ChemicalBook > CAS DataBase List > 4-METHOXY-3-BUTEN-2-ONE

4-METHOXY-3-BUTEN-2-ONE

Product Name
4-METHOXY-3-BUTEN-2-ONE
CAS No.
51731-17-0
Chemical Name
4-METHOXY-3-BUTEN-2-ONE
Synonyms
4-methoxy-3-butene-2-one;TRANS-4-METHOXY-3-BUTEN-2-ONE;Einecs 257-364-0;4-METHOXY-3-BUTEN-2-ONE;Trans 4-Methoxy Butenone;(E)-4-methoxy-3-buten-2-one;(3E)-4-Methoxybut-3-en-2-one;(3E)-4-Methoxy-3-buten-2-one;TRANS-1-METHOXY-1-BUTEN-3-ONE;3-Buten-2-one,4-methoxy-, (3E)-
CBNumber
CB7449808
Molecular Formula
C5H8O2
Formula Weight
100.12
MOL File
51731-17-0.mol
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4-METHOXY-3-BUTEN-2-ONE Property

Melting point:
0℃
Boiling point:
200 °C (lit.)
Density 
0.982 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.468(lit.)
Flash point:
146 °F
storage temp. 
2-8°C
solubility 
sol THF, ether, acetonitrile, benzene.
form 
liquid
Appearance
Colorless to light yellow Liquid
BRN 
2070991
InChI
InChI=1S/C5H8O2/c1-5(6)3-4-7-2/h3-4H,1-2H3/b4-3+
InChIKey
VLLHEPHWWIDUSS-ONEGZZNKSA-N
SMILES
CC(=O)/C=C/OC
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Safety

Risk Statements 
10
Safety Statements 
23-24/25
RIDADR 
1224
WGK Germany 
3
10-21
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H227Combustible liquid

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P235Keep cool.

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P370+P378In case of fire: Use … for extinction.

P403+P235Store in a well-ventilated place. Keep cool.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
122068
Product name
trans-4-Methoxy-3-buten-2-one
Purity
technical grade, 90%
Packaging
10g
Price
$101
Updated
2025/07/31
Sigma-Aldrich
Product number
122068
Product name
trans-4-Methoxy-3-buten-2-one
Purity
technical grade, 90%
Packaging
50g
Price
$215.6
Updated
2025/07/31
Sigma-Aldrich
Product number
122068
Product name
trans-4-Methoxy-3-buten-2-one
Purity
technical grade, 90%
Packaging
250g
Price
$1180
Updated
2025/07/31
AK Scientific
Product number
6378AB
Product name
4-Methoxybut-3-en-2-one,tech.
Packaging
5g
Price
$84
Updated
2021/12/16
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4-METHOXY-3-BUTEN-2-ONE Chemical Properties,Usage,Production

Uses

4-Methoxy-3-buten-2-one is a versatile four-carbon synthon; precursor to the Danishefsky diene; Diels-Alder dienophile; dipolarophile; electrophilic four-carbon synthon subject to conjugate addition at C-4 followed by elimination of the methoxide anion; its enolate is a nucleophilic four-carbon building block.

storage

4-Methoxy-3-buten-2-one may be harmful by inhalation, ingestion, or skin absorption; may cause skin and eye irritation; in addition to standard safety practice, mechanical exhaust is required. Do not breathe vapor. Store in refrigerator under nitrogen or argon.

4-METHOXY-3-BUTEN-2-ONE Preparation Products And Raw materials

Raw materials

Preparation Products

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4-METHOXY-3-BUTEN-2-ONE Suppliers

Tianjin Rongshen Chemical Co., Ltd
Tel
18317763565; 18317763565
Email
18317763565@163.com
Country
China
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9513
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58
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
4006356688 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
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62
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44801
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Syntechem Co.,Ltd
Tel
Fax
E-Mail Inquiry
Email
info@syntechem.com
Country
China
ProdList
12984
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Sichuan Kulinan Technology Co., Ltd
Tel
400-1166-196 18981987031
Fax
028-84555506 800101999
Email
cdhxsj@163.com
Country
China
ProdList
11705
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Anhui Shite Pharmaceutical Technology Co., LTD
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0555-8228058 13621628489
Fax
0512-63261912
Email
sales1@stepuppharm.com
Country
China
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259
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Shanghai Topbiochem Technology Co., Ltd
Tel
021-58170097
Email
info@topbiochem.com
Country
China
ProdList
9510
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9ding chemical ( Shanghai) Limited
Tel
4009209199
Fax
86-021-52271987
Email
sales@9dingchem.com
Country
China
ProdList
22514
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55
Shanghai Aladdin Bio-Chem Technology Co.,LTD
Tel
400-6206333 13167063860
Fax
021-50323701
Email
anhua.mao@aladdin-e.com
Country
China
ProdList
25003
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65
Beijing Universal Century Technology Co., Ltd.
Tel
400-8706899
Fax
400-8706899
Email
hysj_bj.com
Country
China
ProdList
3583
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55

51731-17-0, 4-METHOXY-3-BUTEN-2-ONERelated Search:


  • (3E)-4-Methoxy-3-buten-2-one
  • 4-METHOXY-3-BUTEN-2-ONE
  • trans-4-methoxy-3-buten-2-one (1-1-3)
  • (E)-4-methoxy-3-buten-2-one
  • TRANS-4-METHOXY-3-BUTEN-2-ONE, TECH., 90 %
  • Trans 4-Methoxy Butenone
  • TRANS-1-METHOXY-1-BUTEN-3-ONE
  • TRANS-4-METHOXY-3-BUTEN-2-ONE
  • trans-4-Methoxy-3-buten-2-one technical grade, 90%
  • (3E)-4-Methoxybut-3-en-2-one
  • Einecs 257-364-0
  • 3-Buten-2-one,4-methoxy-, (3E)-
  • 4-methoxy-3-butene-2-one
  • <i>trans</i>-4-Methoxy-3-buten-2-one
  • 51731-17-0
  • C3 to C6
  • Carbonyl Compounds
  • Building Blocks
  • Organic Building Blocks
  • Ketones
  • C3 to C6
  • Carbonyl Compounds
  • Ketones