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Isobutyl vinyl ether

Product Name
Isobutyl vinyl ether
CAS No.
109-53-5
Chemical Name
Isobutyl vinyl ether
Synonyms
IVE;vinoflexmo400*;isobutoxyethene;Lutanol LR 8500;Vinoflex MO 400;isobutoxy-ethene;1-Isobutoxyethene;Isobutyl vinyl eth;ether,isobutylvinyl;1-Isobutoxyethylene
CBNumber
CB6852780
Molecular Formula
C6H12O
Formula Weight
100.16
MOL File
109-53-5.mol
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Isobutyl vinyl ether Property

Melting point:
-112 °C
Boiling point:
83 °C
Density 
0.769
vapor density 
3.45 (vs air)
vapor pressure 
68 mm Hg ( 20 °C)
refractive index 
n20/D 1.395(lit.)
Flash point:
8 °F
storage temp. 
Flammables area
form 
clear liquid
color 
Colorless to Almost colorless
Water Solubility 
0.7 g/L (25 ºC)
BRN 
1560159
Dielectric constant
3.3399999999999999
LogP
3.07 at 25℃
CAS DataBase Reference
109-53-5(CAS DataBase Reference)
NIST Chemistry Reference
Vinylisobutyl ether(109-53-5)
EPA Substance Registry System
Propane, 1-(ethenyloxy)-2-methyl- (109-53-5)
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Safety

Hazard Codes 
F,Xi
Risk Statements 
11-38-52/53
Safety Statements 
16-23-24/25-33-37-61
RIDADR 
UN 1304 3/PG 2
WGK Germany 
1
RTECS 
KO1300000
9
TSCA 
TSCA listed
HazardClass 
3.1
PackingGroup 
II
HS Code 
29091990
Toxicity
rabbit,LD50,skin,20mL/kg (20mL/kg),American Industrial Hygiene Association Journal. Vol. 23, Pg. 95, 1962.
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H225Highly Flammable liquid and vapour

H315Causes skin irritation

H412Harmful to aquatic life with long lasting effects

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P240Ground/bond container and receiving equipment.

P241Use explosion-proof electrical/ventilating/lighting/…/equipment.

P273Avoid release to the environment.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
278351
Product name
Isobutyl vinyl ether
Purity
contains 0.1% potassium hydroxide as stabilizer, 99%
Packaging
250ml
Price
$57.3
Updated
2024/03/01
TCI Chemical
Product number
I0099
Product name
Isobutyl Vinyl Ether (stabilized with KOH)
Purity
>99.0%(GC)
Packaging
25mL
Price
$26
Updated
2024/03/01
TCI Chemical
Product number
I0099
Product name
Isobutyl Vinyl Ether (stabilized with KOH)
Purity
>99.0%(GC)
Packaging
500mL
Price
$86
Updated
2024/03/01
scipoly
Product number
M-207
Product name
Isobutyl vinyl ether
Packaging
100g
Price
$28
Updated
2024/07/03
scipoly
Product number
M-207
Product name
Isobutyl vinyl ether
Packaging
200g
Price
$45
Updated
2024/07/03
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Isobutyl vinyl ether Chemical Properties,Usage,Production

Chemical Properties

Colorless liquid. Very slightly soluble in water; soluble in alcohol and ether; easily polymerized.

Uses

Isobutyl vinyl ether is use in preparation method and formula of bulk polymerized Chloroether resin.

Uses

Polymer and copolymers used in surgical adhesives, coatings, and lacquers; modifier for alkyd and polystyrene resins; plasticizer for nitrocellulose and other plastics; chemical intermediate.

General Description

A clear colorless liquid. Flash point 15°F. May polymerize if contaminated or subjected to heat. If polymerization take place inside a container, the container may violently rupture. Vapors are heavier than air.

Air & Water Reactions

Highly flammable. Less dense than water and very slightly soluble in water. Tends to form explosive peroxides when exposed to air. When ethers containing peroxides are heated (distilled) they can detonate [Lewis, 3rd ed., 1993, p. 728].

Reactivity Profile

Isobutyl vinyl ether is a colorless, moderately toxic liquid, highly flammable. A very dangerous fire hazard when exposed to heat, flame or strong oxidizing agents. Highly explosive in the form of vapor when exposed to open flame or sparks.

Health Hazard

Inhalation or contact with material may irritate or burn skin and eyes. Fire may produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control may cause pollution.

Fire Hazard

HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. May polymerize explosively when heated or involved in a fire. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.

Flammability and Explosibility

Flammable

Synthesis

There are two routes for production of IBVE: one uses acetylene as raw material, the other does not use acetylene as raw material. In industry, acetylene route is mainly used for the production of IBVE. IBVE is produced by vinylation of isobutanol with acetylene in the presence of a catalyst:

Commonly used catalysts for the acetylene process are alkali metal hydroxides (such as NaOH and KOH) and alkali metal alkoxides (such as sodium alkoxide and potassium alkoxide).

Properties and Applications

Isobutyl vinyl ether (IBVE) has a carbon–carbon double bond and is chemically active. It can react with a wide variety of substances to form various derivatives. IBVE is stable to alkalis but readily hydrolyzes to isobutanol and acetaldehyde under acidic conditions. Therefore, it is often stabilized by addition of a small amount of base such as triethanolamine.

Purification Methods

Wash the ether three times with equal volumes of aqueous 1% NaOH, dry with CaH2, reflux it with sodium for several hours, then fractionally distil it from sodium. [Beilstein 1 IV 2054.]

Isobutyl vinyl ether Preparation Products And Raw materials

Raw materials

Preparation Products

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Isobutyl vinyl ether Suppliers

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View Lastest Price from Isobutyl vinyl ether manufacturers

Baoji Guokang Bio-Technology Co., Ltd.
Product
Isobutyl vinyl ether, 98% min. 109-53-5
Price
US $0.00/kg
Min. Order
150kg
Purity
98%
Supply Ability
20tons
Release date
2023-10-30
Hebei Weibang Biotechnology Co., Ltd
Product
Isobutyl vinyl ether 109-53-5
Price
US $10.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10 mt
Release date
2024-11-26
Hebei Yanxi Chemical Co., Ltd.
Product
Isobutyl vinyl ether 109-53-5
Price
US $0.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
20 tons
Release date
2023-11-24

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