Benzyl thiocyanate

Product Name: Benzyl thiocyanate
CAS No.: 3012-37-1
Chemical Name: Benzyl thiocyanate
Synonyms: Troeolin;solvat14;Solvat 14;Tropeolin;Benzylrhodonid;BENZYL RHODANIDE;Benzylthiocyanide;Beazyl thiocyanate;BENZYL THIOCYANATE;a-Thiocyanatotoluene
CBNumber: CB6774554
Molecular Formula: C8H7NS
Formula Weight: 149.21
MOL File: 3012-37-1.mol

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Benzyl thiocyanate Property

Melting point:: 39-41 °C (lit.) 39-41 °C
Boiling point:: 230-235 °C (lit.)
Density: 1.32
refractive index: 1.6000 (estimate)
Flash point:: >230 °F
storage temp.: Store at <= 20°C.
solubility: diethyl ether: soluble0.5g/10 mL, clear to very faintly turbid, colorless to almost colorless
form: Solid
color: Orange-red crystals or solid
Water Solubility: insoluble
Sensitive: Moisture Sensitive
BRN: 1859726
CAS DataBase Reference: 3012-37-1(CAS DataBase Reference)
NIST Chemistry Reference: Thiocyanic acid benzyl ester(3012-37-1)
EPA Substance Registry System: Thiocyanic acid, phenylmethyl ester (3012-37-1)

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Safety

Hazard Codes: Xn
Risk Statements: 20/21/22-32
Safety Statements: 13-36/37-50A
RIDADR: UN 1759 8/PG 2
WGK Germany: 3
RTECS: XK8155000
TSCA: Yes
HazardClass: 6.1
PackingGroup: III
HS Code: 29309070
Toxicity: LDLo ipr-rat: 40 mg/kg ARZNAD 16,870,66ipr-mus LD50:17 mg/kg PCBPBS 2,95,72scu-mus LD50:100 mg/kg JJPAAZ 3,99,54

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H412Harmful to aquatic life with long lasting effects

Precautionary statements

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 13929
Product name: Benzyl thiocyanate
Purity: ≥95.0% (GC)
Packaging: 100g
Price: $63.3
Updated: 2024/03/01

TCI Chemical

Product number: T0198
Product name: Benzyl Thiocyanate
Purity: >99.0%(GC)
Packaging: 25g
Price: $22
Updated: 2024/03/01

TCI Chemical

Product number: T0198
Product name: Benzyl Thiocyanate
Purity: >99.0%(GC)
Packaging: 500g
Price: $170
Updated: 2024/03/01

Alfa Aesar

Product number: B23902
Product name: Benzyl thiocyanate, 98+%
Packaging: 250g
Price: $93.7
Updated: 2021/12/16

TRC

Product number: B315070
Product name: Benzyl Thiocyanate
Packaging: 50g
Price: $1320
Updated: 2021/12/16

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Benzyl thiocyanate Chemical Properties,Usage,Production

Description

Benzyl thiocyanate undergoes regioselective bond dissociation during its electrochemical reduction in acetonitrile at an inert electrode. It is added to stimulate the chlortetracycline biosynthesis during industrial fermentations. It undergoes biotransformation into dibenzyl disulphide by Streptomyces aureofaciens.

Chemical Properties

ALMOST WHITE TO YELLOW CRYSTALS OR CRYST. POWDER

Uses

Benzyl Thiocyanate is found to increase the protein production of Streptomyces aureofaciens. Inhibits methylazoxymethanol acetate-induced intestinal carcinogenesis and reduces unscheduled DNA synthesi s for some genotoxic carcinogens in rats.

Uses

Benzyl thiocyanate was used to study the effects of various dietary compounds on the α-hydroxylation of N-nitrosopyrrolidine in male F344 rats in vitro.

Definition

ChEBI: Benzyl thiocyanate is a member of thiocyanates.

Application

Benzyl thiocyanate was used to study the effects of various dietary compounds on the α-hydroxylation of N-nitrosopyrrolidine in male F344 rats in vitro.

Synthesis Reference(s)

Synthesis, p. 184, 1977
Tetrahedron Letters, 18, p. 4417, 1977 DOI: 10.1016/S0040-4039(01)83524-3

General Description

Benzyl thiocyanate undergoes regioselective bond dissociation during its electrochemical reduction in acetonitrile at an inert electrode. It is added to stimulate the chlortetracycline biosynthesis during industrial fermentations. It undergoes biotransformation into dibenzyl disulphide by Streptomyces aureofaciens.

Hazard

Strong irritant to skin, tissue. Moderate fire hazard.

Safety Profile

Poison by subcutaneous andintraperitoneal routes. Whenheated to decomposition it emits very toxic fumes ofNOx, SOx, and CN??.

Purification Methods

Crystallise the thiocyanate from EtOH or aqueous EtOH. [Beilstein 6 H 460, 6 IV 2680.]

Benzyl thiocyanate Preparation Products And Raw materials

Raw materials

Preparation Products

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Benzyl thiocyanate Suppliers

Austria 1 Belgium 2 Canada 2 China 67 Europe 2 France 1 Germany 8 India 8 Japan 7 South Korea 1 Switzerland 3 The Netherlands 1 United Kingdom 8 United States 23 Global 134

Aladdin Scientific

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View Lastest Price from Benzyl thiocyanate manufacturers

Career Henan Chemical Co

Product: Benzyl thiocyanate 3012-37-1
Price: US $1.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 1kg,5kg,100kg
Release date: 2019-07-04

3012-37-1, Benzyl thiocyanateRelated Search:

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Benzylthiocyanide

Solvat 14

solvat14

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Thiocyanicacid,phenylmethylester

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Tropeolin

LABOTEST-BB LT00053217

Benzyl Thiocyanate, 94+%

2-Thiocyanatotoluene

BENZYL RHODANIDE

BENZYL THIOCYANATE

THIOCYANIC ACID BENZYL ESTER

BENZYL THIOCYANATE 98% MIN

Benzyl Thiocyanate &gt

2-Propen-1-one,1-[(2R,5R)-2-(methoxymethyl)-5-(7H-pyrrolo[2,3-d]pyrimidin-4-ylamino)-1-piperidinyl]-

3012-37-1

C6H5CH2SCN

Building Blocks

Sulfur Compounds

Thiocyanates/Isothiocyanates

Organic Building Blocks