4-Di-p-tolylamino-benzaldehyde
- Product Name
- 4-Di-p-tolylamino-benzaldehyde
- CAS No.
- 42906-19-4
- Chemical Name
- 4-Di-p-tolylamino-benzaldehyde
- Synonyms
- 4-DI-P-TO;4-DI-P-TOLYAMINOBENALDEHYDE;4-dimethylamine benzaldehyde;4-(Di-p-Tlylamino)benzaldehyde;4-(DI-P-TOLYLAMINO)BENZALDEHYDE;(4-(Di-p-tolyamino)benzaldehyde);4-[bis(p-tolyl)amino]benzaldehyde;4-(Di-p-tolylamino)benzaldehyde>4,4'-(Di-p-tolylamino)benzaldehyde ;p-[N,N-Di-p-tolylamino]benzaldehyde
- CBNumber
- CB7140525
- Molecular Formula
- C21H19NO
- Formula Weight
- 301.38
- MOL File
- 42906-19-4.mol
4-Di-p-tolylamino-benzaldehyde Property
- Melting point:
- 109 °C
- Boiling point:
- 470.5±45.0 °C(Predicted)
- Density
- 1.138±0.06 g/cm3(Predicted)
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- solubility
- almost transparency in hot Acetonitrile
- form
- powder to crystal
- pka
- -4.76±0.50(Predicted)
- color
- Light yellow to Amber to Dark green
- InChI
- InChI=1S/C21H19NO/c1-16-3-9-19(10-4-16)22(20-11-5-17(2)6-12-20)21-13-7-18(15-23)8-14-21/h3-15H,1-2H3
- InChIKey
- XCGLXUJEPIVZJM-UHFFFAOYSA-N
- SMILES
- C(=O)C1=CC=C(N(C2=CC=C(C)C=C2)C2=CC=C(C)C=C2)C=C1
- CAS DataBase Reference
- 42906-19-4(CAS DataBase Reference)
- EPA Substance Registry System
- Benzaldehyde, 4-[bis(4-methylphenyl)amino]- (42906-19-4)
Safety
- HS Code
- 2922.39.4500
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- D2737
- Product name
- 4-(Di-p-tolylamino)benzaldehyde
- Purity
- >98.0%(HPLC)
- Packaging
- 1g
- Price
- $44
- Updated
- 2025/07/31
- Product number
- D2737
- Product name
- 4-(Di-p-tolylamino)benzaldehyde
- Purity
- >98.0%(HPLC)
- Packaging
- 5g
- Price
- $176
- Updated
- 2025/07/31
- Product number
- D494785
- Product name
- 4-(Di-p-tolyl-amino)-benzaldehyde
- Packaging
- 10mg
- Price
- $45
- Updated
- 2021/12/16
- Product number
- FD34003
- Product name
- 4-(Di-p-tolylamino)benzaldehyde
- Packaging
- 500mg
- Price
- $50
- Updated
- 2021/12/16
- Product number
- X4693
- Product name
- 4-(Di-p-tolylamino)benzaldehyde
- Packaging
- 1g
- Price
- $85
- Updated
- 2021/12/16
4-Di-p-tolylamino-benzaldehyde Chemical Properties,Usage,Production
Chemical Properties
Light yellow - yellow-green powder
Synthesis
20440-95-3
68-12-2
42906-19-4
N,N-dimethylformamide (2.74 g, 37.5 mmol) was slowly added dropwise to a mixed system of 4,4'-dimethyltriphenylamine (2.27 g, 18.8 mmol) and phosphorus trichloride (5.65 g, 22.5 mmol) at 25 °C. The reaction mixture was continuously stirred and heated at 130 °C for 6 hours. Upon completion of the reaction, the system was cooled to room temperature and subsequently poured into 50 mL of cold water and extracted with chloroform (3 x 15 mL). The organic phases were combined, dried with anhydrous magnesium sulfate and filtered. Purification by recrystallization from dilute ethanol afforded the target product 4-di-p-tolylaminobenzaldehyde (R2-CHO). Yield: 1.75 g (31.5% yield). The melting point of the product was 96.3-97.5 °C. Electrospray ionization mass spectrometry (ESI-MS) showed the molecular ion peak ([M + H]+) m/z was 302.4.
References
[1] Chemical Communications, 2014, vol. 50, # 52, p. 6869 - 6871
[2] Dyes and Pigments, 2011, vol. 88, # 3, p. 333 - 343
[3] Tetrahedron, 2003, vol. 59, # 25, p. 4673 - 4685
[4] Dyes and Pigments, 2014, vol. 108, p. 32 - 40
[5] Journal of Chemical Crystallography, 2000, vol. 30, # 11, p. 749 - 753
4-Di-p-tolylamino-benzaldehyde Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 4-Di-p-tolylamino-benzaldehyde manufacturers
- Product
- 4-Di-p-tolylamino-benzaldehyde 42906-19-4
- Price
- US $188.00-1.00/KG
- Min. Order
- 1KG
- Purity
- 99%, 99.5% Sublimated
- Supply Ability
- g-kg-tons, free sample is available
- Release date
- 2024-01-05
- Product
- 4-Di-p-tolylamino-benzaldehyde 42906-19-4
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-07-10
- Product
- 4-Di-p-tolylamino-benzaldehyde 42906-19-4
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-07-09