ChemicalBook > CAS DataBase List > 1,4-Bis(4-aminophenoxy)benzene

1,4-Bis(4-aminophenoxy)benzene

Product Name
1,4-Bis(4-aminophenoxy)benzene
CAS No.
3491-12-1
Chemical Name
1,4-Bis(4-aminophenoxy)benzene
Synonyms
TPE-Q;RODA;581437;1,4-Phenylene-di-4-aminophenyl ether;4-[4-(4-aminophenoxy)phenoxy]aniline;APB-134;APB-144;1,4-Bis(4-aminopheno;Bisaminophenoxybenzene;1,4-BIS(4-AMINOPHENOXY)BENZENE
CBNumber
CB6781637
Molecular Formula
C18H16N2O2
Formula Weight
292.33
MOL File
3491-12-1.mol
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1,4-Bis(4-aminophenoxy)benzene Property

Melting point:
173°C
Boiling point:
483.6±40.0 °C(Predicted)
Density 
1.243±0.06 g/cm3(Predicted)
storage temp. 
Keep in dark place,Inert atmosphere,Room temperature
Water Solubility 
Insoluble in water
pka
5.20±0.10(Predicted)
InChI
InChI=1S/C18H16N2O2/c19-13-1-5-15(6-2-13)21-17-9-11-18(12-10-17)22-16-7-3-14(20)4-8-16/h1-12H,19-20H2
InChIKey
JCRRFJIVUPSNTA-UHFFFAOYSA-N
SMILES
C1(OC2=CC=C(N)C=C2)=CC=C(OC2=CC=C(N)C=C2)C=C1
CAS DataBase Reference
3491-12-1(CAS DataBase Reference)
NIST Chemistry Reference
Aniline, p,p'-(p-phenylenedioxy)di-(3491-12-1)
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Safety

Risk Statements 
20/21/22-36/37/38
Safety Statements 
26-36/37/39
RTECS 
BY8237000
HS Code 
29222990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
S140112
Product name
4-[4-(4-AMINOPHENOXY)PHENOXY]PHENYLAMINE
Purity
AldrichCPR
Packaging
50MG
Price
$30.7
Updated
2025/07/31
Sigma-Aldrich
Product number
S227366
Product name
4-[4-(4-AMINOPHENOXY)PHENOXY]PHENYLAMINE
Purity
AldrichCPR
Packaging
5MG
Price
$28.6
Updated
2023/06/20
TCI Chemical
Product number
B1243
Product name
1,4-Bis(4-aminophenoxy)benzene
Purity
>98.0%(GC)(T)
Packaging
5g
Price
$35
Updated
2025/07/31
TCI Chemical
Product number
B1243
Product name
1,4-Bis(4-aminophenoxy)benzene
Purity
>98.0%(GC)(T)
Packaging
25g
Price
$105
Updated
2025/07/31
TRC
Product number
P319998
Product name
4,4-(p-Phenylenedioxy)dianiline
Packaging
2.5g
Price
$75
Updated
2021/12/16
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1,4-Bis(4-aminophenoxy)benzene Chemical Properties,Usage,Production

Uses

1,4-bis(4-aminophenoxy)benzene be used for preparation polyimide and epoxy resin material.

Synthesis

20638-32-8

3491-12-1

GENERAL METHODS: A mixture of compounds 1b, 2b or 3b (1.8 g, 5.1 mmol) with 10% Pd/C (0.2 g) in methanol (70 mL) was stirred overnight at room temperature in a hydrogen atmosphere. Upon completion of the reaction, the reaction mixture was treated by diafiltration, followed by addition of water (50 mL) to the filtrate and extraction with dichloromethane three times (50 mL each). The organic layers were combined, washed with brine, dried over anhydrous sodium sulfate and subsequently concentrated under vacuum. The crude product was purified by column chromatography to afford the target products 1c-3c as brown solids in 56.0%, 55.0% and 69.0% yields, respectively.

References

[1] RSC Advances, 2016, vol. 6, # 87, p. 84284 - 84293
[2] RSC Advances, 2014, vol. 4, # 16, p. 7959 - 7966
[3] Dyes and Pigments, 2015, vol. 121, p. 170 - 177
[4] Annali di Chimica (Rome, Italy), 1959, vol. 49, p. 985,992,994
[5] Arzneimittel-Forschung, 1965, vol. 15, # 6, p. 604 - 608

1,4-Bis(4-aminophenoxy)benzene Preparation Products And Raw materials

Raw materials

Preparation Products

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1,4-Bis(4-aminophenoxy)benzene Suppliers

Americas 1 China 184 Europe 1 Germany 4 India 2 Japan 2 United Kingdom 5 United States 8 Global 207
WeylChem GmbH
Tel
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Fax
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Country
Germany
ProdList
396
Advantage
64
PARAGOS
Tel
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Fax
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Email
info@paragos.com
Country
Germany
ProdList
6371
Advantage
39
Service Chemical Inc.
Tel
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Fax
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Email
sales@chemos-group.com
Country
Germany
ProdList
6350
Advantage
71
ABCR GmbH & CO. KG
Tel
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Fax
--
Email
info@abcr.de
Country
Germany
ProdList
6831
Advantage
75
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View Lastest Price from 1,4-Bis(4-aminophenoxy)benzene manufacturers

CHINATECH(TIANJIN) CHEMICAL CO.,LTD.
Product
1,4-Bis(4-aminophenoxy)benzene (TPE-Q) 3491-12-1
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
≥99%
Supply Ability
30MT
Release date
2025-10-27
ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
Product
1,4-Bis(4-aminophenoxy)benzene 3491-12-1
Price
US $2.20-8.80/kg
Min. Order
1kg
Purity
99%min
Supply Ability
1000kg
Release date
2025-09-09
HANGZHOU HAILAN CHEMICAL CO.,LTD.
Product
1,4-Bis(4-aminophenoxy)benzene 3491-12-1
Price
US $0.00/kg
Min. Order
1kg
Purity
99%min
Supply Ability
20tons
Release date
2025-09-05

3491-12-1, 1,4-Bis(4-aminophenoxy)benzeneRelated Search:

4-Aminobenzoic acid Sulfanilamide Sulfanilic acid p-Anisidine Xylene 4-Aminophenylacetic acid Aniline Benzene 1,4-Bis(4-amino-2-trifluoromethylphenoxy)benzene Anthranilic acid 1,3-Bis(4-aMinophenoxy)benzene 4,4'-(HEXAFLUOROISOPROPYLIDENE)BIS[(4-AMINOPHENOXY)BENZENE] 1,3-Bis(3-aminophenoxy)benzene 1,4-BIS(3-AMINOPHENOXY)BENZENE 1,4-Bis(4-aminophenoxy)benzene AKOS BBS-00005242 AKOS BBS-00005189 AKOS BBS-00005158

  • 1,4-Phenylene-di-4-aminophenyl ether
  • 1,4-phenylene-di-4-aminophenylether
  • 4,4’-(1,4-phenlenebis(oxy))bis-benzenamin
  • 4-[4-(4-Aminophenoxy)phenoxy]phenylamine
  • Benzenamine,4,4'-[1,4-phenylenebis(oxy)]bis-
  • p,p’-(p-phenylenedioxy)di-anilin
  • RODA
  • TPE-Q
  • 4,4'-(P-PHENYLENEDIOXY)DIANILINE
  • 1,4-BIS(4-AMINOPHENOXY)BENZENE
  • HYDROQUINONE BIS(4-AMINOPHENYL) ETHER
  • APB-134
  • APB-144
  • Aniline, p,p'-(p-phenylenedioxy)di-
  • Bisaminophenoxybenzene
  • 1,4-BIS(4-AMINOPHENOXY)BENZENE(144BAPB)
  • 1,4-Bis(4-aMinophenoxy)benzene(TPE-Q)
  • 4-[4-(4-aminophenoxy)phenoxy]aniline
  • 4-[4-(4-azanylphenoxy)phenoxy]aniline
  • 1,4-Bis(4-aminopheno
  • 4,4'-(1,4-Phenylenedioxy)dianiline
  • 1,4-Bis(p-aminophenoxy)benzene
  • 4,4'-(1,4-Phenylene)bis(oxy)bisaniline
  • 4,4'-(4,1-Phenylene)bis(oxy)bis(benzenamine)
  • 4,4'-(p-Phenylenebisoxy)dianiline
  • 4,4'-(p-Phenylenedioxy)bisaniline
  • Hydroquinone bis(p-aminophenyl) ether
  • 1,4-Bis(4-aminophenoxyl) benzene (TPE-Q)
  • 581437
  • 1,4-Bis(4-aminophenoxy)benzene ISO 9001：2015 REACH
  • 1,4-Bis( 4-Aminophenoxy)benzene(TPE-Q/1,4,4-APB)
  • 4,4′-[1,4-Phenylenebis(oxy)]bis[benzenamine]
  • 3491-12-1
  • 3491-12-3
  • Diphenyl Ethers (for High-Performance Polymer Research)
  • Reagent for High-Performance Polymer Research
  • Diphenyl Ethers (for High-Performance Polymer Research)
  • Functional Materials
  • Reagent for High-Performance Polymer Research