5-BROMO-2-HYDROXY-4-METHYLPYRIDINE

Product Name: 5-BROMO-2-HYDROXY-4-METHYLPYRIDINE
CAS No.: 164513-38-6
Chemical Name: 5-BROMO-2-HYDROXY-4-METHYLPYRIDINE
Synonyms: CAS:164513-38-6;5-Bromo-2-hydroxy-4-methyL;5-Bromo-4-methyl-2-pyridone;5-BROMO-4-METHYLPYRIDIN-2-OL;5-BROMO-2-HYDROXY-4-PICOLINE;2-HYDROXY-5-BROMO-4-PICOLINE;5-BROMO-4-METHYL-2-PYRIDINOL;5-Bromo-2-hydroxy-4-picoline,97%;5-bromo-4-methylpyridin-2(1H)-one;5-BROMO-4-METHYL-2(1H)-PYRIDINONE
CBNumber: CB7254464
Molecular Formula: C6H6BrNO
Formula Weight: 188.02
MOL File: 164513-38-6.mol

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5-BROMO-2-HYDROXY-4-METHYLPYRIDINE Property

Melting point:: 198-202 °C (lit.)
Boiling point:: 291.8±40.0 °C(Predicted)
Density: 1.5296 (rough estimate)
refractive index: 1.5500 (estimate)
storage temp.: Keep in dark place,Inert atmosphere,Room temperature
form: Solid
pka: 9.99±0.10(Predicted)
color: Off-white
Water Solubility: Slightly soluble in water.
CAS DataBase Reference: 164513-38-6(CAS DataBase Reference)

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Safety

Hazard Codes: Xn,Xi
Risk Statements: 22-37/38-41
Safety Statements: 26
WGK Germany: 3
Hazard Note: Harmful
HazardClass: IRRITANT
HS Code: 2933399990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H318Causes serious eye damage

H335May cause respiratory irritation

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 636363
Product name: 5-Bromo-2-hydroxy-4-methylpyridine
Purity: 97%
Packaging: 1g
Price: $72.4
Updated: 2023/06/20

TCI Chemical

Product number: B4701
Product name: 5-Bromo-2-hydroxy-4-methylpyridine
Purity: >98.0%(GC)(T)
Packaging: 5g
Price: $88
Updated: 2025/07/31

TCI Chemical

Product number: B4701
Product name: 5-Bromo-2-hydroxy-4-methylpyridine
Purity: >98.0%(GC)(T)
Packaging: 25g
Price: $351
Updated: 2025/07/31

TRC

Product number: B697618
Product name: 5-Bromo-4-methyl-2(1H)-pyridinone
Packaging: 500mg
Price: $65
Updated: 2021/12/16

TRC

Product number: B697618
Product name: 5-Bromo-4-methyl-2(1H)-pyridinone
Packaging: 100mg
Price: $45
Updated: 2021/12/16

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5-BROMO-2-HYDROXY-4-METHYLPYRIDINE Chemical Properties,Usage,Production

Chemical Properties

light yellow powder

Uses

It is used for medicine.

Synthesis

98198-48-2

164513-38-6

The general procedure for the synthesis of 5-bromo-2-hydroxy-4-methylpyridine using 2-amino-5-bromo-4-methylpyridine as starting material was as follows: an aqueous solution (14 ml) of sodium nitrite (5.44 g, 78.8 mmol) was added slowly and dropwise at 0-5°C to 20% of a 20% solution containing 2-amino-5-bromo-4-methylpyridine (12.83 g, 68.6 mmol) in sulfuric acid solution (69 ml). The reaction mixture was stirred at 0°C for 1 hour and then heated to reflux for 1 hour. Subsequently, the reaction solution was alkalized to pH 10 with 40% sodium hydroxide solution and after cooling to 5°C, the precipitated product was isolated by filtration. The product was recrystallized from ethanol to give 5-bromo-2-hydroxy-4-methylpyridine (5.97 g, 31% yield) as white needle-like crystals (melting point 200°-201°C). NMR hydrogen spectrum (D6-DMSO) δH: 2.17 (3H, single peak, CH3), 6.40 (1H, single peak, 3-H), 7.76 (1H, single peak, 6-H), 11.58 (1H, single peak, NH). Mass spectrum (EI) m/z: 189 (M+, 100%), 187 (M+, 97%). Measured molecular weight: 186.9634 (theoretical molecular weight of C6H6NOBr is 186.9633).

References

[1] Patent: US5536745, 1996, A
[2] Tetrahedron Letters, 1994, vol. 35, # 22, p. 3771 - 3774

5-BROMO-2-HYDROXY-4-METHYLPYRIDINE Preparation Products And Raw materials

Raw materials

Preparation Products

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5-BROMO-2-HYDROXY-4-METHYLPYRIDINE Suppliers

Americas 1 China 181 Europe 1 Germany 1 India 12 Japan 1 Switzerland 1 The Netherlands 1 United Kingdom 6 United States 25 Global 230

J & K SCIENTIFIC LTD.

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View Lastest Price from 5-BROMO-2-HYDROXY-4-METHYLPYRIDINE manufacturers

Shaanxi Dideu New Materials Co. Ltd

Product: 5-BROMO-2-HYDROXY-4-METHYLPYRIDINE 164513-38-6
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 98.0%
Supply Ability: 10000KGS
Release date: 2025-06-03

Henan Fengda Chemical Co., Ltd

Product: 5-BROMO-2-HYDROXY-4-METHYLPYRIDINE 164513-38-6
Price: US $5.00-0.10/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: g-kg-tons, free sample is available
Release date: 2024-04-09

Henan Bao Enluo International TradeCo.，LTD

Product: 5-BROMO-2-HYDROXY-4-METHYLPYRIDINE 164513-38-6
Price: US $10.00/kg
Min. Order: 1kg
Purity: 99.99%
Supply Ability: 50000tons
Release date: 2023-08-09

164513-38-6, 5-BROMO-2-HYDROXY-4-METHYLPYRIDINERelated Search:

3-Bromo-6-hydroxy-2-methylpyridine ,98%,5-Bromo-2-hydroxy-6-methylpyridine 98%,5-BROMO-2-HYDROXY-6-METHYLPYRIDINE,3-BROMO-6-HYDROXY-2-METHYLPYRIDINE 2-Hydroxy-6-methyl-5-nitropyridine 2-Hydroxy-4-methoxybenzaldehyde 2-Hydroxy-4-methyl-5-nitropyridine 2-Hydroxy-4-methyl-3-nitropyridine PHENYL 2-HYDROXY-4,5-DIMETHOXYBENZOATE 2-Hydroxy-6-methylpyridine 2-HYDROXY-4,5-DIMETHOXY BENZOIC ACID 2-Hydroxy-5-nitropyridine 2-Hydroxy-3-trifluoromethylpyridine 2-Chloro-5-hydroxy-3-methylpyridine 5-Bromo-2-methoxy-4-methyl-3-nitropyridine 5-BROMO-4-METHOXYCARBONYL-2(1H)-PYRIDINONE 5-BROMO-2-HYDROXY-4-METHYLPYRIDINE 5-BROMO-2,2'-DIETHOXY-4,5'-BIPYRIDINE 5-BROMO-2-METHOXY-4-METHYLPYRIDINE 2-Bromo-3-hydroxy-6-methylpyridine 3-BROMO-2-HYDROXY-5-PICOLINE (3-BROMO-2-HYDROXY-5-METHYLPYRIDINE),3-Bromo-2-hydroxy-5-methylpyridine 98%,3-BROMO-2-HYDROXY-5-METHYLPYRIDINE

2-HYDROXY-4-METHYL-5-BROMOPYRIDINE

5-BROMO-2-HYDROXY-4-METHYLPYRIDINE

5-BROMO-2-HYDROXY-4-PICOLINE

5-BROMO-4-METHYLPYRIDIN-2-OL

5-BROMO-4-METHYL-2(1H)-PYRIDINONE

5-BROMO-4-METHYL-2-PYRIDINOL

5-Bromo-4-methylpyridin-2-ol, 5-Bromo-2-hydroxy-4-picoline

2-HYDROXY-5-BROMO-4-PICOLINE

5-Bromo-2-hydroxy-4-picoline,97%

5-bromo-4-methylpyridin-2(1H)-one

5-Bromo-2-hydroxy-4-methyL

2(1H)-Pyridinone, 5-bromo-4-methyl-

5-Bromo-4-methyl-2-pyridone

5-BROMO-2-HYDROXY-4-METHYLPYRIDINE ISO 9001：2015 REACH

5-bromo-4-methyl-1H-pyridin-2-one

2-hydroxy-5-bromo-4-methylpyridine

5-Bromo-2-hydroxy-4-methylpyridine, 95%

CAS:164513-38-6

164513-38-6

C6H6BrNOc

Heterocycle-Pyridine series

blocks

Bromides

Pyridines

Pyridine