ChemicalBook > CAS DataBase List > N-Boc-L-homoserine Methyl Ester

N-Boc-L-homoserine Methyl Ester

Product Name
N-Boc-L-homoserine Methyl Ester
CAS No.
120042-11-7
Chemical Name
N-Boc-L-homoserine Methyl Ester
Synonyms
Boc-L-HomoSer-OMe;N-FmocL-homoserinemethylester;Boc-L-Homoserine methyl ester;N-Boc-L-homoserine Methyl Ester;methyl ((benzyloxy)carbonyl)-L-homoserinate;methyl (tert-butoxycarbonyl)-L-homoserinate;N-[(1,1-Dimethylethoxy)carbonyl]-L-homoserine Methyl Ester;tert-butyl (S)-1-(methoxycarbonyl)-3-hydroxypropylcarbamate;L-Homoserine, N-[(1,1-dimethylethoxy)carbonyl]-, methyl ester;methyl (2S)-2-{[(tert-butoxy)carbonyl]amino}-4-hydroxybutanoate
CBNumber
CB71176561
Molecular Formula
C10H19NO5
Formula Weight
233.26
MOL File
120042-11-7.mol
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N-Boc-L-homoserine Methyl Ester Property

Boiling point:
364.6±37.0 °C(Predicted)
Density 
1.125±0.06 g/cm3(Predicted)
storage temp. 
Sealed in dry,Store in freezer, under -20°C
pka
10.91±0.46(Predicted)
Appearance
Colorless to light yellow Viscous Liquid
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC
Product number
B600370
Product name
N-Boc-L-homoserineMethylEster
Packaging
100mg
Price
$100
Updated
2021/12/16
AK Scientific
Product number
3476AA
Product name
(S)-Methyl2-((tert-butoxycarbonyl)amino)-4-hydroxybutanoate
Packaging
1g
Price
$317
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
AAA0000162
Product name
(S)-N-BOC-L-HOMOSERINE METHYL ESTER
Purity
95.00%
Packaging
5MG
Price
$501.78
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
AAA0000162
Product name
(S)-N-BOC-L-HOMOSERINE METHYL ESTER
Purity
95.00%
Packaging
250MG
Price
$580
Updated
2021/12/16
AK Scientific
Product number
3476AA
Product name
(S)-Methyl2-((tert-butoxycarbonyl)amino)-4-hydroxybutanoate
Packaging
5g
Price
$984
Updated
2021/12/16
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N-Boc-L-homoserine Methyl Ester Chemical Properties,Usage,Production

Synthesis

41088-86-2

74-88-4

120042-11-7

To a solution of (S)-2-(tert-butoxycarbonylamino)-4-hydroxybutyric acid 206 (8.5 g, 38 mmol) in DMF (50 mL) was added K2CO3 (5.24 g, 38 mmol) and iodomethane (5.4 g, 38 mmol). The reaction mixture was stirred at room temperature overnight. After the reaction was completed, the reaction mixture was diluted with water (500 mL) and extracted with dichloromethane (500 mL). The organic layers were combined, dried over anhydrous Na2SO4, filtered, and concentrated under reduced pressure to remove the solvent to afford the crude product (S)-2-((tert-butoxycarbonyl)amino)-4-hydroxybutyric acid methyl ester 207 (8.5 g, 90% yield).

References

[1] Patent: WO2017/189866, 2017, A1. Location in patent: Paragraph 0243
[2] Patent: WO2017/156074, 2017, A1. Location in patent: Paragraph 00494
[3] Biochemistry, 2017, vol. 56, # 8, p. 1062 - 1074
[4] Patent: WO2016/112088, 2016, A1. Location in patent: Paragraph 0481

N-Boc-L-homoserine Methyl Ester Preparation Products And Raw materials

Raw materials

Preparation Products

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120042-11-7, N-Boc-L-homoserine Methyl EsterRelated Search:

(S)-N-Boc-L-homoserine Ethyl Ester Boc-Asp-OtBu N-Boc-cis-4-Hydroxy-L-proline methyl ester N-Boc-trans-4-Hydroxy-L-proline methyl ester Boc-L-aspartic acid 1-benzyl ester N-Boc-trans-4-tosyloxy-L-proline methyl ester N-Boc-L-Homoserine BOC-ASP(OTBU)-ONP BOC-ASP(OSU)-OBZL BOC-ASP(OBZL)-ONP BOC-ASP(OBZL)-N-CARBOXYANHYDRIDE (2S,4R)-N-BOC-4-HYDROXYPIPERIDINE-2-CARBOXYLIC ACID METHYL ESTER, 98% E.E., 95 BOC-HYP-OBZL BOC-HYP-OTBU BOC-ASP-OCHEX DCHA BOC-L-ASP(OCHX)-O-CH2-PHI-CH2-COOH BOC-ASP-OME BOC-ASP-OFM

  • methyl (2S)-4-hydroxy-2-[(2-methylpropan-2-yl)oxycarbonylamino]butanoate
  • N-[(1,1-Dimethylethoxy)carbonyl]-L-homoserine Methyl Ester
  • N-Boc-L-homoserine Methyl Ester
  • (S)-2-(tert-Butoxycarbonylamino)-4-hydroxybutyric Acid Methyl Este
  • methyl (2S)-2-{[(tert-butoxy)carbonyl]amino}-4-hydroxybutanoate
  • L-Homoserine, N-[(1,1-dimethylethoxy)carbonyl]-, methyl ester
  • tert-butyl (S)-1-(methoxycarbonyl)-3-hydroxypropylcarbamate
  • Boc-L-Homoserine methyl ester
  • N-FmocL-homoserinemethylester
  • Boc-L-HomoSer-OMe
  • methyl ((benzyloxy)carbonyl)-L-homoserinate
  • (S)-Methyl 2-((tert-butoxycarbonyl)amino)-4-hydroxybutanoate - [M92108]
  • methyl (tert-butoxycarbonyl)-L-homoserinate
  • 120042-11-7