ChemicalBook > CAS DataBase List > 3-Formylphenylboronic acid

3-Formylphenylboronic acid

Product Name: 3-Formylphenylboronic acid
CAS No.: 87199-16-4
Chemical Name: 3-Formylphenylboronic acid
Synonyms: 3-FORMYLBORONIC ACID;AURORA 15117;AKOS BRN-0110;ZERENEX ZX001648;IFLAB-BB F1371-0205;TIMTEC-BB SBB004078;RARECHEM AH PB 0194;3-BORONOBENZALDEHYDE;3-Formylphenylboroni;OTAVA-BB BB7110951391
CBNumber: CB6677374
Molecular Formula: C7H7BO3
Formula Weight: 149.94
MOL File: 87199-16-4.mol

Less

3-Formylphenylboronic acid Property

Melting point:: 109-113 °C
Boiling point:: 354.4±44.0 °C(Predicted)
Density: 1.24±0.1 g/cm3(Predicted)
storage temp.: Inert atmosphere,2-8°C
solubility: soluble in Methanol
pka: 7.83±0.10(Predicted)
form: Powder, Crystals, and/or Chunks
color: Off-white to beige or light orange
Sensitive: Air Sensitive
BRN: 3030769
InChI: InChI=1S/C7H7BO3/c9-5-6-2-1-3-7(4-6)8(10)11/h1-5,10-11H
InChIKey: HJBGZJMKTOMQRR-UHFFFAOYSA-N
SMILES: B(C1=CC=CC(C=O)=C1)(O)O
CAS DataBase Reference: 87199-16-4(CAS DataBase Reference)

Less

Safety

Hazard Codes: C,Xi
Risk Statements: 34-36/37/38
Safety Statements: 22-26-36/37/39-45-37/39-27
RIDADR: UN 3261 8/PG 3
WGK Germany: 3
Hazard Note: Irritant
HazardClass: IRRITANT, MOISTURE SENSITIVE
PackingGroup: Ⅲ
HS Code: 29319090

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P310Immediately call a POISON CENTER or doctor/physician.

Less

N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 441651
Product name: 3-Formylphenylboronic acid
Purity: ≥95%
Packaging: 5g
Price: $29.09
Updated: 2025/07/31

Sigma-Aldrich

Product number: 441651
Product name: 3-Formylphenylboronic acid
Purity: ≥95%
Packaging: 25g
Price: $68.4
Updated: 2025/07/31

TCI Chemical

Product number: F0445
Product name: 3-Formylphenylboronic Acid (contains varying amounts of Anhydride)
Packaging: 1g
Price: $20
Updated: 2025/07/31

TCI Chemical

Product number: F0445
Product name: 3-Formylphenylboronic Acid (contains varying amounts of Anhydride)
Packaging: 5g
Price: $48
Updated: 2025/07/31

TCI Chemical

Product number: F0445
Product name: 3-Formylphenylboronic Acid (contains varying amounts of Anhydride)
Packaging: 25g
Price: $134
Updated: 2025/07/31

Less

3-Formylphenylboronic acid Chemical Properties,Usage,Production

Chemical Properties

Off-white Cryst

Uses

suzuki reaction

Uses

Reagent used:

To study the effects of boronic acid on fluoride-selective chemosignaling behavior of merocyanine dye
As exciton-coupled CD probes for epigallocatechin gallate

Biological inhibitor of γ-glutamyltranspeptidase

Reactant involved in:

Palladium-catalyzed homocoupling
Suzuki coupling reactions

Uses

3-Formylphenylboronic acid can be used as reagent to study the effects of boronic acid on fluoride-selective chemosignaling behavior of merocyanine dye and as exciton-coupled CD probes for epigallocatechin gallate Biological inhibitor of γ-glutamyltranspeptidase.

Synthesis

540777-53-5

121-43-7

87199-16-4

The general procedure for the synthesis of 3-formylphenylboronic acid from the compound (CAS:540777-53-5) and trimethyl borate was carried out as follows: firstly, a THF solution of trimethyl borate was prepared by adding 154.8 ml of trimethyl borate to a 3-liter three-necked flask, followed by 915 ml of tetrahydrofuran (THF). The solution was stirred under nitrogen protection and cooled with an ice bath. The cooled THF solution was slowly added to a 3-liter flask containing Grignard reagent through a stainless steel tube. The reaction mixture was stirred under ice bath cooling for 1 hour and then an aqueous sulfuric acid solution prepared from 30 ml of concentrated sulfuric acid and 480 ml of water was added. The temperature of the mixture was gradually brought to room temperature and stirring was continued at this temperature for 2 hours. After stopping stirring, the reaction mixture was allowed to stand at room temperature overnight. The precipitate was removed by filtration and the filtrate was concentrated. The concentrated residue was mixed with an equal volume of water and stirred at room temperature for 1 hour. The solid product was collected by filtration and dried to give 123.46 g of 3-formylphenylboronic acid in 88% yield. The 1H-NMR (200 MHz, CDCl3, δ ppm) data of the resulting product were as follows: 7.54 (t, J = 7.5 Hz, 1H), 7.93 (d, J = 6.1 Hz, 1H), 7.9-8.1 (br.d, 1H), 8.2-8.3 (br.s, 1H), 10.04 (s, 1H).

References

[1] BARTOSZ ZARYCHTA. 3-formylphenylboronic acid.[J]. Acta crystallographica. Section C, Crystal structure communications, 2004, 60 Pt 5: o344-5. DOI:10.1107/S0108270104006493.
[2] E. TANI?. Conformational, Structural, Vibrational, Electronic, and Molecular Docking Studies of 3-Formylphenylboronic Acid and 4-Formylphenylboronic Acid: A Comparative Study[J]. Russian Journal of Physical Chemistry A, 2020, 94 13: 2784-2796. DOI:10.1134/S0036024420130282.

3-Formylphenylboronic acid Preparation Products And Raw materials

Raw materials

Preparation Products

3-(4-METHYLPHENYL)BENZALDEHYDE

Less

3-Formylphenylboronic acid Suppliers

Americas 1 Austria 1 Belgium 2 Canada 1 China 304 Europe 5 France 2 Germany 14 India 19 Japan 3 Russia 1 Slovakia 1 Switzerland 2 The Netherlands 1 Ukraine 2 United Kingdom 20 United States 54 Global 433

Zhenjiang Carbochem Pharmatech Co.,LTD

Tel: 0511-82018158 18136818960
Email: sales4@carbo-chem.com
Country: China
ProdList: 350
Advantage: 58

Hebei Maison Chemical Co.,Ltd.

Tel: 155-11852758 15511852758
Fax: 0311-83832777
Email: ruby@maisonchem.com.cn
Country: China
ProdList: 550
Advantage: 58

Zhuhai Aobokai Biomedical Technology Co., Ltd.

Tel: 400-0628126 15697568869;
Email: sales-team@aobchem.com.cn
Country: China
ProdList: 10000
Advantage: 58

J & K SCIENTIFIC LTD.

Tel: 18210857532; 18210857532
Fax: 86-10-82849933
Email: jkinfo@jkchemical.com
Country: China
ProdList: 96815
Advantage: 76

Meryer (Shanghai) Chemical Technology Co., Ltd.

Tel: 4006356688 18621169109
Fax: 86-21-61259102
Email: market03@meryer.com
Country: China
ProdList: 40228
Advantage: 62

Alfa Aesar

Tel: 400-6106006
Fax: 021-67582001/03/05
Email: saleschina@alfa-asia.com
Country: China
ProdList: 30123
Advantage: 84

TCI (Shanghai) Development Co., Ltd.

Tel: 021-67121386
Fax: 021-67121385
Email: Sales-CN@TCIchemicals.com
Country: China
ProdList: 24529
Advantage: 81

Energy Chemical

Tel: 021-021-58432009 400-005-6266
Fax: 021-58436166
Email: sales8178@energy-chemical.com
Country: China
ProdList: 44801
Advantage: 61

Wuhan Chemwish Technology Co., Ltd

Tel: 86-027-67849912
Fax: 86-027-87531808
Email: sales@chemwish.com
Country: China
ProdList: 35896
Advantage: 56

Capot Chemical Co., Ltd

Tel: +86 (0) 571 85 58 67 18
Fax: 0086-571-85864795
Country: China
ProdList: 18207
Advantage: 66

Beijing Ouhe Technology Co., Ltd

Tel: 010-010-82967028 13522913783
Fax: +86-10-82967029
Email: 2355560935@qq.com
Country: China
ProdList: 12000
Advantage: 60

JinYan Chemicals(ShangHai) Co.,Ltd.

Tel: 13817811078
Fax: 86-021-50426522,50426273
Email: sales@jingyan-chemical.com
Country: China
ProdList: 9976
Advantage: 60

Shanghai Sinch Parmaceuticals Tech. Co. Ltd.

Tel: +86-21-54098501
Fax: +86-21-54096319
Email: sales@sinch.com.cn
Country: China
ProdList: 11598
Advantage: 64

Jia Xing Isenchem Co.,Ltd

Tel: 0573-85285100 18627885956
Fax: 0573-85285100
Email: isenchem@163.com
Country: China
ProdList: 9310
Advantage: 66

Accela ChemBio Co.,Ltd.

Tel: 021-50795510 4000665055
Fax: 021-50795055
Email: sales@accelachem.com
Country: China
ProdList: 11035
Advantage: 64

Shanghai Longsheng chemical Co.,Ltd.

Tel: 021-58099652-8005 13585536065
Fax: 021-58099609
Email: bin.wu@shlschem.com
Country: China
ProdList: 9883
Advantage: 59

Nanjing Chemlin Chemical Co., Ltd

Tel: 025-83697070
Fax: +86-25-83453306
Email: info@chemlin.com.cn
Country: China
ProdList: 16075
Advantage: 64

Shanghai Hanhong Scientific Co.,Ltd.

Tel: 021-54306202 13764082696
Email: info@hanhongsci.com
Country: China
ProdList: 42934
Advantage: 64

China DongFan Chemical Co.,LTD

Tel: 86-0571-85151182
Fax: 86-0571-85151182
Country: China
ProdList: 5691
Advantage: 66

XiaoGan ShenYuan ChemPharm co,ltd

Tel: 15527768836
Email: 1791901229@qq.com
Country: China
ProdList: 6950
Advantage: 52

Beijing Isomersyn Technology CO;LTD

Tel: 010-82954736 13391601435
Email: sales@isomersyn.com
Country: China
ProdList: 3295
Advantage: 57

Shandong Xiya Chemical Co., Ltd

Tel: 4009903999 13355009207
Fax: 0539-6365991
Email: 3007715519@qq.com
Country: China
ProdList: 18729
Advantage: 57

Xi’an chemsoar Medical Technology Co., ltd

Tel: 029-86538357
Fax: 029-87871708
Country: China
ProdList: 234
Advantage: 57

Shanghai Ennopharm Co., Ltd.

Tel: +86 (21) 6435-5022
Country: China
ProdList: 4267
Advantage: 65

HANSHANG CHEMICAL SCIENTIFIC LIMITED

Tel: 021-50521775 15800962688
Fax: 86-21-58306291
Email: sales@hanshangchem.com
Country: China
ProdList: 471
Advantage: 57

DKD Shijiazhuang Chemical Co., Ltd.

Tel: 0311-0311-67790228 15531158659
Fax: 66571013
Email: 1257738041@qq.com
Country: China
ProdList: 297
Advantage: 62

Sichuan Kulinan Technology Co., Ltd

Tel: 400-1166-196 18981987031
Fax: 028-84555506 800101999
Email: cdhxsj@163.com
Country: China
ProdList: 11705
Advantage: 57

Tianjin heowns Biochemical Technology Co., Ltd.

Tel: 400 638 7771
Email: sales@heowns.com
Country: China
ProdList: 14435
Advantage: 57

Sinopharm Chemical Reagent Co,Ltd.

Tel: 86-21-63210123
Fax: 86-21-63290778 86-21-63218885
Email: sj_scrc@sinopharm.com
Country: China
ProdList: 9815
Advantage: 79

Nanjing Vital Chemical Co., Ltd.

Tel: Please Send Email 18652950785
Fax: 025-87193546
Email: chemweiao@163.com
Country: China
ProdList: 4378
Advantage: 65

Tongchuang Pharma(Suzhou). Co., Ltd.

Tel: 0512-63263366 18912765016
Fax: 0512-6326 3366
Email: tongtf110@sina.com
Country: China
ProdList: 993
Advantage: 62

Shanghai Sphchem Co., Ltd.

Tel: 021-56491756 13512199871
Fax: 021-5649-1756
Email: 2819742715@qq.com
Country: China
ProdList: 4000
Advantage: 55

Spectrum Chemical Manufacturing Corp.

Tel: 021-021-021-67601398-809-809-809 15221380277
Fax: 021-57711696
Email: marketing_china@spectrumchemical.com
Country: China
ProdList: 9658
Advantage: 60

Chengdu Ai Keda Chemical Technology Co., Ltd.

Tel: 4008-755-333 18080918076
Fax: 028-86757656
Email: 800078821@qq.com
Country: China
ProdList: 9718
Advantage: 55

T&W GROUP

Tel: 021-61551611 13296011611
Fax: ＋86 21-50676805
Email: contact@trustwe.com
Country: China
ProdList: 9895
Advantage: 58

Shanghai civi chemical technology co.,Ltd

Tel: 86-21-34053660
Fax: 86-21-34053661
Email: sale@labgogo.com
Country: China
ProdList: 9865
Advantage: 52

Suzhou Sibian Chemical Technology Co.,Ltd.

Tel: 0512-65617459 18915409046
Fax: 0512-65617459
Email: sales@sibian-chem.com
Country: China
ProdList: 1922
Advantage: 55

Thermo Fisher Scientific

Tel: 800-810-5118
Fax: +86-10-84193589
Email: cnchemical@thermofisher.com
Country: China
ProdList: 17770
Advantage: 75

Beijing HuaMeiHuLiBiological Chemical

Tel: 010-56205725
Fax: 010-65763397
Email: waley188@sohu.com
Country: China
ProdList: 12335
Advantage: 58

Beijing innoChem Science & Technology Co.,Ltd.

Tel: 400-810-7969 010-59572699
Fax: 010-59572688
Email: ningzi.li@inno-chem.com.cn
Country: China
ProdList: 6134
Advantage: 55

Shanghai Litong Chemical Technology Co.,Ltd.

Tel: 13598610367 0373-7129549
Fax: 0373-8369699
Email: 2468833170@qq.com
Country: China
ProdList: 932
Advantage: 58

Shanghai Topbiochem Technology Co., Ltd

Tel: 021-58170097
Email: info@topbiochem.com
Country: China
ProdList: 9510
Advantage: 58

Nanjing Norris-Pharm Technology Co., Ltd

Tel: 18652989687
Fax: +86-25-52131256
Email: sales@norris-pharm.com
Country: China
ProdList: 8878
Advantage: 55

Jiangsu Aikon Biopharmaceutical R&D co.,Ltd.

Tel: 025-66113011 17798518460
Fax: (1)02557626880
Email: cfzhang@aikonchem.com
Country: China
ProdList: 19913
Advantage: 55

Shanghai Jian Chao Chemical Technology Co., Ltd.

Tel: 150-2103-5486 18017383231
Fax: qq：2817624287
Email: 983544897@qq.com
Country: China
ProdList: 9342
Advantage: 55

Candia Thamtech Company Limited

Tel: 0371-86615086 18203638366 0371-86159066 13526786601
Fax: 0371-86159066
Country: China
ProdList: 2015
Advantage: 60

9ding chemical ( Shanghai) Limited

Tel: 4009209199
Fax: 86-021-52271987
Email: sales@9dingchem.com
Country: China
ProdList: 18209
Advantage: 56

Shanghai Aladdin Bio-Chem Technology Co.,LTD

Tel: 400-6206333 13167063860
Fax: 021-50323701
Email: anhua.mao@aladdin-e.com
Country: China
ProdList: 25003
Advantage: 65

The future of Shanghai Industrial Co., Ltd.

Tel: 021-61552785
Fax: 021-55660885
Email: sales@shshiji.com
Country: China
ProdList: 9546
Advantage: 55

Runpharm Technology Limited

Tel: 18171398856 2968382473
Fax: 0086-21-50758330
Email: service@runpharm.com
Country: China
ProdList: 716
Advantage: 55

Less

View Lastest Price from 3-Formylphenylboronic acid manufacturers

Henan Fengda Chemical Co., Ltd

Product: 3-Formylphenylboronic acid 87199-16-4
Price: US $34.00-1.20/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: g-kg-tons, free sample is available
Release date: 2024-04-08

Shijiazhuang tongyang Import and Export Co., LTD

Product: 3-Formylphenylboronic acid 87199-16-4
Price: US $40.00/KG
Min. Order: 1KG
Purity: 99
Supply Ability: 10 tons
Release date: 2021-08-12

Zhuozhou Wenxi import and Export Co., Ltd

Product: 3-Formylphenylboronic acid 87199-16-4
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-07-10

87199-16-4, 3-Formylphenylboronic acidRelated Search:

4-Hydroxyphenylboronic acid Ethyl 2-(Chlorosulfonyl)acetate Glycine Phenylboronic acid Phenethylboronic acid Folic acid Citric acid Ascoric Acid ETHYL 3-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)BENZOATE 2,4-Dimethoxybenzeneboronic acid 5-Borono-2-fluorobenzaldehyde~4-Fluoro-3-formylphenylboronic acid 3-Formyl-4-methoxyphenylboronic acid 3-AMINO-5-METHOXYCARBONYLPHENYLBORONIC ACID, HCL 3-Acetylphenylboronic acid 3-Ethoxycarbonylphenylboronic acid 3-(ISOPROPOXYCARBONYL)PHENYLBORONIC ACID 3-Carboxyphenylboronic acid 3-tert-Butoxycarbonylphenylboronic acid

AKOS BRN-0110

3-BORONOBENZALDEHYDE

3-FORMYLPHENYLBORONIC ACID

3-FORMYLBORONIC ACID

3-FORMYLBENZENEBORONIC ACID

3-(DIHYDROXYBORYL)BENZALDEHYDE

3-Formylpenylboronic Acid

Boronic acid, B-(3-forMylphenyl)-

3-Formylphenylboronic acid 3-Boronobenzaldehyde

(3-methanoylphenyl)boronic acid

AURORA 15117

BENZALDEHYDE-3-BORONIC ACID

IFLAB-BB F1371-0205

ZERENEX ZX001648

TIMTEC-BB SBB004078

RARECHEM AH PB 0194

OTAVA-BB BB7110951391

M-FORMYLPHENYLBORONIC ACID

Boronic acid, (3-formylphenyl)- (9CI)

3-ForMylphenylboronic acid, 97% 1GR

3-ForMylphenylboronic acid, 97% 5GR

3-FORMYLPHENYLBORONIC ACID (CONTAINS VARYING AMOUNTS OF ANHYDRIDE)

3-(Dihydroxyboryl)benzaldehyde, 3-Boronobenzaldehyde

3-Formylphenylboronic acid,97%

2-bromo-1-(2,3-dihydrobenzo[b][1,4]dioxin-6-yl)ethanone

3-Formylphenylboronic acid, May contain varying amounts of anhydride, 97%

3-Formylphenylboroni

m-formyl-benzeneboronic acid

3-Boronobenzaldehyde~3-Formylphenylboronic acid

3-Formylbenzeneboronic acid,3-Boronobenzaldehyde

3-Formylphenylboronic acid - [F3520]

87199-16-4

7199-16-4

C7H7BO3

B (Classes of Boron Compounds)

Boronic Acids

Aryl

Boronic Acids and Derivatives

Analytical Standards

Analytical Chromatography Product Catalog

Alphabetic

Organometallic Reagents

FM - FZ

Aryl Boronic Acids

Boronic Acids and Derivatives

Building Blocks

Chemical Synthesis

Substituted Boronic Acids

Boronic Acids & Esters

Phenyls & Phenyl-Het

Boronic acids

Boronic Acid

Boron, Nitrile, Thio,& TM-Cpds

Carbonyl Compounds

Aryl

Organoborons

B (Classes of Boron Compounds)