ChemicalBook > CAS DataBase List > tert-Butyl nitrite

tert-Butyl nitrite

Product Name
tert-Butyl nitrite
CAS No.
540-80-7
Chemical Name
tert-Butyl nitrite
Synonyms
t-BuNO2;T-BUTYL NITRITE;t-butyl ester;2-Methyl-2-nitrosooxy-propane;ert-buty nitrite;t-Buthyl nitrite;ert-Butylnitrite;Tert-buty nitrite;TERT-BUTYL NITRITE;TIMTEC-BB SBB007659
CBNumber
CB6853772
Molecular Formula
C4H9NO2
Formula Weight
103.12
MOL File
540-80-7.mol
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tert-Butyl nitrite Property

Boiling point:
61-63 °C(lit.)
Density 
0.867 g/mL at 25 °C(lit.)
vapor pressure 
13.466kPa at 25℃
refractive index 
n20/D 1.368(lit.)
Flash point:
−10 °F
storage temp. 
2-8°C
solubility 
alcohol: very soluble(lit.)
form 
Liquid
color 
Clear yellow
Water Solubility 
slightly soluble
Merck 
14,1583
BRN 
1209339
LogP
2.24 at 20℃
CAS DataBase Reference
540-80-7(CAS DataBase Reference)
NIST Chemistry Reference
(CH3)3CONO(540-80-7)
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Safety

Hazard Codes 
F,Xn
Risk Statements 
11-20/22
Safety Statements 
16-24-46
RIDADR 
UN 2351 3/PG 2
WGK Germany 
1
RTECS 
RA0802000
F 
8
HazardClass 
3
PackingGroup 
II
HS Code 
29209085
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H225Highly Flammable liquid and vapour

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P240Ground/bond container and receiving equipment.

P241Use explosion-proof electrical/ventilating/lighting/…/equipment.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
20370
Product name
tert-Butyl nitrite
Purity
technical, ≥90% (GC)
Packaging
100mL
Price
$92
Updated
2024/03/01
Sigma-Aldrich
Product number
20370
Product name
tert-Butyl nitrite
Purity
technical, ≥90% (GC)
Packaging
500mL
Price
$323
Updated
2024/03/01
TCI Chemical
Product number
N0357
Product name
tert-Butyl Nitrite
Purity
>90.0%(GC)
Packaging
25mL
Price
$65
Updated
2024/03/01
TCI Chemical
Product number
N0357
Product name
tert-Butyl Nitrite
Purity
>90.0%(GC)
Packaging
250mL
Price
$392
Updated
2024/03/01
Alfa Aesar
Product number
L16135
Product name
tert-Butyl nitrite
Purity
tech. 90%
Packaging
25g
Price
$35.4
Updated
2023/06/20
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tert-Butyl nitrite Chemical Properties,Usage,Production

Chemical Properties

clear yellow liquid

Uses

tert-Butyl nitrite is employed as a reagent for diazotization and nitrosation of alcohols, thiols, amines and cycloalkanes. It plays an important role in photocatalyzed conversion of aryl and heteroarylamines to selenides. It finds application in the preparation of aryl azides from aryl amines. It is also useful for radical multifunctionalization reactions of aliphatic alkenes and source of nitric oxide.

Uses

Jet propellant.

General Description

tert-Butyl nitrite (TBN) is an efficient NO source. TBN participates in photocatalyzed conversion of aryl- and heteroarylamines to selenides. It also participates in radical multifunctionalization reactions of aliphatic alkenes.

Purification Methods

If it is free from OH bands (IR) then distil it through a 12inch helices packed column under reduced pressure, otherwise wash with aqueous 5% NaHCO3 (effervescence), then H2O, dry (Na2SO4) and fractionate it through a 10 theoretical plates column at ca 10mm pressure. [Allen J Chem Soc 1968 1954, Coe & Doumani J Am Chem Soc 70 1516 1948, UV: Ungnade & Smiley J Org Chem 21 993 1956, IR: Terte Bull Soc Chim Belg 60 240 1951, Beilstein 1 IV 1622.]

tert-Butyl nitrite Preparation Products And Raw materials

Raw materials

Silver nitrate 2-Chloro-2-methylpropane Nitrogen Tetroxide NITRIC OXIDE

Preparation Products

8-Quinolineboronic acid 2-Bromo-5-hydroxypyridine radical ion(1+) 2-Chloro-5-cyano-3-methylpyridine Goserelin 2-CHLORO-5-IODO-3-METHYLPYRIDINE 4,7-DIHYDRO-4-OXO-3H-PYRROLO[2,3-D][1,2,3]TRIAZINE-5-CARBOXAMIDE 2-Bromo-5-fomylthiazole
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View Lastest Price from tert-Butyl nitrite manufacturers

Hebei Yanxi Chemical Co., Ltd.
Product
tert-Butyl nitrite 540-80-7
Price
US $50.00/KG
Min. Order
25KG
Purity
98%
Supply Ability
200 tons
Release date
2020-07-14
airuikechemical co., ltd.
Product
Tert-Butyl nitrite 540-80-7
Price
US $0.00-0.00/Kg
Min. Order
1Kg
Purity
99.99%
Supply Ability
20 tons
Release date
2024-04-10
Hebei Chuanghai Biotechnology Co,.LTD
Product
tert-Butyl nitrite 540-80-7
Price
US $5.00-2.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10000kg
Release date
2024-08-23

540-80-7, tert-Butyl nitriteRelated Search:

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