ChemicalBook > CAS DataBase List > N-HEXYLLITHIUM

N-HEXYLLITHIUM

Product Name
N-HEXYLLITHIUM
CAS No.
21369-64-2
Chemical Name
N-HEXYLLITHIUM
Synonyms
HEXYLLITHIUM;lithium,hexane;1-Hexyllithium;1-Lithiohexane;N-HEXYLLITHIUM;Lithium, hexyl-;hexyllithium solution;N-HEXYLLITHIUM: IN HEXANE;Hexyllithium, 2M in hexane;n-Hexyllithium, soln. in he
CBNumber
CB7480195
Molecular Formula
C6H13Li
Formula Weight
92.11
MOL File
21369-64-2.mol
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N-HEXYLLITHIUM Property

Boiling point:
69 °C
Density 
0.708 g/mL at 25 °C
vapor pressure 
26.9-39.3hPa at 20-35℃
Flash point:
16 °F
storage temp. 
2-8°C
color 
yellow-brown
Sensitive 
Moisture Sensitive
BRN 
3600261
Stability:
Stable, but highly flammable. Reacts violently with water, releasing flammable gas. May spontaneously inflame in air. Moisture and air sensitive. Incompatible with water, alcohols, halocarbons.
EPA Substance Registry System
Lithium, hexyl- (21369-64-2)
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Safety

Hazard Codes 
F,Xn,N,C
Risk Statements 
11-14/15-17-35-48/20-51/53-62-65-67
Safety Statements 
26-30-36/37/39-43-45-61-62-16-6
RIDADR 
UN 3394 4.2/PG 1
WGK Germany 
2
F 
10-23
TSCA 
Yes
HazardClass 
4.3
PackingGroup 
I
HS Code 
29319090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H225Highly Flammable liquid and vapour

H250Catches fire spontaneously if exposed to air

H260In contact with water releases flammable gases which may ignite spontaneously

H304May be fatal if swallowed and enters airways

H314Causes severe skin burns and eye damage

H318Causes serious eye damage

H336May cause drowsiness or dizziness

H361Suspected of damaging fertility or the unborn child

H373May cause damage to organs through prolonged or repeated exposure

H411Toxic to aquatic life with long lasting effects

Precautionary statements

P201Obtain special instructions before use.

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P222Do not allow contact with air.

P223Keep away from any possible contact with water, because of violent reaction and possible flash fire.

P231+P232Handle under inert gas. Protect from moisture.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P307IF exposed:

P370+P378In case of fire: Use … for extinction.

P422Store contents under …

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
468568
Product name
Hexyllithium solution
Purity
2.3M in hexane
Packaging
100ml
Price
$76.2
Updated
2024/03/01
Sigma-Aldrich
Product number
468568
Product name
Hexyllithium solution
Purity
2.3M in hexane
Packaging
1l
Price
$293
Updated
2024/03/01
American Custom Chemicals Corporation
Product number
OGM0002761
Product name
HEXYLLITHIUM
Purity
95.00%
Packaging
1L
Price
$995.06
Updated
2021/12/16
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N-HEXYLLITHIUM Chemical Properties,Usage,Production

Description

n-Hexyllithium [21369-64-2], C6H13Li, Mr 92.11, r 0.766 g/cm3 is a pyrophoric colorless and viscous liquid in the neat state. It is commercially available as a 33 % solution in technical-grade hexane. Its reactivity resembles that of n-butyllithium and it can thus principally be used for the same applications. An advantage is that it does not form gaseous byproducts in deprotonation reactions and on hydrolysis, but liquid hexane instead.

Chemical Properties

often supplied as a deep yellow solution (ca 2M) in hexane

N-HEXYLLITHIUM Preparation Products And Raw materials

Raw materials

Preparation Products

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N-HEXYLLITHIUM Suppliers

Belgium 3 China 109 France 2 Germany 8 India 22 Switzerland 2 United Kingdom 4 United States 17 Global 167
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View Lastest Price from N-HEXYLLITHIUM manufacturers

Career Henan Chemical Co
Product
lithium,hexane 21369-64-2
Price
US $1.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
Customized
Release date
2018-12-25

21369-64-2, N-HEXYLLITHIUMRelated Search:

Methyllithium n-Butyllithium LITHIUM METHOXIDE ISOBUTYLLITHIUM tert-Butyllithium Lithium bis(trimethylsilyl)amide SEC-BUTYLLITHIUM Butyldi-1-adamantylphosphine Lithium chloride (TRIMETHYLSILYL)METHYLLITHIUM Lithium diisopropylamide Lithium hexamethyldisilazide Butylamine n-Butylboronic acid Heptanoyl chloride Hexane Valeric acid Ethyl Hexanoate

  • n-Hexyllithium, 33 wt.% solution in n-hexane, AcroSeal
  • 1-Lithiohexane
  • 1-Hexyllithium
  • lithium,hexane
  • Lithium, hexyl-
  • HexyllithiuM, 2.5 M solution in Hexane, SpcSeal
  • HEXYLLITHIUM SOLUTION, IN HEXANE
  • HEXYLLITHIUM, SOLUTION IN HEXANE
  • n-Hexyllithium, solution in n-hexane
  • n-Hexyllithium, soln. in he
  • N-HEXYLLITHIUM: IN HEXANE
  • n-Hexyllithium, 2.2 M solution in n-hexane, J&KSeal
  • HEXYLLITHIUM
  • N-HEXYLLITHIUM
  • HEXYLLITHIUM SOLUTION, ~2.3 M IN HEXANE
  • HEXYLLITHIUM, 2.3M SOLUTION IN HEXANE
  • n-Hexyllithium, 33 wt.% solution in n-hexane
  • hexyllithium solution
  • N-HEXYLLITHIUM: 25% IN HEXANE, 1.9M
  • n-Hexyllithium, 33% (ca 2.47M) soln. in hexane
  • Hexyllithium (30% in Hexane, ca. 2.3mol/L)
  • n-Hexyllithium33 wt.% solution in n-hexaneAcroSeal§3
  • N-HEXYLLITHIUM ISO 9001：2015 REACH
  • Hexyllithium, 2M in hexane
  • n-Hexyllithium 15% (in Hexane)
  • n-Hexyllithium 23% (in Hexane)
  • n-Hexyllithium 33% (in Hexane)
  • N-HEXYLLITHIUM(2.2Minhexane)
  • 21369-64-2
  • 21369-64-3
  • 21369-94-2
  • CH3CH25Li
  • C6H13Li
  • Organolithium
  • Organometallic Reagents
  • Alkyl
  • Classes of Metal Compounds
  • Alkyl Metals
  • Grignard Reagents & Alkyl Metals
  • Li (Lithium) Compounds
  • Typical Metal Compounds
  • Alkyl
  • Chemical Synthesis
  • Organic Bases
  • Organometallic Reagents
  • Synthetic Reagents
  • Alkyl Metals
  • Classes of Metal Compounds
  • Grignard Reagents & Alkyl Metals
  • Li (Lithium) Compounds
  • Synthetic Organic Chemistry
  • Typical Metal Compounds
  • AlkylChemical Synthesis
  • Organic Bases
  • Organolithium
  • Organometallic Reagents
  • Synthetic Reagents