ChemicalBook > CAS DataBase List > Benzyl cinnamate

Benzyl cinnamate

Product Name
Benzyl cinnamate
CAS No.
103-41-3
Chemical Name
Benzyl cinnamate
Synonyms
CINNAMEIN;FEMA 2142;guisuanbianzhi;Benzyl ciamate;BENZYL CINNAMATE;Benzylcinnamoate;BENZYL CINNAMATE(P);Benzyl cinnamate-RM;Benzyl cinnamate,99%;BENZYL CINNAMATE(SG)
CBNumber
CB7413201
Molecular Formula
C16H14O2
Formula Weight
238.28
MOL File
103-41-3.mol
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Benzyl cinnamate Property

Melting point:
34-37 °C (lit.)
Boiling point:
195-200 °C/5 mmHg (lit.)
Density 
1.11
vapor pressure 
<0.1 hPa (20 °C)
FEMA 
2142 | BENZYL CINNAMATE
refractive index 
1.4025-1.4045
Flash point:
>230 °F
storage temp. 
Store below +30°C.
solubility 
alcohol: soluble(lit.)
form 
Crystalline Mass or Liquid After Melting
color 
Clear colorless to yellow
Odor
aromatic odor
Odor Type
balsamic
biological source
synthetic
Water Solubility 
PRACTICALLY INSOLUBLE
Merck 
14,1130
JECFA Number
670
BRN 
2051339
LogP
4.18 at 23.7℃
CAS DataBase Reference
103-41-3(CAS DataBase Reference)
NIST Chemistry Reference
Benzyl cinnamate(103-41-3)
EPA Substance Registry System
Benzyl cinnamate (103-41-3)
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Safety

Risk Statements 
36/37/38
Safety Statements 
22-24/25
RIDADR 
3077
WGK Germany 
2
RTECS 
GD8400000
TSCA 
Yes
HS Code 
29163900
Hazardous Substances Data
103-41-3(Hazardous Substances Data)
Toxicity
LD50 orally in rats: 5530 mg/kg (Jenner)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H317May cause an allergic skin reaction

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P272Contaminated work clothing should not be allowed out of the workplace.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P333+P313IF SKIN irritation or rash occurs: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
W214205
Product name
Benzyl cinnamate
Purity
≥98%
Packaging
sample-k
Price
$59.8
Updated
2024/03/01
Sigma-Aldrich
Product number
W214205
Product name
Benzyl cinnamate
Purity
≥98%, stabilized
Packaging
1kg
Price
$183
Updated
2024/03/01
Sigma-Aldrich
Product number
W214205
Product name
Benzyl cinnamate
Purity
≥98%, stabilized
Packaging
5kg
Price
$761
Updated
2024/03/01
Sigma-Aldrich
Product number
234214
Product name
Benzyl cinnamate
Purity
99%
Packaging
100g
Price
$61.7
Updated
2024/03/01
Sigma-Aldrich
Product number
W214205
Product name
Benzyl cinnamate
Purity
≥98%, stabilized
Packaging
10Kg
Price
$995
Updated
2023/06/20
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Benzyl cinnamate Chemical Properties,Usage,Production

Chemical Properties

Clear colorless to yellowish crystalline mass or liquid after meltin

Chemical Properties

Benzyl Cinnamate occurs in balsams and balsam oils. It forms white, sweet-balsamic-smelling crystals (mp 35-36°C). Benzyl cinnamate is used as a fixative in perfumes and as a component of heavy, oriental perfumes.

Chemical Properties

Benzyl cinnamate has a sweet, balsamic odor and a honey-like taste.

Occurrence

Reported found in Peru and Tolu balsam, in Sumatra and Penang benzoin, and as the main constituent of copaiba balsam.

Uses

Benzyl cinnamate has been employed as internal standard during the determination of compounds commonly added to personal care products such as UV filters and antimicrobial agents in environmental samples.

Uses

Mild. sweet-balsamic and somewhat floral odor of great tenacity. Used quite frequently in perfumery, mainly as a fixative, and particularly in perfumes for Talcum (powders). It blends well with floral bases, spicy fragrances and Ambre types.
Used in flavor compositions for imitation Apricot, Cherry, Chocolate, Honey, Peach, Pineapple, Liquor, Raspberry, Rum, Prune, etc.
Concentration may be little more than traces, usually about 6 ppm, except in chewing gum: up to 125 ppm.

Definition

ChEBI: Benzyl cinnamate is the cinnamate ester derived from cinnamic acid and benzyl alcohol. Occuring in Balsam of Peru and Tolu balsam, in Sumatra and Penang benzoin, and as the main constituent of copaiba balsam, it is used in heavy oriental perfumes, as a fixative and as a flavouring agent. It has a role as a flavouring agent, a fragrance, a fixative, an antigen and an epitope.

Preparation

By heating benzyl chloride and excess sodium cinnamate in water to 100 to 115°C; by heating sodium cinnamate with an excess of benzyl chloride in the presence of diethylamine.

Production Methods

Benzyl cinnamate is produced by the direct esterification of benzyl alcohol with cinnamic acid.

Taste threshold values

Taste characteristics at 50 ppm: spicy, floral, fruity, balsamic.

General Description

Benzyl cinnamate is widely used as a fragrance ingredient.

Hazard

Moderately toxic.

Flammability and Explosibility

Non flammable

Safety Profile

Moderately toxic by ingestion. Amild allergen and skin irritant. Combustible liquid. When heated to decomposition it emits acridsmoke and irritating fumes.

target

Immunology & Inflammation related

Metabolism

See monograph on Benzyl alcohol (p. 1011).

Purification Methods

Recrystallise the ester to a constant melting point from 95% EtOH. It has the odour of balsam. Alternatively dissolve it in Et2O, wash it with 10% aqueous Na2CO3, H2O, dry (Na2SO4), evaporate and fractionate it under reduced pressure using a short Vigreux column (p 11). It decomposes when boiled at atmospheric pressure. [Eliel & Anderson J Am Chem Soc 74 547 1952, Bender & Zerner J Am Chem Soc 84 2550 1962, Beilstein 9 IV 2012.]

Benzyl cinnamate Preparation Products And Raw materials

Raw materials

Benzyl chloride Benzyl alcohol Diethylamine trans-Cinnamic acid Sodium cinnamate

Preparation Products

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Benzyl cinnamate Suppliers

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View Lastest Price from Benzyl cinnamate manufacturers

Hebei Zhuanglai Chemical Trading Co.,Ltd
Product
Benzyl cinnamate 103-41-3
Price
US $10.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
5000KG/Week
Release date
2024-04-24
Hebei Weibang Biotechnology Co., Ltd
Product
Benzyl cinnamate 103-41-3
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
500000kg
Release date
2024-11-01
Hebei Chuanghai Biotechnology Co,.LTD
Product
Benzyl cinnamate 103-41-3
Price
US $19.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10 ton
Release date
2024-08-23

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