ChemicalBook > CAS DataBase List > 1,1-Di(tert-butylperoxy)cyclohexane

1,1-Di(tert-butylperoxy)cyclohexane

Product Name
1,1-Di(tert-butylperoxy)cyclohexane
CAS No.
3006-86-8
Chemical Name
1,1-Di(tert-butylperoxy)cyclohexane
Synonyms
1,1-bis(T-butylperoxy)cyclohexane;DP275B;Perhexa-C;Chaloxyd P;Trigonox 22;Lupersol 331;Trigonox 22C50;TRIGONOX(R) 22;Luperox 331M80;Luperox? 331P80
CBNumber
CB7451603
Molecular Formula
C14H28O4
Formula Weight
260.37
MOL File
3006-86-8.mol
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1,1-Di(tert-butylperoxy)cyclohexane Property

Melting point:
65 °C (SADT)
Boiling point:
52-54 °C (0.1 mmHg)
Density 
0.891 g/mL at 25 °C
vapor pressure 
4.88hPa at 25℃
refractive index 
n20/D 1.435
Flash point:
155 °F
storage temp. 
2-8°C
form 
Liquid
color 
Clear
Water Solubility 
miscible
InChI
InChI=1S/C14H28O4/c1-12(2,3)15-17-14(10-8-7-9-11-14)18-16-13(4,5)6/h7-11H2,1-6H3
InChIKey
HSLFISVKRDQEBY-UHFFFAOYSA-N
SMILES
C1(CCCCC1)(OOC(C)(C)C)OOC(C)(C)C
LogP
7.2 at 25℃
CAS DataBase Reference
3006-86-8(CAS DataBase Reference)
EPA Substance Registry System
Peroxide, 1,1'-cyclohexylidenebis[2-(1,1-dimethylethyl) (3006-86-8)
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Safety

Hazard Codes 
O,N,T
Risk Statements 
7-62-50/53-36/37/38-61-65-45-51/53
Safety Statements 
17-36/37/39-3/7-14A-61-60-45-26-14-53-62
RIDADR 
UN 3103 5.2
WGK Germany 
2
HazardClass 
5.2
PackingGroup 
II
HS Code 
29096000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H242Heating may cause a fire

H304May be fatal if swallowed and enters airways

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

H340May cause genetic defects

H350May cause cancer

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P235Keep cool.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P331Do NOT induce vomiting.

P370+P378In case of fire: Use … for extinction.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
531758
Product name
Luperox? 331M80, 1,1-Bis(tert-butylperoxy)cyclohexane solution
Purity
~80 wt. % in odorless mineral spirits
Packaging
500ml
Price
$147
Updated
2024/03/01
American Custom Chemicals Corporation
Product number
CHM0005590
Product name
1,1-DI(TERT-BUTYLPEROXY)CYCLOHEXANE
Purity
95.00%
Packaging
500ML
Price
$4102.1
Updated
2021/12/16
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1,1-Di(tert-butylperoxy)cyclohexane Chemical Properties,Usage,Production

Chemical Properties

clear liquid

Uses

Polymerization initiator.

Definition

1,1-Di (tert-butylperoxy) cyclohexane (DTBPH) is a commercial liquid organic peroxide that is to be in aliphatic hydrocarbon solvent and transported and stored under limited temperature[1].

Reactivity Profile

The explosive instability of the lower dialkyl peroxides (e.g., dimethyl peroxide) and 1,1-bis-peroxides decreases rapidly with increasing chain length and degree of branching, the di-tert-alkyl derivatives being amongst the most stable class of peroxides. Though many 1,1-bis-peroxides have been reported, few have been purified because of the higher explosion hazards compared with the monofunctional peroxides. 1,1-Di(tert-butylperoxy)cyclohexane is unlikely that this derivative would be particularly unstable compared to other peroxides in it's class, Bretherick 2nd ed., p 44 1979.

Flammability and Explosibility

Not classified

Toxics Screening Level

The initial threshold screening level (ITSL) for 1,1-Di-(tert-butylperoxy)cyclohexane is set at trace, 0.1 μg/m3 based on an annual averaging time.

References

[1] Jo-Ming Tseng . “The thermal hazard evaluation of 1,1-di (tert-butylperoxy) cyclohexane by DSC using non-isothermal and isothermal-kinetic simulations.” Journal of Loss Prevention in The Process Industries 25 4 (2012): Pages 703-708.

1,1-Di(tert-butylperoxy)cyclohexane Preparation Products And Raw materials

Raw materials

Preparation Products

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1,1-Di(tert-butylperoxy)cyclohexane Suppliers

Aston Chemical
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13000000000
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United States
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View Lastest Price from 1,1-Di(tert-butylperoxy)cyclohexane manufacturers

Sinomore New Material Company Limited
Product
1,1-Di(tert-butylperoxy) cyclohexane 3006-86-8
Price
US $0.00-0.00/kg
Min. Order
500kg
Purity
70%
Supply Ability
200tons
Release date
2024-07-09

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