ChemicalBook > CAS DataBase List > METHYL 5-AMINO-1-BENZOTHIOPHENE-2-CARBOXYLATE

METHYL 5-AMINO-1-BENZOTHIOPHENE-2-CARBOXYLATE

Product Name
METHYL 5-AMINO-1-BENZOTHIOPHENE-2-CARBOXYLATE
CAS No.
20699-85-8
Chemical Name
METHYL 5-AMINO-1-BENZOTHIOPHENE-2-CARBOXYLATE
Synonyms
ASISCHEM D48912;ethyl thieno[3,2-f]quinoline-2-carboxylate;ethyl 5-aMinobenzo[b]thiophene-2-carboxylate;METHYL 5-AMINO-1-BENZOTHIOPHENE-2-CARBOXYLATE;methyl 5-aminobenzo[b]thiophene-2-carboxylate;5-Aminothionaphthene-2-carboxylic acid methyl ester;5-AMINO-BENZO[B]THIOPHENE-2-CARBOXYLIC ACID METHYL ESTER;Benzo[b]thiophene-2-carboxylic acid, 5-amino-, methyl ester
CBNumber
CB7389371
Molecular Formula
C10H9NO2S
Formula Weight
207.25
MOL File
20699-85-8.mol
More
Less

METHYL 5-AMINO-1-BENZOTHIOPHENE-2-CARBOXYLATE Property

Melting point:
178-179 ºC
Boiling point:
382.8±22.0 °C(Predicted)
Density 
1.352±0.06 g/cm3(Predicted)
storage temp. 
under inert gas (nitrogen or Argon) at 2–8 °C
pka
3.52±0.10(Predicted)
Appearance
Light yellow to yellow Solid
More
Less

Safety

Hazard Codes 
Xn
Risk Statements 
20/21/22-36/37/38
Safety Statements 
22-26-36/37/39
HS Code 
2934999090
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

More
Less

N-Bromosuccinimide Price

TRC
Product number
M286670
Product name
Methyl5-Aminobenzo[b]thiophene-2-carboxylate
Packaging
100mg
Price
$75
Updated
2021/12/16
AK Scientific
Product number
W4346
Product name
Methyl5-aminobenzo[b]thiophene-2-carboxylate
Packaging
1g
Price
$130
Updated
2021/12/16
Matrix Scientific
Product number
118889
Product name
Methyl 5-aminobenzo[b]thiophene-2-carboxylate
Purity
95+%
Packaging
1g
Price
$216
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CHM0030724
Product name
METHYL 5-AMINO-1-BENZOTHIOPHENE-2-CARBOXYLATE
Purity
95.00%
Packaging
250MG
Price
$629.42
Updated
2021/12/16
Matrix Scientific
Product number
118889
Product name
Methyl 5-aminobenzo[b]thiophene-2-carboxylate
Purity
95+%
Packaging
5g
Price
$720
Updated
2021/12/16
More
Less

METHYL 5-AMINO-1-BENZOTHIOPHENE-2-CARBOXYLATE Chemical Properties,Usage,Production

Definition

ChEBI: Methyl 5-amino-1-benzothiophene-2-carboxylate is a member of 1-benzothiophenes.

Synthesis

20699-86-9

20699-85-8

General procedure for the synthesis of methyl 5-aminobenzothiophene-2-carboxylate from methyl 5-nitrobenzo[b]thiophene-2-carboxylate: to a reaction flask was added methyl 5-nitrobenzo[b]thiophene-2-carboxylate (1 g, 0.004 mol), concentrated nitric acid (20 mL, 0.24 mol) and SnCl2-2H2O (4.85 g, 0.017 mol). The reaction mixture was stirred at 80 °C for 1 h and subsequently cooled to room temperature. The pH of the reaction mixture was adjusted with 10% aqueous sodium hydroxide solution to 9~11. The resulting suspension was filtered and the solid residue was washed with water and methanol sequentially to afford the target product, methyl 5-aminobenzothiophene-2-carboxylate, as a yellow solid in quantitative yield.

References

[1] Patent: WO2006/101454, 2006, A1. Location in patent: Page/Page column 45
[2] Bioorganic and Medicinal Chemistry, 2002, vol. 10, # 5, p. 1611 - 1618
[3] Journal of the American Chemical Society, 2000, vol. 122, # 27, p. 6382 - 6394
[4] ACS Medicinal Chemistry Letters, 2014, vol. 5, # 9, p. 963 - 967
[5] Patent: WO2005/42513, 2005, A1. Location in patent: Page/Page column 57-58

METHYL 5-AMINO-1-BENZOTHIOPHENE-2-CARBOXYLATE Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

METHYL 5-AMINO-1-BENZOTHIOPHENE-2-CARBOXYLATE Suppliers

Belgium 1 China 61 Germany 2 India 1 United States 11 Global 76
J & K SCIENTIFIC LTD.
Tel
18210857532; 18210857532
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
PharmaBlock Sciences (Nanjing),Inc.
Tel
025-86918202 4000255188
Fax
86-025-86918232
Email
sales@pharmablock.com
Country
China
ProdList
5000
Advantage
55
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
4006356688 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
Adamas Reagent, Ltd.
Tel
400-6009262 16621234537
Fax
021-64823266
Email
chenyj@titansci.com
Country
China
ProdList
14101
Advantage
59
Shanghai Longsheng chemical Co.,Ltd.
Tel
021-58099652-8005 13585536065
Fax
021-58099609
Email
bin.wu@shlschem.com
Country
China
ProdList
9883
Advantage
59
China DongFan Chemical Co.,LTD
Tel
86-0571-85151182
Fax
86-0571-85151182
Country
China
ProdList
5691
Advantage
66
Wuhan Luohua Medical Technology Co.,Ltd.
Tel
13477084141; 13477084141
Fax
+86(27)65566697
Email
sales@luohuapharm.com
Country
China
ProdList
468
Advantage
60
Shanghai Sunway Pharmaceutical Technology Co., Ltd
Tel
18270980682
Fax
021 51613951
Email
mlcheng@sunwaypharm.cn
Country
China
ProdList
8669
Advantage
57
Nanjing Vital Chemical Co., Ltd.
Tel
Please Send Email 18652950785
Fax
025-87193546
Email
chemweiao@163.com
Country
China
ProdList
4378
Advantage
65
Thermo Fisher Scientific
Tel
800-810-5118
Fax
+86-10-84193589
Email
cnchemical@thermofisher.com
Country
China
ProdList
17770
Advantage
75
Shanghai potentpharm CO.,Ltd
Tel
13524892556
Fax
(86) 21 51969655， QQ： 263541193
Email
sales-cn@potentpharm.com
Country
China
ProdList
1011
Advantage
55
9ding chemical ( Shanghai) Limited
Tel
4009209199
Fax
86-021-52271987
Email
sales@9dingchem.com
Country
China
ProdList
22514
Advantage
55
Shanghai Raise Chemical Technology Co.,Ltd
Tel
+86-021-50935922
Fax
+86-021-33847795
Country
China
ProdList
7865
Advantage
55
Wuxi Zhangkun Biochemical Technology Co., Ltd.
Tel
+86 0510-85629785
Fax
+86 0510-85625359
Country
China
ProdList
2327
Advantage
58
Bide Pharmatech Ltd.
Tel
400-164-7117 13681763483
Fax
+86-21-61629029
Email
product02@bidepharm.com
Country
China
ProdList
39966
Advantage
60
Shanghai YuLue Chemical Co., Ltd.
Tel
021-60345187 13671753212
Fax
021-34702061
Email
lzz841106@aliyun.com
Country
China
ProdList
10263
Advantage
55
Shanghai RenYue Chemical Technology Co., Ltd.
Tel
021-62219190; 18321139117
Email
316441092@qq.com
Country
China
ProdList
2905
Advantage
55
Shanghai Chenzhu Pharmaceutical Co., Ltd.
Tel
13162380607
Fax
QQ:1696175688
Email
1696175688@qq.com
Country
China
ProdList
817
Advantage
55
Henan CoreyChem Co., Ltd
Tel
0371-86658258
Fax
0371-60996044
Email
info@coreychem.com
Country
China
ProdList
10453
Advantage
58
Shanghai YuanYe Biotechnology Co., Ltd.
Tel
021-61312847; 18021002903
Fax
QQ:3008007432
Email
3008007409@qq.com
Country
China
ProdList
71826
Advantage
60
Amadis Chemical Company Limited
Tel
571-89925085
Fax
0086-571-89925065
Email
sales@amadischem.com
Country
China
ProdList
131957
Advantage
58
Biokitchen
Tel
021-021-021-31663258 13795219287
Fax
021-31663258
Email
donghuanwen@126.com
Country
China
ProdList
8816
Advantage
58
Aikon International Limited
Tel
025-66061636 18013972705
Fax
(3)02557626880
Email
qqyang@aikonchem.com
Country
China
ProdList
15814
Advantage
58
Zhijiang City Zhou Yuan Yao Biological Technology Co., LTD
Tel
15671050515
Fax
-
Email
2267948566@qq.com
Country
China
ProdList
480
Advantage
58
3A Chemicals
Tel
400-668-9898
Fax
010-51582189
Email
service@3achem.com
Country
China
ProdList
20557
Advantage
58
Shanghai Jizhi Biochemical Technology Co. Ltd.
Tel
4009004166/18616739031 18616739031
Email
3007523370@qq.com
Country
China
ProdList
52687
Advantage
58
Shanghai Baoyisheng Biotechnology Co., LTD
Tel
15221020695
Email
502277408@qq.com
Country
China
ProdList
459
Advantage
58
Shanghai Union Medical Technology Co. Ltd.
Tel
13120563767
Fax
15669989863
Email
chemchen925@outlook.com
Country
China
ProdList
987
Advantage
58
Suzhou klaas biotechnology co., LTD
Tel
18616764616
Fax
2330697233
Email
1715037088@qq.com
Country
China
ProdList
357
Advantage
58
Xinyi Kaiwu Chemical Technology Co., Ltd.
Tel
0516-0516-88997009 18651776937
Email
4164357@qq.com
Country
China
ProdList
3204
Advantage
58
Hefei TNJ Chemical Industry Co.,Ltd.
Tel
+86-0551-65418671 +8618949823763
Fax
0551-65418697
Email
sales@tnjchem.com
Country
China
ProdList
34563
Advantage
58
Dayang Chem (Hangzhou) Co.,Ltd.
Tel
+86-0571-88938639 +8617705817739
Fax
+86-571-88938652，+86-571- 88492614
Email
info@dycnchem.com
Country
China
ProdList
52846
Advantage
58
CONIER CHEM AND PHARMA LIMITED
Tel
+8618523575427
Email
sales@conier.com
Country
China
ProdList
49975
Advantage
58
Shanghai Kaiwei Chemical Technology Co., Ltd.
Tel
021-58461859 15821823057
Email
service@aiviche.com
Country
China
ProdList
49312
Advantage
58
career henan chemical co
Tel
+86-0371-86658258 +8613203830695
Fax
0086-371-86658258
Email
factory@coreychem.com
Country
China
ProdList
29798
Advantage
58
Beijing Haite lesk Technology Co., Ltd
Tel
15210893940; 15116916250
Fax
QQ: 237008221
Email
chemistryliu@163.com
Country
China
ProdList
7327
Advantage
58
Changzhou Kechem Bio-Scientific Co., LTD.
Tel
0519-68985668 13685222090
Fax
qq735434464
Email
sales@kechem.cn
Country
China
ProdList
26028
Advantage
58
Zhengzhou Convergence Chemical Co. LTD
Tel
0371-0371-53736046 13393710386
Fax
QQ:2853979814
Email
2853979814@qq.com
Country
China
ProdList
9947
Advantage
58
Energy Chemical
Tel
021-58432009 400-005-6266
Fax
021-58436166
Email
marketing@energy-chemical.com
Country
China
ProdList
44918
Advantage
58
Shanghai Chino Pharmaceutical Technology Co., Ltd
Tel
021-021-51557188 15901710861
Fax
QQ: 569058060
Email
sales@channelpharm.com
Country
China
ProdList
1228
Advantage
58
Beijing Jin Ming Biotechnology Co., Ltd.
Tel
010-60605840 15801484223;
Email
psaitong@jm-bio.com
Country
China
ProdList
29757
Advantage
58
Shanghai Haohong Pharmaceutical Co., Ltd.
Tel
400-8210725 4008210725
Email
malulu@leyan.com
Country
China
ProdList
40000
Advantage
58
Shaanxi DIDU pharmaceutical and Chemical Co., Ltd
Tel
029-029-81120477 17792793610
Email
1033@dideu.com
Country
China
ProdList
9935
Advantage
58
Beijing Solarbio Science & Tecnology Co., Ltd.
Tel
010-50973130 17801761073
Email
Gsiyu@solarbio.com
Country
China
ProdList
50464
Advantage
58
PharmaBlock Sciences (Nanjing), Inc.
Tel
4000255188 13327728092
Email
sales@pharmablock.com
Country
China
ProdList
10000
Advantage
58
Changzhou Qianai Biotechnology Co., Ltd
Tel
051915240519135 13961152745
Email
yudiguimo@126.COM
Country
China
ProdList
10000
Advantage
58
Shanghai Titan Enterprise Development Co., Ltd
Tel
16621224781
Email
syy@titansci.com
Country
China
ProdList
2896
Advantage
58
shanghai huiyu
Tel
15380804498
Email
330062898@qq.com
Country
China
ProdList
241
Advantage
58
Shaoyuan Technology (Shanghai) Co., Ltd.
Tel
021-50795510 4000665055
Email
sy-c6@accelachem.com
Country
China
ProdList
10000
Advantage
58
Shanghai Aladdin Biochemical Technology Co.,Ltd.
Tel
400-6206333 13167063860
Email
anhua.mao@aladdin-e.com
Country
China
ProdList
48457
Advantage
58
More
Less

View Lastest Price from METHYL 5-AMINO-1-BENZOTHIOPHENE-2-CARBOXYLATE manufacturers

Career Henan Chemical Co
Product
METHYL 5-AMINO-1-BENZOTHIOPHENE-2-CARBOXYLATE 20699-85-8
Price
US $1.00/KG
Min. Order
1KG
Purity
98% HPLC
Supply Ability
10 tons
Release date
2020-02-03

20699-85-8, METHYL 5-AMINO-1-BENZOTHIOPHENE-2-CARBOXYLATERelated Search:

1-Benzothiophen-5-amine METHYL THIOPHENE-2-CARBOXYLATE 2-Thiophenecarboxylic acid Thianaphthene-2-carboxylic acid ETHYL 5-AMINO-3-METHYLBENZO[B]THIOPHENE-2-CARBOXYLATE METHYL 3-AMINO-5-NITROBENZO[B]THIOPHENE-2-CARBOXYLATE ETHYL 3-METHYL-5-NITROBENZO[B]THIOPHENE-2-CARBOXYLATE METHYL 5-([(4-BROMOPHENYL)SULFONYL]AMINO)-1-BENZOTHIOPHENE-2-CARBOXYLATE METHYL 5-(BENZOYLAMINO)-1-BENZOTHIOPHENE-2-CARBOXYLATE METHYL 5-[(4-CHLOROBENZOYL)AMINO]-1-BENZOTHIOPHENE-2-CARBOXYLATE METHYL 5-([(4-METHYLPHENYL)SULFONYL]AMINO)-1-BENZOTHIOPHENE-2-CARBOXYLATE METHYL 5-([(4-CHLOROPHENYL)SULFONYL]AMINO)-1-BENZOTHIOPHENE-2-CARBOXYLATE METHYL 5-([3-(TRIFLUOROMETHYL)BENZOYL]AMINO)-1-BENZOTHIOPHENE-2-CARBOXYLATE METHYL 5-[(4-FLUOROBENZOYL)AMINO]-1-BENZOTHIOPHENE-2-CARBOXYLATE METHYL 3-((4,4-DIMETHYL-2,6-DIOXO(3,5-DIOXANYL))DIAZENYL)-5-NITROBENZO[B]THIOPHENE-2-CARBOXYLATE METHYL 5-([(2,4,5-TRICHLOROPHENYL)SULFONYL]AMINO)-1-BENZOTHIOPHENE-2-CARBOXYLATE METHYL 5-[(3-CHLOROBENZOYL)AMINO]-1-BENZOTHIOPHENE-2-CARBOXYLATE METHYL 5-[(PHENYLSULFONYL)AMINO]-1-BENZOTHIOPHENE-2-CARBOXYLATE

  • METHYL 5-AMINO-1-BENZOTHIOPHENE-2-CARBOXYLATE
  • ASISCHEM D48912
  • 5-AMINO-BENZO[B]THIOPHENE-2-CARBOXYLIC ACID METHYL ESTER
  • methyl 5-aminobenzo[b]thiophene-2-carboxylate
  • 5-Aminothionaphthene-2-carboxylic acid methyl ester
  • ethyl 5-aMinobenzo[b]thiophene-2-carboxylate
  • ethyl thieno[3,2-f]quinoline-2-carboxylate
  • Benzo[b]thiophene-2-carboxylic acid, 5-amino-, methyl ester
  • 20699-85-8