2,2'-OXYDIANILINE
- Product Name
- 2,2'-OXYDIANILINE
- CAS No.
- 24878-25-9
- Chemical Name
- 2,2'-OXYDIANILINE
- Synonyms
- 2,2’-Oxydlaniline;2,2'-Oxydianiline;2-AMINOPHENYL ETHER;Aniline, 2,2'-oxydi-;Olanzapine Impurity 33;Bis(2-aminophenyl) ether;2,2'-Oxybis(benzenamine);2-(2-aminophenoxy)aniline;Benzenamine, 2,2'-oxybis-;2,2'-Diaminodiphenyl ether
- CBNumber
- CB6772545
- Molecular Formula
- C12H12N2O
- Formula Weight
- 200.24
- MOL File
- 24878-25-9.mol
2,2'-OXYDIANILINE Property
- Melting point:
- 61-64 °C(lit.)
- Boiling point:
- 148.5-149.5 °C(Press: 0.3 Torr)
- Density
- 1.216
- storage temp.
- Keep in dark place,Inert atmosphere,Room temperature
- pka
- 4.15±0.10(Predicted)
- form
- Powder
- color
- White to pale brown
- Water Solubility
- Slightly soluble in water.
- InChI
- InChI=1S/C12H12N2O/c13-9-5-1-3-7-11(9)15-12-8-4-2-6-10(12)14/h1-8H,13-14H2
- InChIKey
- GOJFAKBEASOYNM-UHFFFAOYSA-N
- SMILES
- O(C1=CC=CC=C1N)C1=CC=CC=C1N
Safety
- Hazard Codes
- Xi
- Risk Statements
- 36/37/38
- Safety Statements
- 26-27-36/37/39-45
- WGK Germany
- 3
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 470716
- Product name
- 2,2′-Oxydianiline
- Purity
- 98%
- Packaging
- 1g
- Price
- $75
- Updated
- 2023/01/07
- Product number
- O870633
- Product name
- 2,2''-Oxydianiline
- Packaging
- 50mg
- Price
- $60
- Updated
- 2021/12/16
- Product number
- CHM0157206
- Product name
- 2-(2-AMINOPHENOXY)ANILINE
- Purity
- 95.00%
- Packaging
- 1G
- Price
- $721.57
- Updated
- 2021/12/16
- Product number
- CHM0157206
- Product name
- 2-(2-AMINOPHENOXY)ANILINE
- Purity
- 95.00%
- Packaging
- 2.5G
- Price
- $983.88
- Updated
- 2021/12/16
- Product number
- CHM0157206
- Product name
- 2-(2-AMINOPHENOXY)ANILINE
- Purity
- 95.00%
- Packaging
- 5G
- Price
- $1168.42
- Updated
- 2021/12/16
2,2'-OXYDIANILINE Chemical Properties,Usage,Production
Uses
It is catalytic reagent and used in pharmaceutical industry.
Synthesis
2217-65-4
24878-25-9
General procedure for the synthesis of 2,2'-diaminodiphenyl ether from 2,2'-oxo-bis(nitrobenzene): first, an aqueous suspension of iron powder and hydrochloric acid was refluxed under stirring for 25 minutes. Subsequently, the corresponding dinitro compound was added to this hot suspension and the reflux reaction was continued for 24 hours. Upon completion of the reaction, the mixture was cooled to room temperature and hydrolyzed with 20 mL of 2.5 M sodium hydroxide solution. Next, the reaction mixture was extracted with chloroform (20 mL each time, twice). The organic phases were combined, dried with anhydrous sodium sulfate and finally the solvent was evaporated to give the target product 2,2'-diaminodiphenyl ether as a solid.
References
[1] Tetrahedron, 1995, vol. 51, # 2, p. 579 - 590
[2] Polyhedron, 2015, vol. 90, p. 165 - 174
[3] Synthesis, 1996, # 8, p. 930 - 940
[4] Journal of Organic Chemistry, 1994, vol. 59, # 24, p. 7306 - 7315
[5] Zeitschrift fur Anorganische und Allgemeine Chemie, 2015, vol. 641, # 1, p. 128 - 135
2,2'-OXYDIANILINE Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 2,2'-OXYDIANILINE manufacturers
- Product
- 2,2'-OXYDIANILINE in stock Factory 24878-25-9
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- TOP 3 Factory in China
- Supply Ability
- Top 3 largest production capacity Factory
- Release date
- 2019-04-03