2,4-Dimethyl aniline

Product Name: 2,4-Dimethyl aniline
CAS No.: 95-68-1
Chemical Name: 2,4-Dimethyl aniline
Synonyms: 2,4-DIMETHYLANILINE;2,4-XYLIDINE;Benzenamine, 2,4-dimethyl-;M-XYLIDINE;m-4-Xylidine;meta-xylidine;2,4-Xylylamine;2.4-DiMethylan;ASYM-M-XYLIDINE;4-AMINO-M-XYLENE
CBNumber: CB7278882
Molecular Formula: C8H11N
Formula Weight: 121.18
MOL File: 95-68-1.mol

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2,4-Dimethyl aniline Property

Melting point:: 16 °C
Boiling point:: 218 °C(lit.)
Density: 0.98 g/mL at 25 °C(lit.)
vapor density: 4.2 (vs air)
vapor pressure: 0.16 mm Hg ( 25 °C)
refractive index: n20/D 1.558(lit.)
Flash point:: 195 °F
storage temp.: room temp
solubility: 5g/l
form: Liquid
pka: pK1:4.89(+1) (25°C)
color: Clear yellow to red-brown
PH: 7 (22g/l, H2O, 20℃)
Odor: Amine like
explosive limit: 1.1-7.0%(V)
Water Solubility: 5 g/L (20 ºC)
Merck: 14,10084
BRN: 636243
Dielectric constant: 4.9000000000000004
Stability:: Stable. Combustible. Incompatible with strong oxidizing agents, acids, acid anhydrides, acid chlorides, chloroformates, halogens.
LogP: 2.02 at 23℃ and pH8
CAS DataBase Reference: 95-68-1(CAS DataBase Reference)
NIST Chemistry Reference: Benzenamine, 2,4-dimethyl-(95-68-1)
IARC: 3 (Vol. 16, Sup 7) 1987
EPA Substance Registry System: 2,4-Dimethylaniline (95-68-1)

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Safety

Hazard Codes: T,N
Risk Statements: 23/24/25-33-51/53
Safety Statements: 28-36/37-45-61-28A
RIDADR: UN 1711 6.1/PG 2
WGK Germany: 2
RTECS: ZE8925000
F: 8
Autoignition Temperature: 860 °F
TSCA: Yes
HazardClass: 6.1
PackingGroup: II
HS Code: 29214910
Hazardous Substances Data: 95-68-1(Hazardous Substances Data)

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H373May cause damage to organs through prolonged or repeated exposure

H411Toxic to aquatic life with long lasting effects

Precautionary statements

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P314Get medical advice/attention if you feel unwell.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 442315
Product name: 2,4-Dimethylaniline
Purity: analytical standard
Packaging: 1000mg
Price: $27.6
Updated: 2024/03/01

Sigma-Aldrich

Product number: 240915
Product name: 2,4-Dimethylaniline
Purity: ≥99%
Packaging: 50g
Price: $87.7
Updated: 2024/03/01

TCI Chemical

Product number: D0667
Product name: 2,4-Dimethylaniline
Purity: >98.0%(GC)(T)
Packaging: 25mL
Price: $32
Updated: 2024/03/01

TCI Chemical

Product number: D0667
Product name: 2,4-Dimethylaniline
Purity: >98.0%(GC)(T)
Packaging: 500mL
Price: $212
Updated: 2024/03/01

TRC

Product number: X749690
Product name: 2,4-Dimethylaniline(2,4-Xylidine)
Packaging: 10g
Price: $55
Updated: 2021/12/16

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2,4-Dimethyl aniline Chemical Properties,Usage,Production

Chemical Properties

colourless to yellow or dark brown liquid

Uses

2,4-Xylidine, as part of the commercial mixture, has the same uses as xylidine.

Definition

ChEBI: A primary arylamine that is aniline in which the hydrogens at the 2- and 4-positions are replaced by methyl groups. A clear to yellow liquid, it is used in production of certain dyes, pesticides and other chemicals.

General Description

Dark brown liquid.

Air & Water Reactions

2,4-Dimethyl aniline may be sensitive to prolonged exposure to air. Slightly soluble in water.

Reactivity Profile

2,4-Dimethyl aniline ignites on contact with fuming nitric acid . Neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides.

Fire Hazard

2,4-Dimethyl aniline is combustible.

Safety Profile

Suspected carcinogen. Poison by ingestion. Mutation data reported. When heated to decomposition it emits toxic fumes of NOx. See also other xylidine entries.

Metabolic pathway

The major urinary metabolite of 2,4-dimethylaniline (2,4-DMA) in rats is N-acetyl-4-amino-3-methylbenzoic acid, while in dogs, it is 6-hydroxy-2,4-dimethylaniline. Dogs also produce a smaller amount of unacetylated 4-amino-3-methylbenzoic acid and its glycine conjugate. 2,6-Dimethylaniline (2,6-DMA) is metabolized principally to 4-hydroxy-2,6- dimethylaniline in both species, but dogs also produce a significant quantity of 2-amino-3-methylbenzoic acid along with a trace amount of the glycine conjugate of the latter metabolite and 2,6-dimethylnitrosobenzene. Trace levels of an unknown postulated to be 3,5- dimethyl-4-iminoquinone are found in dog urine.

Purification Methods

Convert uns-xylidine to a derivative (see below) which, after recrystallisation, is decomposed with alkali to give the free base. Dry it over KOH and fractionally distil. The acetyl derivative has m 130o, the benzoyl derivative has m 192o, and the picrate has m 209o. [Beilstein 12 H 1111, 12 IV 2545.]

2,4-Dimethyl aniline Preparation Products And Raw materials

Raw materials

4-Nitro-1,3-dimethylbenzene 2,6-Dimethyl-1-nitrobenzene m-Xylene

Preparation Products

AMITRAZ METABOLITE HYDROCHLORIDE SOLVENT YELLOW 85 2,6-Dimethylaniline Solvent Yellow 18 Amitraz

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View Lastest Price from 2,4-Dimethyl aniline manufacturers

Jinan Finer Chemical Co., Ltd

Product: 2,4-Dimethyl aniline 95-68-1
Price: US $0.00/Kg/Drum
Min. Order: 1Kg/Drum
Purity: 99%
Supply Ability: 2000mt/year
Release date: 2021-07-15

Hebei Yanxi Chemical Co., Ltd.

Product: 2,4-Dimethyl aniline 95-68-1
Price: US $0.00-0.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 20 tons
Release date: 2023-08-09

Hebei Yanxi Chemical Co., Ltd.

Product: 2,4-dimethylaniline 95-68-1
Price: US $0.00-0.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 100tons
Release date: 2023-08-10

95-68-1, 2,4-Dimethyl anilineRelated Search:

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TIANFU-CHEM -2,4-Dimethyl aniline

2,4 -XYLIDINE Extra Pure

Amitraz Impurity A

Amitraz EP Impurity A

Vortioxetine Impurity 66

Zeatin Impurity 7

2,4-Dimethylaniline 100 μg/ml Acetonitrile

2,4-Dimethylaniline 100 μg/ml Methanol

C12724500 2,4-Dimethylaniline

L12724500CY 2,4-DimethylanilinE10μg/mLin Cyc

XA12724500AL2,4-DimethylanilinE100μg/mLin Ac