ChemicalBook > CAS DataBase List > 4-(2-METHOXYPHENYL)PIPERIDINE

4-(2-METHOXYPHENYL)PIPERIDINE

Product Name
4-(2-METHOXYPHENYL)PIPERIDINE
CAS No.
58333-75-8
Chemical Name
4-(2-METHOXYPHENYL)PIPERIDINE
Synonyms
4-(2-Methoxyphenyl);2-(Piperidin-4-yl)anisole;4-(2-METHOXYPHENYL)PIPERIDINE;Piperidine,4-(2-methoxyphenyl)-
CBNumber
CB7669983
Molecular Formula
C12H17NO
Formula Weight
191.27
MOL File
58333-75-8.mol
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4-(2-METHOXYPHENYL)PIPERIDINE Property

Melting point:
54 °C
Boiling point:
115-118 °C(Press: 1.1 Torr)
Density 
1.003±0.06 g/cm3(Predicted)
storage temp. 
under inert gas (nitrogen or Argon) at 2–8 °C
pka
10.22±0.10(Predicted)
Appearance
Off-white to light brown Solid
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38-52/53
Safety Statements 
26-36/37/39-61
Hazard Note 
Irritant
HS Code 
2933399990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P321Specific treatment (see … on this label).

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

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N-Bromosuccinimide Price

TRC
Product number
M226553
Product name
4-(2-Methoxyphenyl)piperidine
Packaging
500mg
Price
$130
Updated
2021/12/16
Oakwood
Product number
033949
Product name
4-(2-Methoxyphenyl)piperidine
Purity
97%
Packaging
250mg
Price
$48
Updated
2021/12/16
Matrix Scientific
Product number
113681
Product name
4-(2-Methoxyphenyl)piperidine
Purity
97%
Packaging
1g
Price
$98
Updated
2021/12/16
SynQuest Laboratories
Product number
4H56-1-5N
Product name
4-(2-Methoxyphenyl)piperidine
Purity
97%
Packaging
1g
Price
$116
Updated
2021/12/16
Matrix Scientific
Product number
113681
Product name
4-(2-Methoxyphenyl)piperidine
Purity
97%
Packaging
5g
Price
$312
Updated
2021/12/16
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4-(2-METHOXYPHENYL)PIPERIDINE Chemical Properties,Usage,Production

Synthesis

201609-29-2

58333-75-8

General procedure for the synthesis of 4-(2-methoxyphenyl)piperidine-1-carboxylic acid tert-butyl ester from 4-(2-methoxyphenyl)piperidine-1-carboxylic acid: a solution of 4-(2-methoxyphenyl)piperidine-1-carboxylic acid tert-butyl ester (70 mg, 0.24 mmol) with 10% wet Pd/C (10 mg) in 10 mL of ethyl acetate was purged three times with N2 and then stirred in H2 atmosphere (50 psi) with stirring overnight. After completion of the reaction, the suspension was filtered and the filtrate was evaporated in vacuum to give 4-(2-methoxyphenyl)piperidine (70 mg, yield: 99%) as a colorless oil. 4-(2-methoxyphenyl)piperidine (70 mg, 0.24 mmol) was dissolved in 5 mL HCl/dioxane and stirred overnight at room temperature. After completion of the reaction, the solution was evaporated to dryness in vacuum. The solid was washed with ether to give 4-(2-methoxyphenyl)piperidine hydrochloride (35 mg, yield: 76%) as a white solid.

References

[1] Patent: WO2014/100501, 2014, A1. Location in patent: Paragraph 00407
[2] Bioorganic and Medicinal Chemistry Letters, 1998, vol. 8, # 14, p. 1851 - 1856
[3] Journal of Medicinal Chemistry, 2012, vol. 55, # 20, p. 8685 - 8699,15
[4] Journal of Medicinal Chemistry, 2012, vol. 55, # 20, p. 8685 - 8699

4-(2-METHOXYPHENYL)PIPERIDINE Preparation Products And Raw materials

Raw materials

Preparation Products

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4-(2-METHOXYPHENYL)PIPERIDINE Suppliers

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View Lastest Price from 4-(2-METHOXYPHENYL)PIPERIDINE manufacturers

Career Henan Chemical Co
Product
4-(2-METHOXYPHENYL)PIPERIDINE 58333-75-8
Price
US $5.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
100KG
Release date
2020-01-12

58333-75-8, 4-(2-METHOXYPHENYL)PIPERIDINERelated Search:

Naltrexone hydrochloride MORPHINIUM CHLORIDE HYDROCODONE BITARTRATE NALORPHINE HYDROCHLORIDE THEBAINE 3-METHYLMORPHINE SULFATE SALT NORCODEINE Naloxone hydrochloride NORMORPHINE 4-(3-METHOXYPHENYL) PIPERIDINE HYDROCHLORIDE 4-(4-METHOXY-PHENYL)-PIPERIDINE HYDROCHLORIDE 3-(4-METHOXYPHENYL) PIPERIDINE HYDROCHLORIDE 3-(3-METHOXYPHENYL) PIPERIDINE HYDROCHLORIDE 3-(2-METHOXYPHENYL) PIPERIDINE HYDROCHLORIDE 4-(4-METHOXYPHENYL)PIPERIDINE 4-CYANO-4-(3-METHOXYPHENYL)-1-METHYLPIPERIDINE 1-(4-Methoxyphenyl)piperazine dihydrochloride 4-(2-METHOXYPHENYL) PIPERIDINE HYDROCHLORIDE

  • 4-(2-METHOXYPHENYL)PIPERIDINE
  • 2-(Piperidin-4-yl)anisole
  • Piperidine,4-(2-methoxyphenyl)-
  • 4-(2-Methoxyphenyl)
  • 58333-75-8
  • 58333-75-9