ChemicalBook > CAS DataBase List > DL-tert-Leucine

DL-tert-Leucine

Product Name
DL-tert-Leucine
CAS No.
33105-81-6
Chemical Name
DL-tert-Leucine
Synonyms
L-TLE;D-L-Tle;H-TLE-OH;DL-Tle-OH;T-LEUCINE;H-L-TLE-OH;H-DL-TLE-OH;TBU-GLYCINE;L-T-LEUCINE;tert-leucine
CBNumber
CB7349551
Molecular Formula
C6H13NO2
Formula Weight
131.17
MOL File
33105-81-6.mol
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DL-tert-Leucine Property

Melting point:
>300 °C (lit.)
Boiling point:
242.49°C (rough estimate)
Density 
1.0975 (rough estimate)
refractive index 
1.4240 (estimate)
storage temp. 
Keep in dark place,Inert atmosphere,Room temperature
solubility 
H2O: 0.1 g/mL, clear, colorless
pka
2.39±0.12(Predicted)
form 
Solid
color 
White to off-white
Water Solubility 
soluble
BRN 
1721823
InChI
InChI=1S/C6H13NO2/c1-6(2,3)4(7)5(8)9/h4H,7H2,1-3H3,(H,8,9)
InChIKey
NPDBDJFLKKQMCM-UHFFFAOYSA-N
SMILES
C(O)(=O)C(C(C)(C)C)N
CAS DataBase Reference
33105-81-6(CAS DataBase Reference)
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Safety

Safety Statements 
22-24/25
WGK Germany 
3
HS Code 
29224995
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P321Specific treatment (see … on this label).

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
332178
Product name
DL-tert-Leucine
Purity
98%
Packaging
500mg
Price
$131
Updated
2023/06/20
TCI Chemical
Product number
L0439
Product name
H-DL-Tle-OH
Packaging
5G
Price
$62
Updated
2025/07/31
TCI Chemical
Product number
L0439
Product name
H-DL-Tle-OH
Packaging
25G
Price
$186
Updated
2025/07/31
Usbiological
Product number
290597
Product name
DL-tert-Butylglycine
Packaging
10g
Price
$908
Updated
2021/12/16
TRC
Product number
L330205
Product name
Dl-tert-leucine
Packaging
250mg
Price
$55
Updated
2021/12/16
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DL-tert-Leucine Chemical Properties,Usage,Production

Chemical Properties

white powder

Uses

peptide synthesis

Definition

ChEBI: Tert-butylglycine is a glycine derivative that is glycine with a tertiary butyl group at position 2. It has a role as a metabolite.

reaction suitability

reaction type: solution phase peptide synthesis

Synthesis

26782-71-8

33105-81-6

The general procedure for synthesizing DL-tert-leucine from D-tert-leucine is as follows: Example 3A: A 30% ammonium hydroxide solution (50 mL) was added to the autoclave, followed by D-tert-leucine (5 g). The autoclave was sealed and the mixture was heated to 85°C under stirring conditions and maintained at this temperature for 12 hours of reaction. Upon completion of the reaction, the reaction mixture was cooled and the solution was transferred to a rotary evaporator and concentrated under vacuum at 55 °C. The solid residue obtained after concentration was mixed with acetone (20 mL) with stirring, followed by filtration and drying to finally obtain DL-tert-leucine (4.6 g, 92% yield, of which the L-isomer accounted for 42% and the D-isomer for 58%).

References

[1] Patent: US2012/245379, 2012, A1. Location in patent: Page/Page column 3
[2] Patent: EP2502896, 2012, A1. Location in patent: Page/Page column 4-5

DL-tert-Leucine Preparation Products And Raw materials

Raw materials

Preparation Products

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DL-tert-Leucine Suppliers

Shanxi Bethlehem Pharm-Tech Co.,Ltd.
Tel
19135651983 19135651206
Email
243332738@qq.com
Country
China
ProdList
908
Advantage
58
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
4006356688 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44801
Advantage
61
Wuhan Chemwish Technology Co., Ltd
Tel
86-027-67849912
Fax
86-027-87531808
Email
sales@chemwish.com
Country
China
ProdList
35896
Advantage
56
GL Biochem (Shanghai) Ltd
Tel
21-61263452 13641803416
Fax
86-21-61263399
Email
ymbetter@glbiochem.com
Country
China
ProdList
9981
Advantage
64
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696
Email
info@hanhongsci.com
Country
China
ProdList
42934
Advantage
64
Chemsky (shanghai) International Co.,Ltd
Tel
021-50135380
Email
shchemsky@sina.com
Country
China
ProdList
15402
Advantage
60
Shandong Xiya Chemical Co., Ltd
Tel
4009903999 13355009207
Fax
0539-6365991
Email
3007715519@qq.com
Country
China
ProdList
18729
Advantage
57
Sichuan Kulinan Technology Co., Ltd
Tel
400-1166-196 18981987031
Fax
028-84555506 800101999
Email
cdhxsj@163.com
Country
China
ProdList
11705
Advantage
57
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View Lastest Price from DL-tert-Leucine manufacturers

Career Henan Chemical Co
Product
DL-tert-Leucine 33105-81-6
Price
US $1.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
200kg
Release date
2018-12-24

33105-81-6, DL-tert-LeucineRelated Search:


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