Quinaldine
- Product Name
- Quinaldine
- CAS No.
- 91-63-4
- Chemical Name
- Quinaldine
- Synonyms
- 2-METHYLQUINOLINE;2-Methylchinolin;QuinaL;2-Methylpuinoiline;2-METHYLQUINOLINES;NSC-3397;Quildine;Khinaldin;QUINALDINE;Chinaldine
- CBNumber
- CB7373558
- Molecular Formula
- C10H9N
- Formula Weight
- 143.19
- MOL File
- 91-63-4.mol
Quinaldine Property
- Melting point:
- -2 °C
- Boiling point:
- 248 °C
- Density
- 1.058 g/mL at 25 °C(lit.)
- vapor pressure
- <0.1 hPa (20 °C)
- refractive index
- n20/D 1.612(lit.)
- Flash point:
- 175 °F
- storage temp.
- Store below +30°C.
- solubility
- chloroform: soluble(lit.)
- form
- Crystalline Powder
- pka
- 5.83(at 20℃)
- color
- White to slightly yellow
- PH
- 6.9 (H2O, 20℃)(saturated aqueous solution)
- Water Solubility
- PRACTICALLY INSOLUBLE
- Sensitive
- Light Sensitive
- Merck
- 14,8047
- BRN
- 110309
- Stability:
- Stable, but may be light sensitive. Combustible. Incompatible with strong oxidizing agents.
- LogP
- 2.59
- CAS DataBase Reference
- 91-63-4(CAS DataBase Reference)
- NIST Chemistry Reference
- Quinoline, 2-methyl-(91-63-4)
- EPA Substance Registry System
- Quinaldine (91-63-4)
Safety
- Hazard Codes
- Xn
- Risk Statements
- 21/22-68-36/37/38
- Safety Statements
- 36-45-36/37/39-26
- RIDADR
- NA 1993 / PGIII
- WGK Germany
- 3
- RTECS
- UZ9625000
- F
- 8-23
- TSCA
- Yes
- HS Code
- 29334990
- Toxicity
- LD50 orally in rats: 1.23 g/kg (Smyth)
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H341Suspected of causing genetic defects
H412Harmful to aquatic life with long lasting effects
- Precautionary statements
-
P273Avoid release to the environment.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P308+P313IF exposed or concerned: Get medical advice/attention.
N-Bromosuccinimide Price
- Product number
- 8.05805
- Product name
- Quinaldine
- Purity
- for synthesis
- Packaging
- 100mL
- Price
- $77.2
- Updated
- 2024/03/01
- Product number
- 8.05805
- Product name
- Quinaldine
- Purity
- for synthesis
- Packaging
- 250ML
- Price
- $117
- Updated
- 2024/03/01
- Product number
- 22550
- Product name
- Quinaldine
- Purity
- ≥95.0% (GC)
- Packaging
- 250ML
- Price
- $151
- Updated
- 2024/03/01
- Product number
- 22550
- Product name
- Quinaldine
- Purity
- ≥95.0% (GC)
- Packaging
- 1L
- Price
- $228
- Updated
- 2024/03/01
- Product number
- Q0005
- Product name
- 2-Methylquinoline
- Purity
- >98.0%(GC)(T)
- Packaging
- 25g
- Price
- $24
- Updated
- 2024/03/01
Quinaldine Chemical Properties,Usage,Production
Chemical Properties
Quinaldine or 2-methylquinoline is an organic compound with the formula CH3C9H6N. It is one of the methyl derivative of a heterocyclic compound quinoline. It is bioactive and is used in the preparation of various dyes. It is a colorless oil but commercial samples can appear colored.
Uses
Quinaldine is an anaesthetic used in fish transportation. Also used in anti-malaria drugs, in manufacturing dyes, food colorants , pharmaceuticals and pH indicators.
Uses
It is an anaesthetic used in fish transportation. Used in preparation of oil-soluble dyes. Also used in anti-malaria drugs, in manufacturing dyes, food colorants , pharmaceuticals and pH indicators.
Production Methods
High-temperature coal tar contains an average of 0.2% quinaldine. It is recovered from the quinoline base mixture by rectification and hydration. Quinaldine can be synthesized by the Skraup method from aniline and crotonaldehyde with sulfuric acid in the presence of a dehydrogenating agent.
Definition
ChEBI: A quinoline compound in which the quinoline skeleton is substituted at C-2 with a methyl group.
Synthesis Reference(s)
Journal of Heterocyclic Chemistry, 13, p. 1279, 1976 DOI: 10.1002/jhet.5570130626
The Journal of Organic Chemistry, 52, p. 3847, 1987 DOI: 10.1021/jo00226a023
Synthesis, p. 324, 1996 DOI: 10.1055/s-1996-4221
General Description
A colorless oily liquid darkening to red-brown on exposure to air. Flash point 175°F. Denser than water and slightly soluble in water. Vapors heavier than air. Produces toxic oxides of nitrogen during combustion. Used to make dyes, pharmaceuticals and other chemicals.
Air & Water Reactions
Slightly soluble in water.
Reactivity Profile
Quinaldine neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides. Keep tightly closed and protected from light .
Hazard
Strong irritant to mucous membranes.
Fire Hazard
Quinaldine is probably combustible.
Purification Methods
Dry it with Na2SO4 or by refluxing with BaO, then fractionally distil it under reduced pressure and redistil it from zinc dust. Purify it further by conversion to its phosphate (m 220o) or picrate (m 192o) from which after recrystallisation, the free base is regenerated. [Packer et al. J Am Chem Soc 80 905 1958.] Its ZnCl2 complex can be used for the same purpose. [Beilstein 20 III/IV 3454, 20 V 375.]
Quinaldine Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Quinaldine manufacturers
- Product
- Quinaldine 91-63-4
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 50000KG/month
- Release date
- 2023-08-23
- Product
- 2-Methylquinoline 91-63-4
- Price
- US $5.00-2.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 10000kg
- Release date
- 2023-04-13
- Product
- Quinaldine 91-63-4
- Price
- US $10.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 10 mt
- Release date
- 2021-10-14