ChemicalBook > CAS DataBase List > 3,4-Dimethoxythiophene

3,4-Dimethoxythiophene

Product Name
3,4-Dimethoxythiophene
CAS No.
51792-34-8
Chemical Name
3,4-Dimethoxythiophene
Synonyms
DMOT;JACS-51792-34-8;AKOS BBS-00006359;,4-diMethoxythiophene;3,4-dimethoxytiophene;3,4-DIMETHOXYTHIOPHENE;Thiophene,3,4-dimethoxy-;3,4- twoMethoxythiophene;3,4-Dimethoxythiophene>3,4-DIMETHOXYTHIOPHENE 98%
CBNumber
CB7291223
Molecular Formula
C6H8O2S
Formula Weight
144.19
MOL File
51792-34-8.mol
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3,4-Dimethoxythiophene Property

Boiling point:
100-102 °C/10-11 mmHg
Density 
1.209 g/mL at 25 °C
refractive index 
1.5409
Flash point:
224 ºF
storage temp. 
-20°C
form 
powder to lump to clear liquid
color 
White or Colorless to Yellow
Water Solubility 
Miscible with organic solvents. Slightly miscible with water.
CAS DataBase Reference
51792-34-8(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi,Xn
Risk Statements 
36/37/38-22
Safety Statements 
26-36/37/39-24/25
WGK Germany 
3
HS Code 
29309090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
668257
Product name
3,4-Dimethoxythiophene
Purity
97%
Packaging
5g
Price
$252
Updated
2025/07/31
TCI Chemical
Product number
D2728
Product name
3,4-Dimethoxythiophene
Purity
>98.0%(GC)
Packaging
1g
Price
$43
Updated
2025/07/31
TCI Chemical
Product number
D2728
Product name
3,4-Dimethoxythiophene
Purity
>98.0%(GC)
Packaging
5g
Price
$137
Updated
2025/07/31
TRC
Product number
D476313
Product name
3,4-Dimethoxythiophene
Packaging
10mg
Price
$45
Updated
2021/12/16
Frontier Specialty Chemicals
Product number
JK348273
Product name
3,4-Dimethoxythiophene
Purity
98%
Packaging
1g
Price
$48
Updated
2021/12/16
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3,4-Dimethoxythiophene Chemical Properties,Usage,Production

Chemical Properties

Colorless to yellow to orange liquid

Uses

3,4-Dimethoxythiophene is used as an electronic materials intermediate. It is used as a starting material in the synthesis of porphyrin dyad which is used to study photoinduced energy transfer.

Uses

Building block in the synthesis of an N2S2-N4 porphyrin dyad used to study photoinduced energy transfer.

Synthesis Reference(s)

Journal of the American Chemical Society, 73, p. 2956, 1951 DOI: 10.1021/ja01150a525

General Description

3,4-Dimethoxythiophene (DMOT) is a monomer and a precursor which can be synthesized by ring closure reaction of 2,3-dimethoxy-1,3-butadiene and sulfur dichloride in hexane medium. It is an oligothiphene that is majorly used in the development of electroactive materials for organic electronics based applications.

Synthesis

3141-26-2

124-41-4

51792-34-8

Under argon protection, 21 g of sodium methanolate and 72 g of methanol were added to a 100 mL four-necked flask (the initial concentration of sodium methanolate in methanol was 22.6 wt%) and stirred until complete dissolution. Subsequently, 0.83 g of cuprous bromide was added as a catalyst and 15 g of 3,4-dibromothiophene was slowly added dropwise, and the reaction solution gradually changed from colorless to black transparent. After the dropwise addition was completed, 50 g of methanol was removed by distillation (at this time the concentration of sodium methanolate in the remaining methanol rose to 48.8 wt%). The reaction mixture was heated to 97 °C for reflux reaction. The levels of 3,4-dibromothiophene and 3-bromo-4-methoxythiophene were monitored by gas chromatography and were below the detection limit after 5 h of reaction. After completion of the reaction, water was added to the mixture, filtered and the crude product was extracted with toluene. The toluene layer was sequentially washed with water and dried over magnesium sulfate. After filtration to remove the desiccant, the toluene layer was concentrated by rotary evaporation and finally vacuum distilled to give 7.28 g of 3,4-dimethoxythiophene in 81.5% yield. The product was analyzed by gas chromatography (Agilent 6890N network GC, FID detector) and the purity was 98.01%.

References

[1] Chinese Chemical Letters, 2014, vol. 25, # 4, p. 517 - 522
[2] Journal of Polymer Science, Part A: Polymer Chemistry, 2014, vol. 52, # 14, p. 1989 - 1999
[3] Patent: KR101558628, 2015, B1. Location in patent: Paragraph 0184-0190
[4] Tetrahedron, 1992, vol. 48, # 17, p. 3633 - 3652
[5] Langmuir, 2014, vol. 30, # 51, p. 15581 - 15589

3,4-Dimethoxythiophene Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from 3,4-Dimethoxythiophene manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD
Product
3,4-Dimethoxythiophene 51792-34-8
Price
US $0.00/KG
Min. Order
1KG
Purity
98%min
Supply Ability
30tons/month
Release date
2023-01-11
Hebei Chuanghai Biotechnology Co., Ltd
Product
3,4-Dimethoxythiophene 51792-34-8
Price
US $10.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
5tons
Release date
2024-12-04
Hebei Zhuanglai Chemical Trading Co Ltd
Product
3,4-Dimethoxythiophene 51792-34-8
Price
US $50.00/kg
Min. Order
1kg
Purity
99
Supply Ability
5000
Release date
2024-11-15

51792-34-8, 3,4-DimethoxythiopheneRelated Search:


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