ChemicalBook > CAS DataBase List > 5-BROMO-2-HYDROXY-3-PICOLINE

5-BROMO-2-HYDROXY-3-PICOLINE

Product Name
5-BROMO-2-HYDROXY-3-PICOLINE
CAS No.
89488-30-2
Chemical Name
5-BROMO-2-HYDROXY-3-PICOLINE
Synonyms
5-Bromo-2-hydroxy-3-methyL;5-BROMO-3-METHYL-2-PYRIDONE;2-Hydorxy-5-Bromo-3-Picoline;2-HYDROXY-5-BROMO-3-PICOLINE;5-BROMO-2-HYDROXY-3-PICOLINE;5-BROMO-3-METHYL-2-PYRIDINOL;5-BROMO-3-METHYL-PYRIDIN-2-OL;5-Bromo-2-hydroxy-3-picoline,98%;5-bromo-3-methyl-1H-pyridin-2-one;5-Bromo-3-methyl-2(1H)-pyridinone
CBNumber
CB7163320
Molecular Formula
C6H6BrNO
Formula Weight
188.02
MOL File
89488-30-2.mol
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5-BROMO-2-HYDROXY-3-PICOLINE Property

Melting point:
170-174 °C(lit.)
Boiling point:
295.1±40.0 °C(Predicted)
Density 
1.5296 (rough estimate)
refractive index 
1.5500 (estimate)
storage temp. 
Inert atmosphere,Room Temperature
solubility 
soluble in Methanol
pka
10.55±0.10(Predicted)
form 
Solid
color 
Off-white
CAS DataBase Reference
89488-30-2(CAS DataBase Reference)
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Safety

Hazard Codes 
Xn,Xi
Risk Statements 
22-38-41-36/37/38
Safety Statements 
36/37/39-36-26
WGK Germany 
3
Hazard Note 
Harmful
HazardClass 
IRRITANT
HS Code 
29337900
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H318Causes serious eye damage

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
636355
Product name
5-Bromo-2-hydroxy-3-methylpyridine
Purity
97%
Packaging
1g
Price
$81.2
Updated
2023/01/07
TCI Chemical
Product number
B2797
Product name
5-Bromo-2-hydroxy-3-methylpyridine
Purity
>98.0%(GC)
Packaging
1g
Price
$16
Updated
2025/07/31
TCI Chemical
Product number
B2797
Product name
5-Bromo-2-hydroxy-3-methylpyridine
Purity
>98.0%(GC)
Packaging
5g
Price
$57
Updated
2025/07/31
TRC
Product number
B696253
Product name
5-Bromo-2-hydroxy-3-picoline
Packaging
100mg
Price
$45
Updated
2021/12/16
TRC
Product number
B696253
Product name
5-Bromo-2-hydroxy-3-picoline
Packaging
250mg
Price
$55
Updated
2021/12/16
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5-BROMO-2-HYDROXY-3-PICOLINE Chemical Properties,Usage,Production

Chemical Properties

creamish to light brown crystalline powder

Uses

5-Bromo-3-methylpyridin-2(1H)-one is a biochemical reagent that can be used as a biological material or organic compound for life science related research.

Synthesis

3430-21-5

89488-30-2

The general procedure for the synthesis of 5-bromo-3-methylpyridin-2-one from 2-amino-3-methyl-5-bromopyridine is as follows: Example 1. 1A. To a solution of 2.6 M H2SO4 (70 mL) of 2-amino-5-bromo-3-methylpyridine (5.0 g, 26.7 mmol) was added dropwise an aqueous solution (10 mL) of sodium 2-nitrite (5.0 g, 72.5 mmol) at 0 °C. 1B. The reaction mixture was slowly warmed to room temperature and stirring was continued for 1.5 hours. 1C. Upon completion of the reaction, the mixture was filtered and the resulting solid was washed with cold water. 1D. The washed solid was dissolved in dichloromethane (100 mL), dried by adding anhydrous magnesium sulfate, and the solvent was subsequently concentrated to give 5-bromo-3-methylpyridin-2-one (4.2 g, 84% yield). MS (DCI/NH3) m/z: 188/190 (M+H)+.

References

[1] Patent: US2002/19388, 2002, A1
[2] Patent: EP1428824, 2004, A1. Location in patent: Page 49
[3] Patent: WO2008/67644, 2008, A1. Location in patent: Page/Page column 39

5-BROMO-2-HYDROXY-3-PICOLINE Preparation Products And Raw materials

Raw materials

Preparation Products

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5-BROMO-2-HYDROXY-3-PICOLINE Suppliers

J & K SCIENTIFIC LTD.
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18210857532; 18210857532
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86-10-82849933
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jkinfo@jkchemical.com
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China
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Meryer (Shanghai) Chemical Technology Co., Ltd.
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86-21-61259102
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market03@meryer.com
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China
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TCI (Shanghai) Development Co., Ltd.
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021-67121386
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021-67121385
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Sales-CN@TCIchemicals.com
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China
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ShangHai DEMO Chemical Co.,Ltd
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400-021-7337 2355568890
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Beijing Ouhe Technology Co., Ltd
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JinYan Chemicals(ShangHai) Co.,Ltd.
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View Lastest Price from 5-BROMO-2-HYDROXY-3-PICOLINE manufacturers

Shaanxi Dideu New Materials Co. Ltd
Product
5-BROMO-2-HYDROXY-3-PICOLINE 89488-30-2
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
98.0%
Supply Ability
10000KGS
Release date
2025-05-30
Henan Fengda Chemical Co., Ltd
Product
5-BROMO-2-HYDROXY-3-PICOLINE 89488-30-2
Price
US $5.00-0.10/KG
Min. Order
1KG
Purity
98%
Supply Ability
g-kg-tons, free sample is available
Release date
2024-04-09
Dideu Industries Group Limited
Product
5-BROMO-2-HYDROXY-3-PICOLINE 89488-30-2
Price
US $1.10/g
Min. Order
1g
Purity
99.00%
Supply Ability
100 Tons Min
Release date
2021-09-24

89488-30-2, 5-BROMO-2-HYDROXY-3-PICOLINERelated Search:


  • 5-BROMO-3-METHYL-PYRIDIN-2-OL
  • 5-BROMO-3-METHYL-2-PYRIDINOL
  • 5-BROMO-3-METHYL-2-PYRIDONE
  • 5-BROMO-2-HYDROXY-3-METHYLPYRIDINE
  • 5-BROMO-2-HYDROXY-3-PICOLINE
  • 2-HYDROXY-5-BROMO-3-PICOLINE
  • 5-BROMO-2-HYDROXY-3-PICOLINE (5-BROMO-2-HYDROXY-3-METHYLPYRIDINE)
  • 2-Hydorxy-5-Bromo-3-Picoline
  • 5-bromo-3-methyl-1H-pyridin-2-one
  • JR-8303, 5-Bromo-2-hydroxy-3-methylpyridine, 97%
  • 5-Bromo-2-hydroxy-3-picoline 5-Bromo-3-methyl-2-pyridinol 5-Bromo-3-methyl-2-pyridone
  • 2-Hydroxy-5-bromo-3-methylpyridine
  • 5-Bromo-2-hydroxy-3-picoline,98%
  • 5-Bromo-3-methyl-2(1H)-pyridinone
  • 5-BroMo-3-Methylpyridin-2(1H)-one
  • 5-Bromo-2-hydroxy-3-picoline, 5-Bromo-3-methylpyridin-2-ol
  • 5-BroMo-2-hydroxy-3-Methylpyridine, 97+%
  • 5-Bromo-2-hydroxy-3-methylpyridine &gt
  • 5-Bromo-2-hydroxy-3-methyL
  • 2(1H)-Pyridinone, 5-bromo-3-methyl-
  • 5-BROMO-2-HYDROXY-3-PICOLINE ISO 9001:2015 REACH
  • 89488-30-2
  • Pyridines
  • Halogenated Heterocycles
  • Heterocyclic Building Blocks
  • Building Blocks
  • Halopyridines
  • Bromopyridines
  • Halides
  • Pyridines
  • Bromopyridines
  • Halopyridines
  • C6Heterocyclic Building Blocks
  • Halogenated Heterocycles
  • Heterocyclic Building Blocks
  • Pyridine