ChemicalBook > CAS DataBase List > 1,3-Bis(4-aMinophenoxy)benzene

1,3-Bis(4-aMinophenoxy)benzene

Product Name
1,3-Bis(4-aMinophenoxy)benzene
CAS No.
2479-46-1
Chemical Name
1,3-Bis(4-aMinophenoxy)benzene
Synonyms
TPE-R;1,3,4-APB;7FDA;4,4'-(m-Phenyle;RESORCINOLDIANILINE;4,4'-(1,3-Phenylened;resorcinoloxydianiline;4,4-(1,3-PHENEDIOXY)DIANILINE;1,3-BIS(4-AMINOPHENOXY)BENZENE;1,3-Bis(4'-Amino-phenoxyl)benz
CBNumber
CB5687981
Molecular Formula
C18H16N2O2
Formula Weight
292.33
MOL File
2479-46-1.mol
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1,3-Bis(4-aMinophenoxy)benzene Property

Melting point:
115-118 °C(lit.)
Boiling point:
434.27°C (rough estimate)
Density 
1.1925 (rough estimate)
refractive index 
1.5700 (estimate)
storage temp. 
Keep in dark place,Inert atmosphere,Room temperature
solubility 
very faint turbidity in Acetonitrile
form 
powder to crystal
pka
5.06±0.10(Predicted)
color 
White to Brown
InChI
InChI=1S/C18H16N2O2/c19-13-4-8-15(9-5-13)21-17-2-1-3-18(12-17)22-16-10-6-14(20)7-11-16/h1-12H,19-20H2
InChIKey
WUPRYUDHUFLKFL-UHFFFAOYSA-N
SMILES
C1(OC2=CC=C(N)C=C2)=CC=CC(OC2=CC=C(N)C=C2)=C1
CAS DataBase Reference
2479-46-1(CAS DataBase Reference)
EPA Substance Registry System
Benzenamine, 4,4'-[1,3-phenylenebis(oxy)]bis- (2479-46-1)
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Safety

Hazard Codes 
Xn
Risk Statements 
22-36/37/38
Safety Statements 
26-36
WGK Germany 
3
RTECS 
BY8236000
HS Code 
29222990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
476323
Product name
4,4′-(1,3-Phenylenedioxy)dianiline
Purity
98%
Packaging
100g
Price
$394
Updated
2024/03/01
TCI Chemical
Product number
B1680
Product name
1,3-Bis(4-aminophenoxy)benzene
Purity
>98.0%(GC)(T)
Packaging
25g
Price
$89
Updated
2024/03/01
TRC
Product number
B405505
Product name
1,3-Bis(4-aminophenoxy)benzene
Packaging
500mg
Price
$60
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB62666
Product name
1,3-Bis(4-aminophenoxy)benzene
Packaging
100g
Price
$80
Updated
2021/12/16
Frontier Specialty Chemicals
Product number
JK213939
Product name
1,3-Bis(4-aminophenoxy)benzene
Purity
98%
Packaging
25g
Price
$82
Updated
2021/12/16
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1,3-Bis(4-aMinophenoxy)benzene Chemical Properties,Usage,Production

Chemical Properties

Light yellow powder

Uses

1,3-Bis(4'-aminophenoxyl)benzene be used for the preparation of a polyimide material.

Application

1,3-Bis(4-aMinophenoxy)benzene (TPE-R) is a phenyl ether derivative with two anilines in the terminal closure. It has the following applications:
(1) TPE-R with BPDA and BPDA can be used to prepare a series of polyimide oligomer (Oligo-PI) resins with controlled molecular weights through polymerisation reactions. Oligo-PI resins have an asymmetric and amorphous structure, which allows for better processing of composite materials.
(2) TPE-R copolymerised with other monomers (e.g. PEG) for the manufacture of fuel cell membranes with high ionic conductivity (210 mS/cm) and sufficient thermal stability (up to 140 °C).
(3) Polyimide composites prepared from TPE-R and titanate nanotubes can be used for electromagnetic shielding at microwave frequencies.
(4) TPE-R as an aromatic ligand can be crystallised with a variety of transition metals to form 0D, 1D and 2D coordination metal polymers, which can be used for sensing nitroaromatic compounds.
(5) TPE-R reacts with polydimethylsiloxanes with varying degrees of chloromethyl side functionalisation to form sec-amides and undergo cross-linking to form two networks, a siloxane-organic network and a silica network.

Toxicity evaluation

orl-mus LD50:1240 mg/kg; orl-rat LD50:1378 mg/kg; ora-rat LD50:690 mg/kg [pubchem].

1,3-Bis(4-aMinophenoxy)benzene Preparation Products And Raw materials

Raw materials

Preparation Products

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1,3-Bis(4-aMinophenoxy)benzene Suppliers

CHINATECH(TIANJIN) CHEMICAL CO.,LTD.
Tel
+86-022-83726202 +86-18222493702
Fax
022-83726200
Email
sales@chinatechem.com
Country
China
ProdList
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Hubei Baidu Chemical Co., Ltd
Tel
027-59106051 13627137652
Fax
027-59223020
Email
1438180055@qq.com
Country
China
ProdList
9963
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58
Liling Chuangli Technology Co. LTD
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0534-8101711 13606437406
Fax
0534-8101711
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sales@chuanglichem.com
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China
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Changzhou Sunlight Pharmaceutical Co., Ltd
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519-83131668 15995063688
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+86-519-83138041
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info@sunlightchem.com
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China
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Ningbo Agracechem Technology Co., Ltd.
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0574-87621641 13989375151
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tianze@agracechem.com
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China
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J & K SCIENTIFIC LTD.
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010-82848833 400-666-7788
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86-10-82849933
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jkinfo@jkchemical.com
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China
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Meryer (Shanghai) Chemical Technology Co., Ltd.
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021-61259108 18621169109
Fax
86-21-61259102
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market03@meryer.com
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China
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40228
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TCI (Shanghai) Development Co., Ltd.
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021-67121386
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021-67121385
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Sales-CN@TCIchemicals.com
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China
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24529
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Energy Chemical
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021-021-58432009 400-005-6266
Fax
021-58436166
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sales8178@energy-chemical.com
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China
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44688
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Shanghai Longsheng chemical Co.,Ltd.
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021-58099652-8005 13585536065
Fax
021-58099609
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bin.wu@shlschem.com
Country
China
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View Lastest Price from 1,3-Bis(4-aMinophenoxy)benzene manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD
Product
1,3-Bis(4-aMinophenoxy)benzene 2479-46-1
Price
US $0.00/KG
Min. Order
1KG
Purity
98%min
Supply Ability
30tons/month
Release date
2023-02-24
Shanghai Daken Advanced Materials Co.,Ltd
Product
1,3-Bis(4-aminophenoxy)benzene(TPE-R) 2479-46-1
Price
US $0.00/KG
Min. Order
1KG
Purity
99.00%
Supply Ability
1500KG/month
Release date
2021-11-01
Hebei Weibang Biotechnology Co., Ltd
Product
1,3-Bis(4-aMinophenoxy)benzene 2479-46-1
Price
US $30.00-10.00/KG
Min. Order
50KG
Purity
99%
Supply Ability
500000kg
Release date
2024-10-24

2479-46-1, 1,3-Bis(4-aMinophenoxy)benzeneRelated Search:


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  • Benzenamine, 4,4'-[1,3-phenylenebis(oxy)]bis-
  • 4,4'-[1,3-phenylenebis(oxy)]dianiline
  • 4,4'-(m-Phenylenebisoxy)bis(aniline)
  • 4,4'-(m-Phenylenebisoxy)dianiline
  • 4,4'-(m-Phenylenedioxy)bisaniline
  • RESORCINOL BIS(4-AMINOPHENYL) ETHER
  • TPE-R
  • 1,3-BIS(4-AMINOPHENOXY)BENZENE
  • 1,3-BIS(4'-AMINOPHENOXYL)BENZENE
  • 1,3,4-APB
  • 1,3-Bis(4-aminophenoxy)benzene (TPE-R).
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  • RESORCINOLDIANILINE
  • 4,4'-(M-PHENYLENEDIOXY)DIANILINE
  • 4,4'-(1,3-PHENYLENEDIOXY)DIANILINE
  • 4,4'-(m-Phenyle
  • 1,3'-Bis(4-aminophenoxyl)benzene (1,3,4-APB,TPE-R)
  • 1,3-Bis(4-aminophenoxy)benzene ,99%
  • 4,4'-(1,3-Phenylened
  • 1,3-Bis(4-AMinophenoxy) Benzene (TPE-R) 4,4'-(1,3-Phenylenedioxy) Dianiline
  • 4,4'-(1,3-Phenylenedioxy)dianiline 98%
  • 1,3'-Bis(4-aminophenoxyl)benzene (TPE-R)
  • 1,3-phenylene-di-4-aminophenylether
  • 4,4’-(1,3-phenylenebis(oxy))bis-benzenamin
  • p,p’-(m-phenylenedioxy)di-anilin
  • resorcinoloxydianiline
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  • 1,3-Bis(4-aminophenoxy)benzene &gt
  • 7FDA
  • 1,3-Bis(4-aminophenoxy)benzene(TPE-R) CAS
  • 1,3'-Bis(4-aminophenoxyl)benzene
  • 1,3-bis(4'-Aminophenoxyl)benzene
  • 4,4'-(1,3-phenylenedioxy)dianiline
  • 1,3-bis(4'-aminophenoxy)benzene
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  • 1,3-Bis( 4-aminophenoxy)benzene (TPE-R/1,3,4-APB)
  • 2479-46-1
  • 2427-46-1
  • C6H4OC6H4NH22
  • C18H16N2O2
  • C18H16O2N2
  • Diphenyl Ethers (for High-Performance Polymer Research)
  • Reagent for High-Performance Polymer Research
  • Amine Monomers
  • Monomers
  • Primary Amines
  • Electronic Chemicals
  • Miscellaneous
  • Diphenyl Ethers (for High-Performance Polymer Research)
  • Functional Materials
  • Reagent for High-Performance Polymer Research
  • 2479-46-1