ChemicalBook > CAS DataBase List > Chlorotriphenyltin

Chlorotriphenyltin

Product Name
Chlorotriphenyltin
CAS No.
639-58-7
Chemical Name
Chlorotriphenyltin
Synonyms
TPTC;gc8993;ls4442;GC 8993;Aquatin;hoe2872;LS 4442;Tinmate;SKL1129;HOE 2872
CBNumber
CB7143511
Molecular Formula
C18H15ClSn
Formula Weight
385.47
MOL File
639-58-7.mol
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Chlorotriphenyltin Property

Melting point:
108 °C (dec.)(lit.)
Boiling point:
240 °C13.5 mm Hg(lit.)
Density 
1.49 g/cm3 (20℃)
vapor pressure 
<0.02 hPa (20 °C)
Flash point:
70°C
storage temp. 
APPROX 4°C
solubility 
0.04g/l
form 
Powder
color 
white
Water Solubility 
insoluble
Sensitive 
Moisture Sensitive
Hydrolytic Sensitivity
7: reacts slowly with moisture/water
BRN 
524762
Exposure limits
ACGIH: TWA 0.1 mg/m3; STEL 0.2 mg/m3 (Skin)
NIOSH: IDLH 25 mg/m3; TWA 0.1 mg/m3
Stability:
Very Moisture Sensitive
CAS DataBase Reference
639-58-7(CAS DataBase Reference)
NIST Chemistry Reference
Chlorotriphenyl tin(639-58-7)
EPA Substance Registry System
Triphenyltin chloride (639-58-7)
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Safety

Hazard Codes 
T,N,C
Risk Statements 
23/24/25-50/53-34
Safety Statements 
26-27-28-45-60-61-28A-36/37/39
RIDADR 
UN 3146 6.1/PG 3
WGK Germany 
3
RTECS 
WH6860000
Autoignition Temperature
>250 °C
TSCA 
Yes
HazardClass 
6.1
PackingGroup 
III
HS Code 
29310095
Hazardous Substances Data
639-58-7(Hazardous Substances Data)
Toxicity
LD50 orally in Rabbit: 135 mg/kg
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H315Causes skin irritation

H318Causes serious eye damage

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
45492
Product name
Fentin chloride
Purity
PESTANAL
Packaging
250mg
Price
$50
Updated
2022/05/15
Sigma-Aldrich
Product number
8.08395
Product name
Triphenyltin chloride for synthesis. CAS 639-58-7, EC Number 211-358-4, chemical formula (C H ) SnCl., for synthesis
Packaging
8083950100
Price
$81.4
Updated
2021/12/16
TCI Chemical
Product number
T0447
Product name
Triphenyltin Chloride
Packaging
5G
Price
$53
Updated
2024/03/01
Alfa Aesar
Product number
L14289
Product name
Triphenyltin chloride, 95%
Packaging
25g
Price
$36.2
Updated
2023/06/20
Alfa Aesar
Product number
L14289
Product name
Triphenyltin chloride, 95%
Packaging
100g
Price
$67.2
Updated
2023/06/20
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Chlorotriphenyltin Chemical Properties,Usage,Production

Uses

Triphenyltin chloride is an important organic intermediate. It is used in agrochemical, pharmaceutical and dyestuff field.

Uses

Chlorotriphenylstannane is used in the synthesis of nanoparticles which bear triamide ligands.

Definition

ChEBI: An organotin compound that is triphenylstannane in which the hydrogen attached to tin is replaced by a chloro group. A fungicide used to control blights on potatoes, leaf spot diseases on sugar beet and anthracnose on beans.

General Description

White crystalline solid, insoluble in water; soluble in organic solvents. Used as a rodent repellent, molluscicide, fungicide and insecticide.

Air & Water Reactions

Hydrolyzes to hydroxide in water.

Reactivity Profile

Chlorotriphenyltin is in the family of tin compounds widely used as stabilizers for plastics, additives to paint(as antifouling agents). Some have catalytic properties. Examples include butyl tin, dibutyl tin oxide. Their main hazard is associated with their high toxicity, in skin adsorption or inhalation.

Health Hazard

Toxic and irritating to the skin. Dermal exposure may lead to severe skin burns as well as renal failure and possible death. (Non-Specific -- Tin Compounds, Organic) Target organs affected are central nervous system, eyes, liver, urinary tract, skin and the blood.

Fire Hazard

When heated to decomposition, Chlorotriphenyltin emits toxic fumes of chlorides. Hydrolyzes to hydroxide in water. Stable when stored in dark with dry air.

Safety Profile

Poison by ingestion, intraperitoneal, and intravenous routes. Experimental reproductive effects. Mutation data reported. An insect chemosterilant. See also TIN COMPOUNDS. When heated to decomposition it emits toxic fumes of Cl-.

Purification Methods

Purify it by distillation, followed by recrystallisation from MeOH by adding pet ether (b 30-60o), m 105-106o [Kozeschow et al. Chem Ber 67 1348 1934], or by crystallisation from Et2O, or 5 parts of EtOH and a small volume of pet ether. [Krause Chem Ber 51 914 1918.] It sublimes in a vacuum. [Beilstein 16 H 914, 16 I 540, 16 II 625, 16 III 1240, 16 IV 1606.] HIGHLY TOXIC.

Chlorotriphenyltin Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Chlorotriphenyltin manufacturers

Henan Fengda Chemical Co., Ltd
Product
Chlorotriphenyltin 639-58-7
Price
US $50.00-1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2023-12-22
Career Henan Chemical Co
Product
Chlorotriphenyltin 639-58-7
Price
US $8.00/KG
Min. Order
1KG
Purity
>98% HPLC
Supply Ability
20 tons
Release date
2020-02-17

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