2,2'-OXYDIANILINE

Product Name: 2,2'-OXYDIANILINE
CAS No.: 24878-25-9
Chemical Name: 2,2'-OXYDIANILINE
Synonyms: 2,2’-Oxydlaniline;2,2'-Oxydianiline;2-AMINOPHENYL ETHER;Aniline, 2,2'-oxydi-;Olanzapine Impurity 33;Bis(2-aminophenyl) ether;2,2'-Oxybis(benzenamine);2-(2-aminophenoxy)aniline;Benzenamine, 2,2'-oxybis-;2,2'-Diaminodiphenyl ether
CBNumber: CB6772545
Molecular Formula: C12H12N2O
Formula Weight: 200.24
MOL File: 24878-25-9.mol

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2,2'-OXYDIANILINE Property

Melting point:: 61-64 °C(lit.)
Boiling point:: 148.5-149.5 °C(Press: 0.3 Torr)
Density: 1.216
storage temp.: Keep in dark place,Inert atmosphere,Room temperature
pka: 4.15±0.10(Predicted)
form: Powder
color: White to pale brown
Water Solubility: Slightly soluble in water.
InChI: InChI=1S/C12H12N2O/c13-9-5-1-3-7-11(9)15-12-8-4-2-6-10(12)14/h1-8H,13-14H2
InChIKey: GOJFAKBEASOYNM-UHFFFAOYSA-N
SMILES: O(C1=CC=CC=C1N)C1=CC=CC=C1N

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-27-36/37/39-45
WGK Germany: 3
Storage Class: 11 - Combustible Solids
Hazard Classifications: Eye Irrit. 2
Skin Irrit. 2
STOT SE 3

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 470716
Product name: 2,2′-Oxydianiline
Purity: 98%
Packaging: 1g
Price: $75
Updated: 2023/01/07

TRC

Product number: O870633
Product name: 2,2''-Oxydianiline
Packaging: 50mg
Price: $60
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: CHM0157206
Product name: 2-(2-AMINOPHENOXY)ANILINE
Purity: 95.00%
Packaging: 1G
Price: $721.57
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: CHM0157206
Product name: 2-(2-AMINOPHENOXY)ANILINE
Purity: 95.00%
Packaging: 2.5G
Price: $983.88
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: CHM0157206
Product name: 2-(2-AMINOPHENOXY)ANILINE
Purity: 95.00%
Packaging: 5G
Price: $1168.42
Updated: 2021/12/16

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2,2'-OXYDIANILINE Chemical Properties,Usage,Production

Uses

It is catalytic reagent and used in pharmaceutical industry.

Synthesis

2217-65-4

24878-25-9

General procedure for the synthesis of 2,2'-diaminodiphenyl ether from 2,2'-oxo-bis(nitrobenzene): first, an aqueous suspension of iron powder and hydrochloric acid was refluxed under stirring for 25 minutes. Subsequently, the corresponding dinitro compound was added to this hot suspension and the reflux reaction was continued for 24 hours. Upon completion of the reaction, the mixture was cooled to room temperature and hydrolyzed with 20 mL of 2.5 M sodium hydroxide solution. Next, the reaction mixture was extracted with chloroform (20 mL each time, twice). The organic phases were combined, dried with anhydrous sodium sulfate and finally the solvent was evaporated to give the target product 2,2'-diaminodiphenyl ether as a solid.

References

[1] Tetrahedron, 1995, vol. 51, # 2, p. 579 - 590
[2] Polyhedron, 2015, vol. 90, p. 165 - 174
[3] Synthesis, 1996, # 8, p. 930 - 940
[4] Journal of Organic Chemistry, 1994, vol. 59, # 24, p. 7306 - 7315
[5] Zeitschrift fur Anorganische und Allgemeine Chemie, 2015, vol. 641, # 1, p. 128 - 135

2,2'-OXYDIANILINE Preparation Products And Raw materials

Raw materials

Preparation Products

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2,2'-OXYDIANILINE Suppliers

China 67 India 3 Switzerland 2 United Kingdom 3 United States 6 Global 81

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View Lastest Price from 2,2'-OXYDIANILINE manufacturers

Chemwill Asia Co.,Ltd.

Product: 2,2'-OXYDIANILINE in stock Factory 24878-25-9
Price: US $1.00/KG
Min. Order: 1KG
Purity: TOP 3 Factory in China
Supply Ability: Top 3 largest production capacity Factory
Release date: 2019-04-03

24878-25-9, 2,2'-OXYDIANILINERelated Search:

4-(4-fluoro-3-(piperazine-1-carbonyl)benzyl)phthalazin-1(2H)-one PIPERAZINE DIHYDROCHLORIDE 3-((4-Oxo-3,4-dihydrophthalazin-1-yl)methyl)benzoic acid 1,1,3,3-Tetramethylurea 1-Hydroxybenzotriazole Olaparib Impurity 14 5-Bromo-2-fluorobenzonitrile Cyclopropanecarbonyl Chloride 2-Fluoro-5-((4-oxo-3,4-dihydrophthalazin-1-yl)Methyl)benzonitrile 2-Propanone, 1-[4,5-dihydro-2-(4-methyl-1-piperazinyl)-4-thioxo-3H-1,5-benzodiazepin-3-ylidene]- Olaparib Impurity 31 Olaparib Impurity 30 tert-butyl 4-(2-fluoro-5-((4-oxo-3,4-dihydrophthalazin-1-yl)Methyl)benzoyl)piperazine-1-carboxylate 2,2'-Oxybis(nitrobenzene) Olaparib Impurity 25 Olaparib Impurity 15 tert-butyl 4-(cyclopropylcarbonyl)-1-piperazinecarboxylate tert-Butyl 1-piperazinecarboxylate

2-AMINOPHENYL ETHER

2,2'-Oxybis(benzenamine)

Bis(2-aminophenyl) ether

2,2’-Oxydlaniline

2,2′-Oxydianiline,2-Aminophenyl ether

2,2'-Diaminodiphenyl ether

Aniline, 2,2'-oxydi-

2,2'-OXYDIANILINE in stock Factory

Benzenamine, 2,2'-oxybis-

Olanzapine Impurity 33

2-(2-aminophenoxy)aniline

Oxirane, 2-[10-(phenylMethoxy)ethyl]-

2,2'-Oxydianiline

2,2′-Oxydianiline, CAS 24878-25-9

24878-25-9

Building Blocks

Nitrogen Compounds

Organic Building Blocks

Polyamines