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ChemicalBook > CAS DataBase List > PHENYL 2-HYDROXY-4,5-DIMETHOXYBENZOATE

PHENYL 2-HYDROXY-4,5-DIMETHOXYBENZOATE

Application
Product Name
PHENYL 2-HYDROXY-4,5-DIMETHOXYBENZOATE
CAS No.
877997-98-3
Chemical Name
PHENYL 2-HYDROXY-4,5-DIMETHOXYBENZOATE
Synonyms
Acotiamide Impurity 35;Alcotimide intermediate 2;PHENYL 2-HYDROXY-4,5-DIMETHOXYBENZOATE;Phenyl 2-hydroxy-4,5-dimethyoxybenzoate;Phenyl -2-hydroxy -4,5-dimethyl benzoate;2-Hydroxy-4,5-dimethoxybenzoic acid phenyl ester;Benzoic acid,2-hydroxy-4,5-dimethoxy-,phenyl ester;Ethyl 2-(2-hydroxy-4,5-diMethoxybenzaMido)thiazole-4-carboxylate;Benzoic acid,2-hydroxy-4,5-dimethoxy-,phenyl ester (for Acotiamide);4, 5-dimethoxybenzoic acid, phenyl ester, 2-hydroxy-4, 5-dimethoxybenzoic acid
CBNumber
CB4478258
Molecular Formula
C15H14O5
Formula Weight
274.27
MOL File
Mol file
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PHENYL 2-HYDROXY-4,5-DIMETHOXYBENZOATE Property

Boiling point:
431.2±45.0 °C(Predicted)
Density 
1.250±0.06 g/cm3(Predicted)
storage temp. 
Sealed in dry,Room Temperature
pka
8.83±0.23(Predicted)
Appearance
White to off-white Solid
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC
Product number
P321060
Product name
Phenyl2-Hydroxy-4,5-dimethoxybenzoate
Packaging
50mg
Price
$45
Updated
2021/12/16
AK Scientific
Product number
X5044
Product name
Phenyl2-hydroxy-4,5-dimethoxybenzoate
Packaging
250mg
Price
$73
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CHM0294571
Product name
PHENYL-2-HYDROXY-4,5-DIMETHOXYBENZOATE
Purity
98.00%
Packaging
25G
Price
$1761.38
Updated
2021/12/16
Ambeed
Product number
A1476019
Product name
Phenyl2-hydroxy-4,5-dimethoxybenzoate
Purity
98+%
Packaging
100g
Price
$107
Updated
2021/12/16
Alichem
Product number
877997983
Product name
Phenyl2-hydroxy-4,5-dimethoxybenzoate
Packaging
10g
Price
$161.6
Updated
2021/12/16
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PHENYL 2-HYDROXY-4,5-DIMETHOXYBENZOATE Chemical Properties,Usage,Production

Application

2-Hydroxy-4,5-dimethoxybenzoic acid phenyl ester is an important intermediate in the synthesis of 2-aminothiazole compounds. 2-Aminothiazole compounds are an important class of heterocyclic compounds in organic medicinal chemistry, possessing a wide range of biological activities. They can be used as local anesthetics and have anticonvulsant, antiviral, antibacterial, and insecticidal effects.

Synthesis

101-02-0

5722-93-0

877997-98-3

(1) Toluene (1.5 g), triphenyl phosphite (2.35 g), 2-hydroxy-4,5-dimethoxybenzoic acid (1.5 g) and concentrated sulfuric acid (40.3 μL) were mixed in a reaction flask under argon protection. The reaction mixture was refluxed under stirring conditions for 2.5 hours. After completion of the reaction, it was cooled to room temperature, methanol (5 g) was added and stirring was continued for 30 min. Subsequently, water (2.5 g) was added to the mixture and stirred for another 30 minutes. The precipitated crystals were filtered and dried under reduced pressure to afford phenyl 2-hydroxy-4,5-dimethoxybenzoate (2.0 g) in 96% yield.

References

[1] Patent: WO2006/22252, 2006, A1. Location in patent: Page/Page column 11
[2] Patent: US2013/253222, 2013, A1. Location in patent: Paragraph 0039
[3] Patent: CN105439977, 2016, A. Location in patent: Paragraph 0016

PHENYL 2-HYDROXY-4,5-DIMETHOXYBENZOATE Preparation Products And Raw materials

Raw materials

Preparation Products

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PHENYL 2-HYDROXY-4,5-DIMETHOXYBENZOATE Suppliers

Adamas Reagent, Ltd.
Tel
400-6009262 16621234537
Fax
021-64823266
Email
chenyj@titansci.com
Country
China
ProdList
14101
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59
XiaoGan ShenYuan ChemPharm co,ltd
Tel
15527768836
Email
1791901229@qq.com
Country
China
ProdList
6950
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52
Hunan Hui Bai Shi Biotechnology Co., Ltd.
Tel
0731-85526065 13308475853
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ivy@hnhbsj.com
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China
ProdList
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SHANGHAI YINGRUI CHEMICAL TECHNOLOGY CO.,LTD.
Tel
21-33585366 13311639313
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+86-21-34979012
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sales@shyrchem.com
Country
China
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Shanghai Yonghong Industry Group Chemical technology Co., Ltd.
Tel
86-21-50102722
Fax
86-21-50102722
Country
China
ProdList
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Anhui Dexinjia Biopharm Co., Ltd
Tel
0531-82375892 15553111391
Email
3276840968@qq.com
Country
China
ProdList
301
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Shanghai Run-Biotech Co., Ltd.
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021-57171705 13817537615
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QQ3095748324
Email
sales@run-biotech.com
Country
China
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2339
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Taizhou Tongxin Bio-Tech Co., Ltd
Tel
0523-86818997 18652728585
Email
sales@allyrise.com
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China
ProdList
2965
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Shanghai YuLue Chemical Co., Ltd.
Tel
021-60345187 13671753212
Fax
021-34702061
Email
lzz841106@aliyun.com
Country
China
ProdList
10263
Advantage
55
Nanjing Duolong Bio-tech Co.,Ltd.
Tel
18905173768
Fax
025-83263139
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52513593@qq.com
Country
China
ProdList
2331
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View Lastest Price from PHENYL 2-HYDROXY-4,5-DIMETHOXYBENZOATE manufacturers

Hebei Yanxi Chemical Co., Ltd.
Product
phenyl 2-hydroxy-4,5-dimethoxybenzoate 877997-98-3
Price
US $150.00/Kg/Bag
Min. Order
1Kg/Bag
Purity
≥98%
Supply Ability
5000kg/month
Release date
2023-09-15
Henan Bao Enluo International TradeCo.,LTD
Product
Phenyl2-hydroxy-4,5-dimethoxybenzoate 877997-98-3
Price
US $100.00/kg
Min. Order
25kg
Purity
99%
Supply Ability
500t/month
Release date
2023-05-24
Hebei Mingeng Biotechnology Co., Ltd
Product
Phenyl 2-hydroxy-4,5-dimethoxybenzoate 877997-98-3
Price
US $100.00/KG
Min. Order
10g
Purity
99%
Supply Ability
500kg/month
Release date
2021-12-21

877997-98-3, PHENYL 2-HYDROXY-4,5-DIMETHOXYBENZOATERelated Search:


  • Benzoic acid,2-hydroxy-4,5-dimethoxy-,phenyl ester (for Acotiamide)
  • Benzoic acid,2-hydroxy-4,5-dimethoxy-,phenyl ester
  • Acotiamide Impurity 35
  • Phenyl 2-hydroxy-4,5-dimethyoxybenzoate
  • Ethyl 2-(2-hydroxy-4,5-diMethoxybenzaMido)thiazole-4-carboxylate
  • PHENYL 2-HYDROXY-4,5-DIMETHOXYBENZOATE
  • Phenyl 2-hydroxy-4,5-dimethoxybenzoate Benzoic acid,2-hydroxy-4,5-dimethoxy-,phenyl ester (for Acotiamide)
  • 2-Hydroxy-4,5-dimethoxybenzoic acid phenyl ester
  • 4, 5-dimethoxybenzoic acid, phenyl ester, 2-hydroxy-4, 5-dimethoxybenzoic acid
  • Alcotimide intermediate 2
  • Phenyl -2-hydroxy -4,5-dimethyl benzoate
  • 877997-98-3