ChemicalBook > CAS DataBase List > 2,2'-OXYDIANILINE

2,2'-OXYDIANILINE

Product Name
2,2'-OXYDIANILINE
CAS No.
24878-25-9
Chemical Name
2,2'-OXYDIANILINE
Synonyms
2,2’-Oxydlaniline;2,2'-Oxydianiline;2-AMINOPHENYL ETHER;Aniline, 2,2'-oxydi-;Olanzapine Impurity 33;Bis(2-aminophenyl) ether;2,2'-Oxybis(benzenamine);2-(2-aminophenoxy)aniline;Benzenamine, 2,2'-oxybis-;2,2'-Diaminodiphenyl ether
CBNumber
CB6772545
Molecular Formula
C12H12N2O
Formula Weight
200.24
MOL File
24878-25-9.mol
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2,2'-OXYDIANILINE Property

Melting point:
61-64 °C(lit.)
Boiling point:
148.5-149.5 °C(Press: 0.3 Torr)
Density 
1.216
storage temp. 
Keep in dark place,Inert atmosphere,Room temperature
pka
4.15±0.10(Predicted)
form 
Powder
color 
White to pale brown
Water Solubility 
Slightly soluble in water.
InChI
InChI=1S/C12H12N2O/c13-9-5-1-3-7-11(9)15-12-8-4-2-6-10(12)14/h1-8H,13-14H2
InChIKey
GOJFAKBEASOYNM-UHFFFAOYSA-N
SMILES
O(C1=CC=CC=C1N)C1=CC=CC=C1N
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-27-36/37/39-45
WGK Germany 
3
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
470716
Product name
2,2′-Oxydianiline
Purity
98%
Packaging
1g
Price
$75
Updated
2023/01/07
TRC
Product number
O870633
Product name
2,2''-Oxydianiline
Packaging
50mg
Price
$60
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CHM0157206
Product name
2-(2-AMINOPHENOXY)ANILINE
Purity
95.00%
Packaging
1G
Price
$721.57
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CHM0157206
Product name
2-(2-AMINOPHENOXY)ANILINE
Purity
95.00%
Packaging
2.5G
Price
$983.88
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CHM0157206
Product name
2-(2-AMINOPHENOXY)ANILINE
Purity
95.00%
Packaging
5G
Price
$1168.42
Updated
2021/12/16
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2,2'-OXYDIANILINE Chemical Properties,Usage,Production

Uses

It is catalytic reagent and used in pharmaceutical industry.

Synthesis

2217-65-4

24878-25-9

General procedure for the synthesis of 2,2'-diaminodiphenyl ether from 2,2'-oxo-bis(nitrobenzene): first, an aqueous suspension of iron powder and hydrochloric acid was refluxed under stirring for 25 minutes. Subsequently, the corresponding dinitro compound was added to this hot suspension and the reflux reaction was continued for 24 hours. Upon completion of the reaction, the mixture was cooled to room temperature and hydrolyzed with 20 mL of 2.5 M sodium hydroxide solution. Next, the reaction mixture was extracted with chloroform (20 mL each time, twice). The organic phases were combined, dried with anhydrous sodium sulfate and finally the solvent was evaporated to give the target product 2,2'-diaminodiphenyl ether as a solid.

References

[1] Tetrahedron, 1995, vol. 51, # 2, p. 579 - 590
[2] Polyhedron, 2015, vol. 90, p. 165 - 174
[3] Synthesis, 1996, # 8, p. 930 - 940
[4] Journal of Organic Chemistry, 1994, vol. 59, # 24, p. 7306 - 7315
[5] Zeitschrift fur Anorganische und Allgemeine Chemie, 2015, vol. 641, # 1, p. 128 - 135

2,2'-OXYDIANILINE Preparation Products And Raw materials

Raw materials

Preparation Products

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2,2'-OXYDIANILINE Suppliers

Shanghai Sealing Biotechnology Co. Ltd..
Tel
15721176654
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1815535157@qq.com
Country
China
ProdList
881
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58
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
Chemexcel (Zhangjiakou) Fine Chemicals Co., Ltd
Tel
86-10-62944695-809
Fax
86-10-82415873
Email
sales@chemexcel.com.cn
Country
China
ProdList
80
Advantage
62
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696
Email
info@hanhongsci.com
Country
China
ProdList
42934
Advantage
64
Shandong Xiya Chemical Co., Ltd
Tel
4009903999 13355009207
Fax
0539-6365991
Email
3007715519@qq.com
Country
China
ProdList
18729
Advantage
57
Shanghai yirong biology science and technology co., ltd
Tel
18049974220
Fax
+86 (21) 51062076
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3060526242@qq.com
Country
China
ProdList
995
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60
Shanghai Aladdin Bio-Chem Technology Co.,LTD
Tel
400-6206333 13167063860
Fax
021-50323701
Email
anhua.mao@aladdin-e.com
Country
China
ProdList
25003
Advantage
65
Bide Pharmatech Ltd.
Tel
400-164-7117 13681763483
Fax
+86-21-61629029
Email
product02@bidepharm.com
Country
China
ProdList
42446
Advantage
60
Porse Fine Chemical Co.,LTD
Tel
20-66003216 18666003216
Fax
+86-20-28069063
Email
info@porsefinechemical.com
Country
China
ProdList
1941
Advantage
62
ShangHai KenEn Chemical Technology Co., Ltd.
Tel
13120367189
Fax
021-50315529
Email
mychess007@163.com
Country
China
ProdList
1994
Advantage
55
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View Lastest Price from 2,2'-OXYDIANILINE manufacturers

Chemwill Asia Co.,Ltd.
Product
2,2'-OXYDIANILINE in stock Factory 24878-25-9
Price
US $1.00/KG
Min. Order
1KG
Purity
TOP 3 Factory in China
Supply Ability
Top 3 largest production capacity Factory
Release date
2019-04-03

24878-25-9, 2,2'-OXYDIANILINERelated Search:


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