Reaction
ChemicalBook > CAS DataBase List > (R)-4-(anthracen-9-yl)-3-(t ert-butyl)-2,3-dihydrobenz o[d][1,3]oxaphosphole

(R)-4-(anthracen-9-yl)-3-(t ert-butyl)-2,3-dihydrobenz o[d][1,3]oxaphosphole

Reaction
Product Name
(R)-4-(anthracen-9-yl)-3-(t ert-butyl)-2,3-dihydrobenz o[d][1,3]oxaphosphole
CAS No.
1456816-37-7
Chemical Name
(R)-4-(anthracen-9-yl)-3-(t ert-butyl)-2,3-dihydrobenz o[d][1,3]oxaphosphole
Synonyms
ZJ-0026;(R)-AntPhos;99％ee）[（R）-AntPhos];99% ee) [(R)-AntPhos];(3R)-4-(9-anthryl)-3-tert-butyl-2H-1,3-benzoxaphosphole;(R)-4-(9-Anthracenyl)-3-(tert-butyl)-2,3-dihydro-1,3-benzoxaphosphole;(R)-4-(Anthracen-9-yl)-3-(t-butyl-2,3-dihydrobenzo[d][1,3]oxaphosphole;(R)-4-(anthracen-9-yl)-3-(t ert-butyl)-2,3-dihydrobenz o[d][1,3]oxaphosphole;(R)-4-(Anthracen-9-yl)-3-(t-butyl-2,3-dihydrobenzo[d][1,3]oxaphosphole,98+% (>1,3-Benzoxaphosphole, 4-(9-anthracenyl)-3-(1,1-dimethylethyl)-2,3-dihydro-, (3R)-
CBNumber
CB73340391
Molecular Formula
C25H23OP
Formula Weight
370.42
MOL File
1456816-37-7.mol
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(R)-4-(anthracen-9-yl)-3-(t ert-butyl)-2,3-dihydrobenz o[d][1,3]oxaphosphole Property

Boiling point:
525.7±50.0 °C(Predicted)
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
form 
crystal
color 
light yellow
Sensitive 
air sensitive, store cold
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Safety

HS Code 
2931499090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
913456
Product name
(R)-AntPhos
Purity
≥97%
Packaging
100MG
Price
$106
Updated
2024/03/01
Sigma-Aldrich
Product number
913456
Product name
(R)-AntPhos
Purity
≥97%
Packaging
250MG
Price
$217
Updated
2024/03/01
Strem Chemicals
Product number
15-1963
Product name
(R)-4-(Anthracen-9-yl)-3-(t-butyl-2,3-dihydrobenzo[d][1,3]oxaphosphole,98+% (>99% ee) [(R)-AntPhos]
Packaging
100mg
Price
$77
Updated
2024/03/01
Strem Chemicals
Product number
15-1963
Product name
(R)-4-(Anthracen-9-yl)-3-(t-butyl-2,3-dihydrobenzo[d][1,3]oxaphosphole,98+% (>99% ee) [(R)-AntPhos]
Packaging
500mg
Price
$309
Updated
2024/03/01
Strem Chemicals
Product number
15-1963
Product name
(R)-4-(Anthracen-9-yl)-3-(t-butyl-2,3-dihydrobenzo[d][1,3]oxaphosphole,98+% (>99% ee) [(R)-AntPhos]
Purity
98+% (>99% ee) [(R)-AntPhos]
Packaging
2g
Price
$925
Updated
2024/03/01
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(R)-4-(anthracen-9-yl)-3-(t ert-butyl)-2,3-dihydrobenz o[d][1,3]oxaphosphole Chemical Properties,Usage,Production

Reaction

  1. Ligand/palladium catalyst for general Miyaura borylation reactions.
  2. Ligand/palladium catalyst for general and sterically demanding Suzuki-Miyaura cross-coupling reactions.
  3. Ligand/palladium catalyst for aryl-alkyl Suzuki-Miyaura cross-coupling reactions.
  4. Ligand/nickel catalyst for intramolecular reductive cyclization.
  5. Ligand/palladium catalyst for Dearomative cyclization.

(R)-4-(anthracen-9-yl)-3-(t ert-butyl)-2,3-dihydrobenz o[d][1,3]oxaphosphole Preparation Products And Raw materials

Raw materials

Preparation Products

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(R)-4-(anthracen-9-yl)-3-(t ert-butyl)-2,3-dihydrobenz o[d][1,3]oxaphosphole Suppliers

China 26 United States 2 Global 28
Energy Chemical
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021-021-58432009 400-005-6266
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021-58436166
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sales8178@energy-chemical.com
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China
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Daicel Chiral Technologies (China)CO.,LTD
Tel
021-50460086-9 15921403865
Fax
+86-21-50462321
Email
han_yajun@dctc.daicel.com
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China
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Bide Pharmatech Ltd.
Tel
400-164-7117 13681763483
Fax
+86-21-61629029
Email
product02@bidepharm.com
Country
China
ProdList
41462
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60
LaaJoo
Tel
021-60702684 18516024827
Email
huang.jiayi@sinocompound.com
Country
China
ProdList
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58
Greenherbs Science and Technology Development Co., Ltd.
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010-61136123
Fax
+86 (10) 8857-9127
Email
pub02@greenherbs.com.cn
Country
China
ProdList
4049
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Aikon International Limited
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025-66028182 18112977050
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(3)02557626880
Email
cfzhang@aikonchem.com
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China
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15818
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Rhawn Reagent
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400-400-1332688 18019345275
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400-133-2688
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amy@rhawn.cn
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China
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Henan Alfachem Co.,Ltd.
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0371-0371-55051623 18137891487
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QQ：2853979817
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2853979817@qq.com
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China
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9936
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3A Chemicals
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400-668-9898
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010-51582189
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service@3achem.com
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China
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20557
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Shanghai Anyinuo Biomedical Technology Co., Ltd.
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021-34625901
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420970979@qq.com
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5790
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58

1456816-37-7, (R)-4-(anthracen-9-yl)-3-(t ert-butyl)-2,3-dihydrobenz o[d][1,3]oxaphospholeRelated Search:

(2R,3R)-3-(tert-butyl)-4-(2, 6-dimethoxyphenyl)-2-iso propyl-2,3-dihydrobenzo[d ][1,3]oxaphosphole (2S,3S)-3-(tert-butyl)-4-(2, 6-dimethoxyphenyl)-2-iso propyl-2,3-dihydrobenzo[d ][1,3]oxaphosphole (2R,2'R,3R,3'R)-3,3'-di-tert-butyl-4,4'-bis(2,6-dimethoxyphenyl)-2,2',3,3'-tetrahydro-2,2'-bibenzo[d][1,3]oxaphosphole (2R,3R)-3-(tert-butyl)-4-(2, 6-dimethoxyphenyl)-2-met hyl-2,3-dihydrobenzo[d][1, 3]oxaphosphole (2S,3S)-3-(tert-butyl)-4-(2, 6-dimethoxyphenyl)-2-met hyl-2,3-dihydrobenzo[d][1, 3]oxaphosphole (R)-3-(tert-butyl)-4-(2,6-di methoxyphenyl)-2,3-dihyd robenzo[d][1,3]oxaphosph ole (2R,2'R,3R,3'R)-4,4'-di(ant hracen-9-yl)-3,3'-di-tert-bu tyl-2,2',3,3'-tetrahydro-2,2' -bibenzo[d][1,3]oxaphosp hole 4-(anthracen-9-yl)-3-(tertbutyl)-2,3-dihydrobenzo[d] [1,3]oxaphosphole (2S,2'S,3S,3'S)-4,4'-di(anth racen-9-yl)-3,3'-di-tert-but yl-2,2',3,3'-tetrahydro-2,2'- bibenzo[d][1,3]oxaphosph ole (S)-4-(anthracen-9-yl)-3-(te rt-butyl)-2,3-dihydrobenzo [d][1,3]oxaphosphole (S)-3-(tert-butyl)-4-(2,6-di methoxyphenyl)-2,3-dihyd robenzo[d][1,3]oxaphosph ole

  • (R)-4-(ANTHRACEN-9-YL)-3-(T-BUTYL-2,3-DIHYDROBENZO[D][1,3]OXAPHOSPHOLE,98+%(>99%EE)[(R)-ANTPHOS]
  • (R)-4-(9-Anthracenyl)-3-(tert-butyl)-2,3-dihydro-1,3-benzoxaphosphole
  • (R)-4-(anthracen-9-yl)-3-(t ert-butyl)-2,3-dihydrobenz o[d][1,3]oxaphosphole
  • (R)-AntPhos
  • ZJ-0026
  • 99％ee）[（R）-AntPhos]
  • (R)-4-(Anthracen-9-yl)-3-(t-butyl-2,3-dihydrobenzo[d][1,3]oxaphosphole,98+% (&gt
  • 99% ee) [(R)-AntPhos]
  • 1,3-Benzoxaphosphole, 4-(9-anthracenyl)-3-(1,1-dimethylethyl)-2,3-dihydro-, (3R)-
  • ZJ-0026/(R)-4-(anthracen-9-yl)-3-(t ert-butyl)-2,3-dihydrobenz o[d][1,3]oxaphosphole
  • (R)-4-(Anthracen-9-yl)-3-(t-butyl-2,3-dihydrobenzo[d][1,3]oxaphosphole
  • (3R)-4-(9-anthryl)-3-tert-butyl-2H-1,3-benzoxaphosphole
  • 1456816-37-7
  • Chiral Phosphine