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2-Methyl butyric acid

Description References
Product Name
2-Methyl butyric acid
CAS No.
116-53-0
Chemical Name
2-Methyl butyric acid
Synonyms
2-METHYLBUTANOIC ACID;2-METHYLBUTYRIC ACID;Ethylmethylacetic acid;DL-2-Methylbutyric acid;2-methylbutyric;2-methylbutyrate;NSC 7304;FEMA 2695;2-Methylbutyri;Hydroangelic acid
CBNumber
CB7766118
Molecular Formula
C5H10O2
Formula Weight
102.13
MOL File
116-53-0.mol
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2-Methyl butyric acid Property

Melting point:
-70 °C
Boiling point:
176-177 °C (lit.)
Density 
0.936 g/mL at 25 °C (lit.)
vapor pressure 
0.5 mm Hg ( 20 °C)
refractive index 
n20/D 1.405(lit.)
FEMA 
2695 | 2-METHYLBUTYRIC ACID
Flash point:
165 °F
storage temp. 
Sealed in dry,Room Temperature
solubility 
20g/l
form 
Liquid
pka
4.8(at 25℃)
color 
Clear colorless to pale yellow
Odor
at 10.00 % in propylene glycol. pungent acid roquefort cheese
Odor Type
acidic
explosive limit
1.6-7.3%(V)
Water Solubility 
45 g/L (20 ºC)
JECFA Number
255
BRN 
1720486
LogP
1.8 at 25℃
CAS DataBase Reference
116-53-0(CAS DataBase Reference)
NIST Chemistry Reference
Butanoic acid, 2-methyl-(116-53-0)
EPA Substance Registry System
2-Methylbutyric acid (116-53-0)
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Safety

Hazard Codes 
C
Risk Statements 
21/22-34
Safety Statements 
26-36/37/39-45
RIDADR 
UN 3265 8/PG 3
WGK Germany 
1
RTECS 
EK7897000
13
TSCA 
Yes
HazardClass 
8
PackingGroup 
III
HS Code 
29156090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H290May be corrosive to metals

H314Causes severe skin burns and eye damage

Precautionary statements

P234Keep only in original container.

P270Do not eat, drink or smoke when using this product.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
W269514
Product name
(±)-2-Methylbutyric acid
Purity
natural,≥98%,FG
Packaging
100g
Price
$87.7
Updated
2024/03/01
Sigma-Aldrich
Product number
W269514
Product name
(±)-2-Methylbutyric acid
Purity
natural,≥98%,FG
Packaging
1kg
Price
$355
Updated
2024/03/01
Sigma-Aldrich
Product number
W269514
Product name
(±)-2-Methylbutyric acid
Purity
natural,≥98%,FG
Packaging
5kg
Price
$1140
Updated
2024/03/01
Sigma-Aldrich
Product number
W269506
Product name
2-Methylbutyric acid
Purity
≥98%, FG
Packaging
1kg
Price
$151
Updated
2024/03/01
Sigma-Aldrich
Product number
W269506
Product name
2-Methylbutyric acid
Purity
≥98%, FG
Packaging
5kg
Price
$416
Updated
2024/03/01
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2-Methyl butyric acid Chemical Properties,Usage,Production

Description

2-methyl butyric acid has a pungent, acrid odor which is similar to Roquefort cheese with an acrid taste. At low dilutions, it has a pleasant fruity taste. It can be prepared either by decarboxylation of methyl ethyl malonic acid or by the oxidation of fermentation amyl alcohol (fusel oil). It is used as a flavor ingredient for butter, cream, cheese flavor deployment. It also provides acyl moiety for the preparation of the respective flavor esters.

References

[1] George A. Burdock, Encyclopedia of Food and Color Additives, Band 1, 1996
[2] T. Tachihara, H. Hashimoto, S. Ishizaki, T. Komai, A. Fujita, M. Ishikawa and T. Kitahara, Microbial resolution of 2-methylbutyric acid and its application to several chiral flavour compounds, Developments in Food Science, 2006, vol. 43, 97-100

Description

2-Methylbutyric acid has a pungent, acrid odor similar to Roquefort cheese with an acrid taste. At low dilutions, it has a pleasant fruity taste. May be prepared by decarboxylation of methyl ethyl malonic acid (with heat); also by oxidation of fermentation amyl alcohol (fusel oil).

Chemical Properties

clear colorless to pale yellowish liquid

Chemical Properties

2-Methylbutyric acid has a pungent, acrid odor similar to Roquefort cheese with an acrid taste. At low dilutions, it has a pleasant, fruity taste. Slightly soluble in water, soluble in alcohol and oils. Also soluble in Propylene glycol and poorly soluble in Glycerin.

Occurrence

Occurring as the d-, l-, and dl-isomers; the racemic form has been reported found in angelica root oil and coffee; the d-isomer in the ester form has been identified in lavender oil. Also reported found in apple, apricot, berries, grapes, papaya, peach, guava, pineapple, potato, bell pepper, tomato, peppermint and spearmint oil, vinegar, wheat breads, cheeses, chicken, mutton, pork, hop oil, beer, cognac, rum, whiskies, cider, cocoa, coffee, tea, peanuts, passion fruit, trassi, mango, plum, tamarind, rice, corn oil, loquat, scallops, Chinese quince, maté, mammee apple and Roman chamomile oil, cranberry, grape brandy, oriental tobacco, and strawberry

Uses

2-Methylbutyric acid, can be used as food additive for butter, cream, cheese flavor deployment. It is an important raw material and intermediate used in Organic Synthesis, Pharmaceuticals, Agrochemicals and Dyestuff. It is also used in the synthesis of 2-methylbutyric anhydride.

Uses

2-Methylbutyric acid was used in the synthesis of 2-methylbutyric anhydride, an acylating agent.

Definition

ChEBI: A methylbutyric acid comprising a butyric acid core carrying a 2-methyl substituent. Produced from amino acid leucine during nutrient starvation in bacteria.

Preparation

By decarboxylation of methyl ethyl malonic acid (with heat); also by oxidation of fermentation amyl alcohol (fusel oil).

Aroma threshold values

Detection: 10 to 60 ppb. Aroma characteristics at 1.0%: acidic sour, pungent, ripe fruit leather, lingonberry, dirty cheesy, fermented pineapple fruity with a woody nuance

Taste threshold values

Taste characteristics at 10 ppm: dirty, acidic sour, ripe fruity, with a dairy buttery and cheesy nuance

General Description

Enantioselective esterification of (+/-)-2-methylbutynic acid catalyzed by Chromobacterium viscosum lipase immobilized in microemulsion-based organogels has been investigated.

Flammability and Explosibility

Not classified

Biochem/physiol Actions

Taste at 10 ppm

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2-Methyl butyric acid Suppliers

Juye Zhongyue Spices Co., Ltd
Tel
0530-8599699 13701896116
Email
liujun@zhongyuearoma.com
Country
China
ProdList
168
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58
Nanjing DoneChemical Technology Co., Ltd.
Tel
025-85282271 13851695187
Fax
025-83616148
Email
19969001@qq.com
Country
China
ProdList
76
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58
SHANGHAI BANGCHENG CHEMICAL Co.,Ltd.
Tel
021-69106960 13701823733
Fax
021-69106780
Email
13701823733@163.com
Country
China
ProdList
4767
Advantage
60
Guangzhou Rui Lion Biotechnology Co., LTD
Tel
13168345686 17306666488
Email
607141423@qq.com
Country
China
ProdList
1541
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58
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
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76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
Beijing HwrkChemical Technology Co., Ltd
Tel
010-89508211 18501085097
Fax
010-89508210
Email
sales.bj@hwrkchemical.com
Country
China
ProdList
8418
Advantage
55
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44689
Advantage
61
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View Lastest Price from 2-Methyl butyric acid manufacturers

Hebei Andu Technology Com.,Ltd
Product
2-Methyl butyric acid 116-53-0
Price
US $3.50/kg
Min. Order
1kg
Purity
≥99%
Supply Ability
3000tons/month
Release date
2024-08-25
WUHAN FORTUNA CHEMICAL CO., LTD
Product
2-Methyl butyric acid 116-53-0
Price
US $0.00/kg
Min. Order
25kg
Purity
98%min
Supply Ability
1000kg
Release date
2023-01-14
Hebei Yanxi Chemical Co., Ltd.
Product
2-Methyl butyric acid 116-53-0
Price
US $0.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
20 tons
Release date
2023-11-29

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