(S)-1-(4-FLUOROPHENYL)ETHYLAMINE

Product Name: (S)-1-(4-FLUOROPHENYL)ETHYLAMINE
CAS No.: 66399-30-2
Chemical Name: (S)-1-(4-FLUOROPHENYL)ETHYLAMINE
Synonyms: (S)-1-(4-FLUOROPHENYL)ETHANAMINE;(S)-1-(4-fluorophenyl)ethan-1-amine;S-PF-PEM;(S)-(-)-4-F-phenylethylamine;1(S)-(4-Fluorophenyl)ethylamine;(S)-1-(4-FLUOROPHENYL)ETHYLAMINE;(s)-4-fluoro-à-methylbenzylamine;(S)-α-Methyl-4-fluorobenzylaMine;(S)-4-Fluoro-α-methylbenzylamine;(1S)-1-(4-Fluorophenyl)ethylamine
CBNumber: CB7200810
Molecular Formula: C8H10FN
Formula Weight: 139.17
MOL File: 66399-30-2.mol

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(S)-1-(4-FLUOROPHENYL)ETHYLAMINE Property

Melting point:: -30°C
Boiling point:: 76°C 22mm
Density: 1,03 g/cm³
refractive index: 1.501
Flash point:: 76°C/22mm
storage temp.: under inert gas (nitrogen or Argon) at 2–8 °C
solubility: Miscible with dimethyl sulfoxide.
pka: 8.98±0.10(Predicted)
form: liquid
color: Clear
optical activity: Consistent with structure
Sensitive: Air Sensitive
BRN: 6791614
CAS DataBase Reference: 66399-30-2(CAS DataBase Reference)

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Safety

Hazard Codes: Xi,N,C
Risk Statements: 34-51/53-22
Safety Statements: 26-36/37/39-61-45
RIDADR: 2735
Hazard Note: Irritant
HazardClass: 8
PackingGroup: III
HS Code: 2921490090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H227Combustible liquid

H302Harmful if swallowed

H314Causes severe skin burns and eye damage

H411Toxic to aquatic life with long lasting effects

Precautionary statements

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P310Immediately call a POISON CENTER or doctor/physician.

P405Store locked up.

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N-Bromosuccinimide Price

TCI Chemical

Product number: F1392
Product name: (S)-1-(4-Fluorophenyl)ethan-1-amine
Purity: min. 98.0 %
Packaging: 1G
Price: $72
Updated: 2025/07/31

TCI Chemical

Product number: F1392
Product name: (S)-1-(4-Fluorophenyl)ethan-1-amine
Purity: min. 98.0 %
Packaging: 5G
Price: $216
Updated: 2025/07/31

SynQuest Laboratories

Product number: 3630-3-S4
Product name: (S)-1-(4-Fluorophenyl)ethylamine
Purity: 97%
Packaging: 25g
Price: $345
Updated: 2021/12/16

Apolloscientific

Product number: PC0613
Product name: (1S)-1-(4-Fluorophenyl)ethylamine
Packaging: 5g
Price: $174
Updated: 2021/12/16

SynQuest Laboratories

Product number: 3630-3-S4
Product name: (S)-1-(4-Fluorophenyl)ethylamine
Purity: 97%
Packaging: 5G
Price: $115
Updated: 2021/12/16

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(S)-1-(4-FLUOROPHENYL)ETHYLAMINE Chemical Properties,Usage,Production

Chemical Properties

Colorless transparent liquid

Uses

(S)-(-)-1-(4-Fluorophenyl)ethylamine is used in organic synthesis. It acts as a ligand and form a coordination complex, diacetato-2-O-bis[(S)-1-(4-fluorophenyl)ethylamine-N]palladium(II) by reacting with palladium(II) acetate.

Synthesis

403-42-9

66399-30-2

General procedure for the synthesis of (S)-1-(4-fluorophenyl)ethylamine using 4-fluoroacetophenone as starting material: to a vial containing 4-fluoroacetophenone (0.2 mmol, 1.0 eq.), ammonium formate (HCO2NH4, 37.8 mg, 2 mmol, 10.0 eq.), and Pdα-nanocatalyst (Pd°-AmP-MFC, 2.68 mg. 0.002 mmol, 8 wt%) were added to the vial with methanol (0.3 mL) and the reaction mixture was stirred for the time indicated in Table 4. Upon completion of the reaction, the vials were cooled in an ice bath, followed by the addition of methanol (0.367 mL) and a buffer solution (50 mM HEPES, pH 8.2, 6 mL) containing aminotransferase (ATA) and 2-5 equivalents of sodium pyruvate (1 equivalent = 0.2 mmol, 22 mg). The reaction tubes were placed under light-avoiding conditions and left to stand at room temperature for 24 h with gentle shaking on an orbital oscillator. Upon completion of the reaction, the enantiomeric excess (ee) of the product was determined by high performance liquid chromatography (HPLC) analysis (repeated three times for each sample).

References

[1] Patent: WO2016/96905, 2016, A1. Location in patent: Page/Page column 25
[2] Chemistry Letters, 2004, vol. 33, # 11, p. 1424 - 1425
[3] Journal of Organic Chemistry, 2013, vol. 78, # 11, p. 5314 - 5327
[4] Organic Process Research and Development, 2014, vol. 18, # 6, p. 788 - 792
[5] ACS Catalysis, 2016, vol. 6, # 6, p. 3932 - 3940

(S)-1-(4-FLUOROPHENYL)ETHYLAMINE Preparation Products And Raw materials

Raw materials

Preparation Products

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(S)-1-(4-FLUOROPHENYL)ETHYLAMINE Suppliers

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View Lastest Price from (S)-1-(4-FLUOROPHENYL)ETHYLAMINE manufacturers

Shaanxi Dideu New Materials Co. Ltd

Product: (S)-1-(4-FLUOROPHENYL)ETHYLAMINE 66399-30-2
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 98.0%
Supply Ability: 10000KGS
Release date: 2025-05-16

Career Henan Chemical Co

Product: (S)-1-(4-FLUOROPHENYL)ETHYLAMINE 66399-30-2
Price: US $7.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 1000KG
Release date: 2018-08-15

66399-30-2, (S)-1-(4-FLUOROPHENYL)ETHYLAMINERelated Search:

Lomerizine hydrochloride ALMITRINE (S)-1-(4-FLUOROPHENYL)ETHYLAMINE Lomerizine Carsatrin Flunarizine dihydrochloride Almitrine dimesylate (R)-4-Fluorophenylglycine 4,4'-Difluorobenzhydrylpiperazine Efletirizine Flunarizine 1-(4-Fluorophenyl)-2-methylpropan-2-amine (R)-1-(4-Fluorophenyl)ethylamine (S)-1-(2-Fluorophenyl)ethylamine, ee 98% (+/-)-1-(4-FLUOROPHENYL)ETHYLAMINE,1-(4'-FLUOROPHENYL)ETHYLAMINE,1-(4-FLUOROPHENYL)ETHYLAMINE,1-(P-FLUOROPHENYL)-ETHYLAMINE ,(n)-1-(4-fluorophenyl)ethylamine Benzenemethanamine, 3,4-difluoro-alpha-methyl-, (alphaS)- (9CI) (R)-1-(3-Fluorophenyl)ethylamine (S)-1-(3-Fluorophenyl)ethylamine hydrochloride

(S)-1-(4-FLUOROPHENYL)ETHANAMINE

(S)-(-)-1-(4-FLUOROPHENYL)ETHYLAMINE

(S)-1-(4-FLUOROPHENYL)ETHYLAMINE

S-PF-PEM

(S)-4-Fluoro-alpha-methylbenzylamine

(s)-4-fluoro-à-methylbenzylamine

(S)-(-)-1-(4-Fluorophenyl)ethylamine, ChiPros 99%, ee 99%

Benzenemethanamine, 4-fluoro-α-methyl-, (αS)-

Benzenemethanamine, 4-fluoro-.alpha.-methyl-, (.alpha.S)-

(1S)-1-(4-Fluorophenyl)ethylamine

(S)-1-(4-FLUOROPHENYL)ETHYLAMINE-HCl

(S)-1-(4-Fluorophenyl)ethylaMine hydrochloride

(S)-α-Methyl-4-fluorobenzylaMine

(1S)-1-(4-fluorophenyl)ethan-1-aMine

(S)-4-Fluoro-α-methylbenzylamine

(S)-1-(4-Fluorophenyl)ethylamine hydrochloride, >=95%

(S)-(-)-1-(4-Fluorophenyl)ethylamine, 99%, ee 99+%

(S)-1-(4-fluorophenyl)ethan-1-amine

(1S)-1-(4-fluorophenyl)ethanamine

(S)-(-)-4-F-phenylethylamine

1(S)-(4-Fluorophenyl)ethylamine

66399-30-2