ChemicalBook > CAS DataBase List > N-[(Trimethylsilyl)methyl]benzylamine

N-[(Trimethylsilyl)methyl]benzylamine

Product Name: N-[(Trimethylsilyl)methyl]benzylamine
CAS No.: 53215-95-5
Chemical Name: N-[(Trimethylsilyl)methyl]benzylamine
Synonyms: SILANE BENZYL-TMSMA;N-(trimethylsilylmethyl)benzamine;Benzyl(trimethylsilylmethyl)amine;N-BENZYLAMINOMETHYLTRIMETHYLSILANE;N-(TRIMETHYLSILYLMETHYL)BENZYAMINE;N-(TRIMETHYLSILYLMETHYL)BENZYLAMINE;N-Benzyl-1-(trimethylsilyl)methylamine;N-benzyl-1-(trimethylsilyl)methanamine;N-(Trimethylsilylmethyl)benzylamine 95+%;N-Benzyl-N-[(triMethylsilyl)Methyl]aMine
CBNumber: CB6744252
Molecular Formula: C11H19NSi
Formula Weight: 193.36
MOL File: 53215-95-5.mol

Less

N-[(Trimethylsilyl)methyl]benzylamine Property

Boiling point:: 89-90 °C5 mm Hg(lit.)
Density: 0.88 g/mL at 25 °C(lit.)
refractive index: n20/D 1.496(lit.)
Flash point:: 205 °F
storage temp.: Keep in dark place,Sealed in dry,Room Temperature
form: Liquid
pka: 9.29±0.20(Predicted)
Specific Gravity: 0.88
color: Pale yellow
Hydrolytic Sensitivity: 4: no reaction with water under neutral conditions
InChI: InChI=1S/C11H19NSi/c1-13(2,3)10-12-9-11-7-5-4-6-8-11/h4-8,12H,9-10H2,1-3H3
InChIKey: WECLUYCAWLJMKM-UHFFFAOYSA-N
SMILES: C1(CNC[Si](C)(C)C)=CC=CC=C1
CAS DataBase Reference: 53215-95-5(CAS DataBase Reference)

Less

Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-37/39
WGK Germany: 3
TSCA: No
HS Code: 29319090

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Less

N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 303615
Product name: N-[(Trimethylsilyl)methyl]benzylamine
Purity: 98%
Packaging: 5g
Price: $48.5
Updated: 2022/05/15

TCI Chemical

Product number: T3000
Product name: N-[(Trimethylsilyl)methyl]benzylamine
Purity: >96.0%(GC)(T)
Packaging: 5mL
Price: $49
Updated: 2025/07/31

TRC

Product number: B124808
Product name: N-Benzyl-1-(trimethylsilyl)methanamine
Packaging: 100mg
Price: $60
Updated: 2021/12/16

AK Scientific

Product number: V3960
Product name: N-[(Trimethylsilyl)methyl]benzylamine
Packaging: 5g
Price: $15
Updated: 2021/12/16

Matrix Scientific

Product number: 075352
Product name: N-(Trimethylsilylmethyl)benzylamine
Purity: 95+%
Packaging: 25g
Price: $49
Updated: 2021/12/16

Less

N-[(Trimethylsilyl)methyl]benzylamine Chemical Properties,Usage,Production

Chemical Properties

Colorless liquid

Uses

N-[(Trimethylsilyl)methyl]benzylamine may be used in chemical synthesis.

General Description

N-[(Trimethylsilyl)methyl]benzylamine is useful intermediate to cyanoaminosilanes which are subsequently used as azomethine ylide equivalents.

Synthesis

4206-67-1

100-46-9

53215-95-5

General method: Benzylamine derivatives (24.3 mmol, 37 (2.6 g); 28.0 mmol, 38 (3.4 g); 28.0 mmol, 39 (3.8 g); 11.2 mmol, 40 (1.4 g); and 11.2 mmol, 41 (2.0 g)) were dissolved in acetonitrile (120 mL), added K2CO3 (37.4 mmol, 5.2 g (for 37); 46.7 mmol, 2.5 g (for 38-39); 18.7 mmol, 2.6 g (for 40-41)) and Me3SiCH2I (18.5 mmol, 4.0 g (for 37); 38.4 mmol, 59 g (for 38-39); 9.3 mmol, 2.0 g (for 40-41)). The reaction mixture was stirred for 12 h at room temperature. After completion of the reaction, the mixture was concentrated in vacuum to give a residue. The residue was ground with CH2Cl2, dried and concentrated again under vacuum. Finally, it was purified by silica gel column chromatography (eluent ratio: EtOAc:hexane=1:8~1:15) to give the products 421 (3.2 g, 89%), 43 (3.85 g, 79%), 442 (3.3 g, 63%), 45 (1.51 g, 76%) and 46 (1.9 g, 78%), respectively.

References

[1] Tetrahedron Letters, 2015, vol. 56, # 23, p. 3014 - 3018
[2] Organic and Biomolecular Chemistry, 2016, vol. 14, # 44, p. 10502 - 10510
[3] Tetrahedron Letters, 2017, vol. 58, # 10, p. 949 - 954
[4] Tetrahedron, 2017, vol. 73, # 44, p. 6249 - 6261

N-[(Trimethylsilyl)methyl]benzylamine Preparation Products And Raw materials

Raw materials

Preparation Products

Less

N-[(Trimethylsilyl)methyl]benzylamine Suppliers

China 153 Germany 1 India 5 Japan 1 Singapore 1 Slovakia 1 Switzerland 1 United Kingdom 3 United States 23 Global 189

Suzhou Highfine Biotech Co., Ltd

Tel: 0512-69209928 18796809688
Email: zhouyingxiang@highfine.com
Country: China
ProdList: 1356
Advantage: 58

Shanghai Annengjian Biomedical Technology Co., LTD

Tel: 021-68781987 13818305065
Email: sales@energybiopharma.com
Country: China
ProdList: 652
Advantage: 58

Shanghai Meiquan Chemical Technology Co., Ltd.

Tel: 15802146997; 15802146997
Email: zkq1984@163.com
Country: China
ProdList: 454
Advantage: 58

J & K SCIENTIFIC LTD.

Tel: 18210857532; 18210857532
Fax: 86-10-82849933
Email: jkinfo@jkchemical.com
Country: China
ProdList: 96815
Advantage: 76

Meryer (Shanghai) Chemical Technology Co., Ltd.

Tel: 4006356688 18621169109
Fax: 86-21-61259102
Email: market03@meryer.com
Country: China
ProdList: 40228
Advantage: 62

TCI (Shanghai) Development Co., Ltd.

Tel: 021-67121386
Fax: 021-67121385
Email: Sales-CN@TCIchemicals.com
Country: China
ProdList: 24529
Advantage: 81

Energy Chemical

Tel: 021-021-58432009 400-005-6266
Fax: 021-58436166
Email: sales8178@energy-chemical.com
Country: China
ProdList: 44801
Advantage: 61

Capot Chemical Co., Ltd

Tel: +86 (0) 571 85 58 67 18
Fax: 0086-571-85864795
Country: China
ProdList: 18207
Advantage: 66

JinYan Chemicals(ShangHai) Co.,Ltd.

Tel: 13817811078
Fax: 86-021-50426522,50426273
Email: sales@jingyan-chemical.com
Country: China
ProdList: 9976
Advantage: 60

Shangchem Co., Ltd.

Tel: +86-21-68182121
Fax: +86-21-68182121
Country: China
ProdList: 882
Advantage: 52

Tetranov Biopharm

Tel: 13526569071
Email: sales@leadmedpharm.com
Country: China
ProdList: 7892
Advantage: 64

Accela ChemBio Co.,Ltd.

Tel: 021-50795510 4000665055
Fax: 021-50795055
Email: sales@accelachem.com
Country: China
ProdList: 11035
Advantage: 64

Nanjing Chemlin Chemical Co., Ltd

Tel: 025-83697070
Fax: +86-25-83453306
Email: info@chemlin.com.cn
Country: China
ProdList: 16077
Advantage: 64

Shanghai Hanhong Scientific Co.,Ltd.

Tel: 021-54306202 13764082696
Email: info@hanhongsci.com
Country: China
ProdList: 42934
Advantage: 64

China Langchem Inc.

Tel: 0086-21-58956006
Fax: 0086-21-58956100
Country: China
ProdList: 7811
Advantage: 57

SpringPharma Tech Co.,Ltd

Tel: +86-25-68710855, +86-25-68710897
Fax: 025-68710856
Email: sales@springpharma.net
Country: China
ProdList: 1261
Advantage: 62

Chengdu Ai Keda Chemical Technology Co., Ltd.

Tel: 4008-755-333 18080918076
Fax: 028-86757656
Email: 800078821@qq.com
Country: China
ProdList: 9718
Advantage: 55

Shanghai civi chemical technology co.,Ltd

Tel: 86-21-34053660
Fax: 86-21-34053661
Email: sale@labgogo.com
Country: China
ProdList: 9865
Advantage: 52

Suzhou Sibian Chemical Technology Co.,Ltd.

Tel: 0512-65617459 18915409046
Fax: 0512-65617459
Email: sales@sibian-chem.com
Country: China
ProdList: 1922
Advantage: 55

Nanjing JinruiJiuAn Biotechnology Co., Ltd.

Tel: 025-58196018 800028039
Fax: 025-83453306
Email: sales@fartop.net
Country: China
ProdList: 2229
Advantage: 55

Shanghai Topbiochem Technology Co., Ltd

Tel: +86-21-60341587
Fax: +86-21-61294319
Email: sales@topbiochem.com
Country: China
ProdList: 6175
Advantage: 58

9ding chemical ( Shanghai) Limited

Tel: 4009209199
Fax: 86-021-52271987
Email: sales@9dingchem.com
Country: China
ProdList: 18209
Advantage: 56

Shanghai Aladdin Bio-Chem Technology Co.,LTD

Tel: 400-6206333 13167063860
Fax: 021-50323701
Email: anhua.mao@aladdin-e.com
Country: China
ProdList: 25003
Advantage: 65

Shanghai chuqing Organosilane technology ltd

Tel: 021-61530618; 18721685818
Fax: 86-21-51714575
Email: sales@chuqingtech.com
Country: China
ProdList: 274
Advantage: 55

Shanghai Sheepchem Co., Ltd.

Tel: +86 (21) 6715-7650
Fax: +86 (21) 6715-7651
Email: sheepchem@163.com
Country: China
ProdList: 994
Advantage: 60

Shanghai Witofly Chemical Co.,Ltd

Tel
Email: sales@witofly.com
Country: China
ProdList: 2864
Advantage: 52

Shanghai Raise Chemical Technology Co.,Ltd

Tel: +86-021-50935922
Fax: +86-021-33847795
Country: China
ProdList: 7865
Advantage: 55

Chengdu AstaTech Trading Co., Ltd./AstaTech (Chengdu) Pharma. Co., Ltd.

Tel: +86-28-85122536 85324413
Fax: +86-28-85326443
Email: market@astatech.cn
Country: China
ProdList: 8026
Advantage: 55

Shanghai JONLN Reagent Co., Ltd.

Tel: 400-0066400 13621662912
Fax: 021-55660885
Email: 422131432@qq.com
Country: China
ProdList: 9979
Advantage: 55

Huainan Kedi Chemical Factory

Tel: 0554-2106669
Fax: 0554-2666215
Email: sales1@kedichem.com
Country: China
ProdList: 4924
Advantage: 55

Bide Pharmatech Ltd.

Tel: 400-164-7117 13681763483
Fax: +86-21-61629029
Email: product02@bidepharm.com
Country: China
ProdList: 39966
Advantage: 60

Shanghai Gileader Advanced Material Technology Co.,Ltd

Tel: 18516111942
Email: 823898732@qq.com
Country: China
ProdList: 1328
Advantage: 56

Shanghai Worldyang Chemical Co.,Ltd.

Tel: 021-021-56795766
Fax: +86-21-56795266
Email: sales@worldyachem.com
Country: China
ProdList: 9476
Advantage: 58

Chengdu HuaXia Chemical Reagent Co. Ltd

Tel: 400-1166-196 13458535857
Fax: QQ：800101999
Email: cdhxsj@163.com
Country: China
ProdList: 13350
Advantage: 58

Shanghai AQBioPharma Co., Ltd.

Tel: 13661411401
Fax: 51370935-8011
Email: yinglv.que@aqbiopharma.com.cn
Country: China
ProdList: 2930
Advantage: 58

Tianjin Anhao Biological Technology Co., Ltd.

Tel
Email: sales@ahpharmatech.com
Country: China
ProdList: 5734
Advantage: 55

Shanghai Jovan Biochemical Technology Co. Ltd.

Tel: +86-021-61654350
Fax: +86-021-61654350
Email: 1245958370@qq.com
Country: China
ProdList: 2982
Advantage: 50

Jiangsu Aikon Biopharmaceutical R&D co.,Ltd.

Tel: 025-66028182 18626450290
Email: yftan@aikonchem.com
Country: China
ProdList: 16679
Advantage: 50

Cool Pharm, Ltd

Tel: 021-60455363 18019463053
Fax: 50966098
Email: sales@coolpharm.com
Country: China
ProdList: 12346
Advantage: 58

Sigma-Aldrich

Tel: 021-61415566 800-8193336
Email: orderCN@merckgroup.com
Country: China
ProdList: 51395
Advantage: 80

Infinity SCI

Tel: 400-106-2016 17800804092
Email: admin@infsci.com
Country: China
ProdList: 553
Advantage: 55

Shanghai Enchem Industry Co., Ltd.

Tel: 15021317485
Fax: 021-58109752
Country: China
ProdList: 1403
Advantage: 58

Shanghai Zhuang Ming New Material Technology Co., Ltd.

Tel: 17312398916 051386936896 15216715905
Fax: 051386936896
Email: sales@zhuangming.net
Country: China
ProdList: 1271
Advantage: 58

Shanghai Synchem Pharma Co., ltd

Tel: 21-619849051-1 18521059765
Email: synchempharma@aliyun.com
Country: China
ProdList: 6468
Advantage: 55

NovoChemy Ltd.

Tel: 86-(0)21-31261262 373522135
Fax: 86-(0)21-33250524
Email: sales@novochemy.com
Country: China
ProdList: 6498
Advantage: 58

Chengdu RunZeBenTu Chemical Co., Ltd

Tel: 028-88469284 18000562381
Email: rzbtsj@163.com
Country: China
ProdList: 9951
Advantage: 56

Hubei Chuangliankangcheng Pharmaceutical Co., Ltd.

Tel: 027-65388397 18164111589
Fax: 027-65388397
Email: 3321478047@qq.com
Country: China
ProdList: 2007
Advantage: 55

Codow Chemical Co.,Ltd.

Tel: 18620099427
Fax: +86-20-62619665
Email: amy@howeipharm.com
Country: China
ProdList: 6687
Advantage: 55

Haimen Ruiyi Medical Tech Co., LTD

Tel: 021-54718086
Fax: 021-54711707
Email: sales5@ruiyitech.com
Country: China
ProdList: 271
Advantage: 58

Henan CoreyChem Co., Ltd

Tel: 0371-86658258
Fax: 0371-60996044
Email: info@coreychem.com
Country: China
ProdList: 10453
Advantage: 58

Less

View Lastest Price from N-[(Trimethylsilyl)methyl]benzylamine manufacturers

Shaanxi Dideu New Materials Co. Ltd

Product: N-[(Trimethylsilyl)methyl]benzylamine 53215-95-5
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 98.0%
Supply Ability: 10000KGS
Release date: 2025-07-07

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD

Product: N-(Trimethylsilylmethyl)benzylamine 53215-95-5
Price: US $3.00-9.00/KG
Min. Order: 0.1KG
Purity: 99%
Supply Ability: g-kg-tons, free sample is available
Release date: 2025-06-27

Zhuozhou Wenxi import and Export Co., Ltd

Product: N-[(Trimethylsilyl)methyl]benzylamine 53215-95-5
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-07-10

53215-95-5, N-[(Trimethylsilyl)methyl]benzylamineRelated Search:

4-Fluorobenzylamine Methylparaben Kresoxim-methyl DL-ALPHA-METHYLBENZYLAMINE Methyl acrylate Phenoxybenzamine hydrochloride Methyl acetate N-(Trimethylsilyl)acetamide METHYL THIOPHENE-2-CARBOXYLATE Bensulfuron methyl N-(Trimethylsilyl)imidazole Trimethoprim Trimethylsilylacetylene Thiophanate-methyl Methyl (S)-(-)-N-METHOXYMETHYL-N-(TRIMETHYLSILYL)METHYL-1-PHENYLETHYLAMINE N-(Methoxymethyl)-N-(trimethylsilylmethyl)benzylamine Methyl bromide

N-(TRIMETHYLSILYLMETHYL)BENZYAMINE

N-(Trimethylsilylmethyl)benzylamine 95+%

Benzyl(trimethylsilylmethyl)amine

N-(trimethylsilylmethyl)benzamine

N-benzyl-1-(trimethylsilyl)methanamine

N-Benzyl-1-(trimethylsilyl)methylamine

BenzeneMethanaMine, N-[(triMethylsilyl)Methyl]-

N-Benzyl-N-[(triMethylsilyl)Methyl]aMine

N-[(TriMethylsilyl)Methyl]benzylaMine 98%

<i>N</i>-(Trimethylsilylmethyl)benzylamine

N-BENZYLAMINOMETHYLTRIMETHYLSILANE

N-(TRIMETHYLSILYLMETHYL)BENZYLAMINE

SILANE BENZYL-TMSMA

1-phenyl-N-(trimethylsilylmethyl)methanamine

53215-95-5

C11H19NSi

C6H5CH2NHCH2SiCH33

AMINE

Building Blocks

C11 to C37

Nitrogen Compounds

Organic Building Blocks

Amines

C11 to C38

Nitrogen Compounds

Amines and Anilines