risk Statements
- 22-37/38-41
- Safety Statements
- 26-36
- WGK Germany
- 3
- HazardClass
- 8
- HS Code
- 2922290090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H318Causes serious eye damage
H335May cause respiratory irritation
- Precautionary statements
-
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
N-Bromosuccinimide Price
- Product number
- 593958
- Product name
- 2-Methoxy-N-methylbenzylamine
- Purity
- 97%
- Packaging
- 1g
- Price
- $62.3
- Updated
- 2023/01/07
- Product number
- 593958
- Product name
- 2-Methoxy-N-methylbenzylamine
- Purity
- 97%
- Packaging
- 5g
- Price
- $202
- Updated
- 2023/01/07
- Product number
- M265983
- Product name
- 2-Methoxy-N-methylbenzylamine
- Packaging
- 50mg
- Price
- $60
- Updated
- 2021/12/16
- Product number
- M265983
- Product name
- 2-Methoxy-N-methylbenzylamine
- Packaging
- 250mg
- Price
- $75
- Updated
- 2021/12/16
- Product number
- M265983
- Product name
- 2-Methoxy-N-methylbenzylamine
- Packaging
- 25mg
- Price
- $45
- Updated
- 2021/12/16
2-METHOXY-N-METHYLBENZYLAMINE 97 Chemical Properties,Usage,Production
Synthesis
135-02-4
74-89-5
6851-80-5
Step A: 2-methoxybenzaldehyde (5.56 g, 40 mmol) was dissolved in methanol (40 mL) and methylamine (40 wt% aqueous solution, 6.9 mL, 80 mmol) and acetic acid (240 mg, 4 mmol) were added sequentially. The reaction mixture was stirred at room temperature for 16 h and then cooled in an ice bath. Sodium borohydride (1.51 g, 40 mmol) was added in batches under ice bath cooling conditions. After addition, the reaction mixture was continued to stir at room temperature for 3 hours. After completion of the reaction, most of the solvent was removed by concentration under reduced pressure. The residue was diluted with distilled water (100 mL) and ethyl acetate (100 mL) and partitioned. The aqueous phase was extracted with ethyl acetate (2 × 100 mL) and the organic phases were combined. The organic phase was washed sequentially with saturated brine, dried over anhydrous sodium sulfate, and concentrated under reduced pressure to afford the target product N-methyl-2-methoxybenzylamine (4.7 g, 79% yield). The product was characterized by 1H NMR (CDCl3, 500 MHz): δ 7.23 (d, J = 7.4 Hz, 2H), 6.91 (t, J = 7.4 Hz, 1H), 6.86 (d, J = 7.9 Hz, 1H), 3.83 (s, 3H), 3.75 (s, 2H), 2.42 (s, 3H); ESI MS m/z = 152 [M + H]+. The crude product obtained can be used directly in the subsequent reaction without further purification.
References
[1] Patent: US2006/52378, 2006, A1. Location in patent: Page/Page column 144
[2] Bioorganic and Medicinal Chemistry Letters, 2016, vol. 26, # 10, p. 2539 - 2543
[3] Journal of the American Chemical Society, 1944, vol. 66, p. 1875,1879
[4] European Journal of Medicinal Chemistry, 2014, vol. 76, p. 314 - 331
[5] Bioorganic and Medicinal Chemistry, 2015, vol. 23, # 5, p. 911 - 923
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