METHYL 4-(4-PYRIDINYL)BENZOATE
- Product Name
- METHYL 4-(4-PYRIDINYL)BENZOATE
- CAS No.
- 106047-17-0
- Chemical Name
- METHYL 4-(4-PYRIDINYL)BENZOATE
- Synonyms
- AKOS BAR-0605;METHYL 4-PYRIDIN-4-YL-BENZATE;Methyl 4-(pyridin-4-yl)benoate;METHYL 4-(4-PYRIDINYL)BENZOATE;METHYL 4-(PYRIDIN-4-YL)BENZOATE;Benzoic acid, 4-(4-pyridinyl)-, methyl ester
- CBNumber
- CB7703427
- Molecular Formula
- C13H11NO2
- Formula Weight
- 213.23
- MOL File
- 106047-17-0.mol
METHYL 4-(4-PYRIDINYL)BENZOATE Property
- Melting point:
- 103-105℃
- Boiling point:
- 160 °C(Press: 1 Torr)
- Density
- 1.147
- storage temp.
- Inert atmosphere,Room Temperature
- pka
- 4.98±0.10(Predicted)
Safety
- HS Code
- 2933399990
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H320Causes eye irritation
H371May cause damage to organs
H400Very toxic to aquatic life
- Precautionary statements
-
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P270Do not eat, drink or smoke when using this product.
P273Avoid release to the environment.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P337+P313IF eye irritation persists: Get medical advice/attention.
P391Collect spillage. Hazardous to the aquatic environment
P405Store locked up.
P501Dispose of contents/container to..…
N-Bromosuccinimide Price
- Product number
- OR346705
- Product name
- 4-(Pyridin-4-yl)benzoic acid methyl ester
- Packaging
- 1g
- Price
- $187
- Updated
- 2021/12/16
- Product number
- 1335AA
- Product name
- Methyl4-(pyridin-4-yl)benzoate
- Packaging
- 250mg
- Price
- $101
- Updated
- 2021/12/16
- Product number
- OR346705
- Product name
- 4-(Pyridin-4-yl)benzoic acid methyl ester
- Packaging
- 5g
- Price
- $578
- Updated
- 2021/12/16
- Product number
- 1335AA
- Product name
- Methyl4-(pyridin-4-yl)benzoate
- Packaging
- 10g
- Price
- $594
- Updated
- 2021/12/16
- Product number
- CHM0290536
- Product name
- METHYL-4-(PYRIDIN-4-YL)BENZOATE
- Purity
- 98.00%
- Packaging
- 0.5G
- Price
- $1347.5
- Updated
- 2021/12/16
METHYL 4-(4-PYRIDINYL)BENZOATE Chemical Properties,Usage,Production
Synthesis
1120-87-2
99768-12-4
106047-17-0
Step A: 4-Bromopyridine (3.0 g, 19.0 mmol), 4-methoxycarbonylphenylboronic acid (2.63 g, 14.6 mmol), Pd(PPh3)2Cl2 (0.35 g, 0.5 mmol) and sodium carbonate (6.91 g, 65.2 mmol) were dissolved in 1,2-dimethoxyethane (40 mL) under nitrogen protection. The reaction mixture was heated to 90 °C and stirred for 10 hours. Upon completion of the reaction, the mixture was concentrated under reduced pressure and the residue was purified by silica gel column chromatography (eluent: petroleum ether/ethyl acetate = 6:1 to 2:1) to afford methyl 4-(pyridin-4-yl)benzoate (2.7 g, yield: 86.8%) as a white solid. m/z MS (ESI): 214 [M+H]+.
References
[1] Patent: EP3190113, 2017, A1. Location in patent: Paragraph 0101
[2] Patent: TWI558709, 2016, B. Location in patent: Page/Page column 50; 51
[3] Patent: US2004/242572, 2004, A1. Location in patent: Page/Page column 73
METHYL 4-(4-PYRIDINYL)BENZOATE Preparation Products And Raw materials
Raw materials
Preparation Products
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