ChemicalBook > CAS DataBase List > 5-BROMO-2,2'-BIPYRIDINE

5-BROMO-2,2'-BIPYRIDINE

Product Name
5-BROMO-2,2'-BIPYRIDINE
CAS No.
15862-19-8
Chemical Name
5-BROMO-2,2'-BIPYRIDINE
Synonyms
Abametapir Impurity 13;5-Bromo-2,2'-bipyridyl;-BROMO-2,2'-BIPYRIDINE;5-BROMO-2,2'-BIPYRIDINE;2,2'-Bipyridine,5-broMo-;5-Bromo-[2,2']bipyridinyl;2-(2-Pyridyl)-5-broMopyridine;3-Bromo-6-(2-pyridyl)pyridine;5-Bromo-2,2'-bipyridine, >=97%;5-BROMO-2-(PYRIDIN-2-YL)PYRIDINE
CBNumber
CB7379196
Molecular Formula
C10H7BrN2
Formula Weight
235.08
MOL File
15862-19-8.mol
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5-BROMO-2,2'-BIPYRIDINE Property

Melting point:
73 °C
Boiling point:
322.4±27.0 °C(Predicted)
Density 
1.493±0.06 g/cm3(Predicted)
storage temp. 
Inert atmosphere,Room Temperature
form 
crystalline solid
pka
3.55±0.22(Predicted)
color 
White to faint brown
InChI
InChI=1S/C10H7BrN2/c11-8-4-5-10(13-7-8)9-3-1-2-6-12-9/h1-7H
InChIKey
AWJPULCSDFBFDR-UHFFFAOYSA-N
SMILES
C1(C2=NC=CC=C2)=NC=C(Br)C=C1
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Safety

HS Code 
2933399990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TCI Chemical
Product number
B6181
Product name
5-Bromo-2,2'-bipyridine
Purity
min. 98.0 %
Packaging
1G
Price
$216
Updated
2025/07/31
ChemScene
Product number
CS-W004577
Product name
5-Bromo-2,2'-bipyridine
Purity
99.84%
Packaging
250mg
Price
$57
Updated
2021/12/16
Apolloscientific
Product number
OR50952
Product name
5-Bromo-2,2'-bipyridine
Packaging
250mg
Price
$58
Updated
2021/12/16
SynQuest Laboratories
Product number
3H32-9-FD
Product name
5-Bromo-2,2'-bipyridine
Packaging
250mg
Price
$64
Updated
2021/12/16
ChemScene
Product number
CS-W004577
Product name
5-Bromo-2,2'-bipyridine
Purity
99.84%
Packaging
1g
Price
$133
Updated
2021/12/16
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5-BROMO-2,2'-BIPYRIDINE Chemical Properties,Usage,Production

Chemical Properties

White solid

Synthesis

624-28-2

13737-05-8

15862-19-8

The general procedure for the synthesis of 5-bromo-2,2'-bipyridine from 2,5-dibromopyridine and 2-(trimethylstannyl)pyridine was as follows: 1.91 g (7.89 mmol, 1.0 eq.) of 2-(trimethylstannyl)pyridine and 2.08 g (8.77 mmol, 1.1 eq.) of 2,5-dibromopyridine were dissolved in 16 mL of freshly distilled xylene. The solution was degassed and 0.061 g (0.053 mmol, 0.06 eq.) of Pd(PPh3)4 was added and stirred under reflux conditions for 15 hours. Upon completion of the reaction, 40 mL of 2N NaOH solution was added, followed by three extractions with 40 mL of toluene. The organic phases were combined, washed with brine, dried over anhydrous MgSO4 and concentrated under reduced pressure to remove the solvent. Purification by silica gel column chromatography (SiO2, 3.3 × 10 cm, pentane/EtOAc = 20:1) afforded 2.57 g (63% yield) of 5-bromo-2,2'-bipyridine as a colorless solid.

References

[1] Journal of Organic Chemistry, 2002, vol. 67, # 2, p. 443 - 449
[2] Synlett, 2016, vol. 27, # 7, p. 1056 - 1060
[3] Inorganica Chimica Acta, 2013, vol. 395, p. 145 - 150
[4] Bioorganic and Medicinal Chemistry Letters, 2012, vol. 22, # 4, p. 1670 - 1673

5-BROMO-2,2'-BIPYRIDINE Preparation Products And Raw materials

Raw materials

Preparation Products

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5-BROMO-2,2'-BIPYRIDINE Suppliers

Americas 1 China 142 Europe 1 Germany 1 India 2 Japan 1 Lithuania 1 South Korea 1 Switzerland 3 United States 8 Global 161
TCI AMERICA
Tel
800-4238616
Fax
+1-888-520-1075 / +1-503-283-1987
Email
sales@tciamerica.com
Country
Americas
ProdList
23653
Advantage
75
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View Lastest Price from 5-BROMO-2,2'-BIPYRIDINE manufacturers

Henan Aochuang Chemical Co.,Ltd.
Product
5-BROMO-2,2'-BIPYRIDINE 15862-19-8
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
1ton
Release date
2022-09-27
Shanghai UCHEM Inc.
Product
5-Bromo-2,2'-bipyridine 15862-19-8
Price
US $57.00-252.00/g
Min. Order
1g
Purity
0.98
Supply Ability
10kg
Release date
2024-07-09
Career Henan Chemical Co
Product
5-BROMO-2,2'-BIPYRIDINE 15862-19-8
Price
US $1.00/KG
Min. Order
1G
Purity
99%
Supply Ability
100kg
Release date
2018-08-12

15862-19-8, 5-BROMO-2,2'-BIPYRIDINERelated Search:

2,2'-BipyridiniuM,1,1'-diMethyl-, iodide (1:2) 2,2'-bipyridne-6,6'(1H,1'H)-dione, 1,1'-diMethyl- 4,4'-DIBROMO-2,2'-BIPYRIDINE 2,2'-bipyridine-5,5'-diamine 4-Bromo-2,2''-bipyridine 4'-CHLORO-2,2':6',2''-TERPYRIDINE 2,2'-BIPYRIDINE-5-CARBOXYLIC ACID 2,2'-DIPYRIDYL N,N'-DIOXIDE 2,2':6',2''-TERPYRIDINE-4,4',4''-TRICARBOXYLIC ACID 4,4'-Dimethyl-2,2'-bipyridyl 4‘-(4-hydroxyphenyl)-2, 2':6‘, 2“-terpyridine 1,3,5-Tris(m-iodophenyl)benzene 4'-BROMO-2,2':6',2''-TERPYRIDINE 4-Methyl-4'-(3-carboxypropyl)-2,2'-bipyridine 6-BROMO-2,2'-BIPYRIDINE 5,5'-Dibromo-2,2'-bipyridyl 1,10-Phenanthroline-5,6-dione,3,8-dibromo 5-BROMO-2,2'-BIPYRIDINE

  • 5-BROMO-2,2'-BIPYRIDINE
  • 2-(pyridin-2-yl)-5-bromopyridine
  • 5-Bromo-[2,2']bipyridinyl
  • 2,2'-Bipyridine,5-broMo-
  • 2-(2-Pyridyl)-5-broMopyridine
  • 5-Bromo-2,2'-bipyridine, >=97%
  • 3-Bromo-6-(2-pyridyl)pyridine
  • 5-BROMO-2-(PYRIDIN-2-YL)PYRIDINE
  • -BROMO-2,2'-BIPYRIDINE
  • 5-Bromo-2,2'-bipyridyl
  • Abametapir Impurity 13
  • 15862-19-8