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TERT-BUTYL DIAZOACETATE

Product Name
TERT-BUTYL DIAZOACETATE
CAS No.
35059-50-8
Chemical Name
TERT-BUTYL DIAZOACETATE
Synonyms
Zolpidem Impurity 66;TERT-BUTYL DIAZOACETATE;tert-butyl 2-diazoacetate;tert-ButylDiazoacetate,80%;tert-ButylDiazoacetate,85%;(tert-Butoxycarbonyl)diazoMethane;tert-Butyl diazoacetate solution ;2-Diazo-acetic Acid 1,1-DiMethylethyl Ester;2-Diazoacetic acid tert-butyl ester solution;2-diazonio-1-[(2-methylpropan-2-yl)oxy]ethenolate
CBNumber
CB7229112
Molecular Formula
C6H10N2O2
Formula Weight
142.16
MOL File
35059-50-8.mol
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TERT-BUTYL DIAZOACETATE Property

Boiling point:
51-53 °C/12 mmHg (lit.)
Density 
1.026 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.453(lit.)
Flash point:
110 °F
storage temp. 
2-8°C
solubility 
soluble in Chloroform, Methanol
form 
Oil
color 
Clear Yellow
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Safety

Hazard Codes 
T,F
Risk Statements 
45-10-22-36/37/38-63-67-65-48/20-38-11
Safety Statements 
53-16-23-36/37/39-45-36/37-26-62
RIDADR 
UN 1993 3/PG 3
WGK Germany 
3
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H226Flammable liquid and vapour

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

H350May cause cancer

H361Suspected of damaging fertility or the unborn child

Precautionary statements

P201Obtain special instructions before use.

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P308+P313IF exposed or concerned: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
752169
Product name
tert-Butyl diazoacetate solution
Purity
15% in toluene
Packaging
25ML
Price
$122
Updated
2024/03/01
Sigma-Aldrich
Product number
752169
Product name
tert-Butyl diazoacetate solution
Purity
15% in toluene
Packaging
100ML
Price
$378
Updated
2024/03/01
Sigma-Aldrich
Product number
480754
Product name
tert-Butyl diazoacetate
Packaging
1g
Price
$144
Updated
2024/03/01
TRC
Product number
B691035
Product name
tert-ButylDiazoacetate,85%
Packaging
5g
Price
$260
Updated
2021/12/16
TRC
Product number
B691035
Product name
tert-ButylDiazoacetate,85%
Packaging
10g
Price
$430
Updated
2021/12/16
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TERT-BUTYL DIAZOACETATE Chemical Properties,Usage,Production

Chemical Properties

Yellow Oil

Uses

It is a key starting material in the total synthesis of manzacidin A. It can also be used in the synthesis of diastero- and enantioselective synthesis of 2-vinylcyclopropa[b]indolines from 2-vinylindoles.

Uses

New Diazoacetate Formulations

Uses

An intermediate in the production of Zolpidem metabolites

General Description

tert-Butyl diazoacetate can be used for numerous organic transformations, including cyclopropanation, insertion, and aziridine-forming reactions.

TERT-BUTYL DIAZOACETATE Preparation Products And Raw materials

Raw materials

Preparation Products

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TERT-BUTYL DIAZOACETATE Suppliers

Canada 1 China 53 India 3 Switzerland 1 United States 3 Global 61

35059-50-8, TERT-BUTYL DIAZOACETATERelated Search:

2-[4-(Ethoxycarbonyl)phenyl]-6-methyl-imidazo[1,2-a]pyridine Zolpidem Phenyl-4-carboxylic Acid DIMETHYL-(6-METHYL-2-P-TOLYL-IMIDAZO[1,2-A]PYRIDIN-3-YLMETHYL)-AMINE 6-(Methoxycarbonyl)-2-(4-methylphenyl)imidazo[1,2-a]pyridine-3-acetic Acid, Zolpidem 6-Carboxylic Acid ETHYL DIAZOACETOACETATE Zolpidem Impurity 18 Ethyl diazoacetate 6-Methyl-2-(4-Methylphenyl)-α-oxo-iMidazo[1,2-a]pyridine-3-acetic Acid Ethyl Ester 2-[4-(Ethoxycarbonyl)phenyl]-6-methyl-imidazo[1,2-a]pyridine-3-acetic Acid L-4-(2-Amino-1-hydroxyethyl)-1,2-benzenediol bitartrate Tetrabutylammonium tribromide Tetraethyl orthocarbonate Tetrabutylammonium hexafluorophosphate TETRAETHYL METHYLENEDIPHOSPHONATE Diazolidinyl Urea bis(methoxycarbonyl)methylidene-imino-azanium 6-(Methoxycarbonyl)-2-(4-methylphenyl)imidazo[1,2-a]pyridine

  • TERT-BUTYL DIAZOACETATE
  • (tert-Butoxycarbonyl)diazoMethane
  • 2-Diazo-acetic Acid 1,1-DiMethylethyl Ester
  • tert-butyl 2-diazoacetate
  • tert-ButylDiazoacetate,85%
  • 2-Diazoacetic acid tert-butyl ester solution
  • tert-Butyl diazoacetate solution
  • 2-diazonio-1-[(2-methylpropan-2-yl)oxy]ethenolate
  • Zolpidem Impurity 66
  • tert-ButylDiazoacetate,80%
  • 35059-50-8
  • N2CHCO2CCH33
  • Nitrogen Compounds
  • Organic Building Blocks
  • Building Blocks
  • Azo/Diazo Compounds
  • Azo/Diazo Compounds
  • Nitrogen Compounds
  • Organic Building Blocks
  • Intermediates