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Mannose Triflate

Product Name
Mannose Triflate
CAS No.
92051-23-5
Chemical Name
Mannose Triflate
Synonyms
MANNOSE TRIFLATE;TATM;TATM USP/EP/BP;MANNOSE TRIFLATE F;beta-D-Mannopyranose;Mannose Triflate?New;Mannose triflate≥ 99%(GC);1,3,4,6-Tetra-O-acetyl-2-O-;Mannose Triflate, ultra pure;Mannose Triflate PLUS, ultra pure
CBNumber
CB7774955
Molecular Formula
C15H19F3O12S
Formula Weight
480.36
MOL File
92051-23-5.mol
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Mannose Triflate Property

Melting point:
118-122 °C
alpha 
[α]D20 -14～-17゜(c=1,CHCl3)
Boiling point:
481.6±45.0 °C(Predicted)
Density 
1.50±0.1 g/cm3(Predicted)
refractive index 
-16 ° (C=1, CHCl3)
storage temp. 
-20°C
solubility 
Chloroform (Slightly), Ethyl Acetate (Slightly)
form 
Solid
color 
White to Off-White
optical activity
[α]22/D -16°, c = 1 in chloroform
BRN 
4341413
InChI
InChI=1/C15H19F3O12S/c1-6(19)25-5-10-11(26-7(2)20)12(27-8(3)21)13(14(29-10)28-9(4)22)30-31(23,24)15(16,17)18/h10-14H,5H2,1-4H3/t10-,11-,12+,13+,14-/s3
InChIKey
OIBDVHSTOUGZTJ-UBBZJQTNNA-N
SMILES
[C@H]1(OC(=O)C)[C@H](OC(=O)C)[C@H](O[C@@H](OC(=O)C)[C@H]1OS(=O)(=O)C(F)(F)F)COC(=O)C |&1:0,5,10,12,17,r|
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Safety

Hazard Codes 
Xi
Safety Statements 
24/25
WGK Germany 
3
F 
10-21
HS Code 
29329990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
M1568
Product name
Mannose triflate
Purity
For PET imaging, ≥98% (TLC)
Packaging
20mg
Price
$27.3
Updated
2024/03/01
Sigma-Aldrich
Product number
Y0001087
Product name
Tetra-<I>O</I>-acetyl-mannose triflate
Purity
European Pharmacopoeia (EP) Reference Standard
Packaging
2each
Price
$144
Updated
2024/03/01
Sigma-Aldrich
Product number
655112
Product name
β-D-Mannopyranose 1,3,4,6-tetra-O-acetate 2-O-trifluoromethanesulfonate
Purity
98%
Packaging
100mg
Price
$28.4
Updated
2024/03/01
Sigma-Aldrich
Product number
Y0001087
Product name
Tetra-O-acetyl-mannose triflate
Purity
European Pharmacopoeia (EP) Reference Standard
Packaging
2EA
Price
$144
Updated
2023/06/20
TCI Chemical
Product number
T2307
Product name
1,3,4,6-Tetra-O-acetyl-2-O-(trifluoromethanesulfonyl)-beta-D-mannopyranose
Purity
>98.0%(GC)
Packaging
100mg
Price
$39
Updated
2024/03/01
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Mannose Triflate Chemical Properties,Usage,Production

Description

Mannose triflate is a glucose analog. Mannose triflate is a well-known precursor for 18F-FDG synthesis for PET applications. 18F-FDG is an imaging technique for cancer.

Physical properties

White to off-white powder or crystal

Uses

1,3,4,6-Tetra-O-acetyl-2-O-trifluoromethanesulfonyl-beta-D-mannopyranose is a radiolabelled pharmaceutical preparation for diagnostic aims used in positron emission tomography.

Preparation

The tetraacetyl mannose (1.8 g, 5 mmol) was dissolved in anhydrous CH2Cl2(14 mL) containing dry pyridine (0.9 mL, 11 mmol). This solution was cooled to -15°C, and trifluoromethanesulfonic anhydride (triflic anhydride) (0.9 mL, 5.2 mmol) was added dropwise over 25 min under a nitrogen atmosphere with vigorous stirring. The mixture was then allowed to reach room temperature overnight. The reaction mixture was successively washed with ice-cold saturated aqueous NaHCO3(50 mL) and water (50 mL). The organic layer was dried over anhydrous Na2SO4, filtered, and concentrated on a rotary evaporator.2-Tf-O-AcManwas isolated by column chromatography on silica with hexane :EtOAc=1: 1 as the eluant as white solid Mannose triflate(1.4 g, 56percent).

Mannose Triflate Preparation Products And Raw materials

Raw materials

Preparation Products

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Mannose Triflate Suppliers

Belgium 1 Canada 2 China 172 Denmark 1 France 1 Germany 6 India 5 Israel 1 Japan 3 Russia 2 South Korea 1 Switzerland 2 The Netherlands 1 United Kingdom 9 United States 31 Global 238
ISOFLEX
Tel
--
Fax
--
Email
info@isoflex.com.ru
Country
Russia
ProdList
22
Advantage
58
Chimex Ltd.
Tel
--
Fax
--
Email
chimex@mail.wplus.net
Country
Russia
ProdList
545
Advantage
58
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View Lastest Price from Mannose Triflate manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD
Product
Mannose Triflate 92051-23-5
Price
US $0.00/G
Min. Order
1G
Purity
98%min
Supply Ability
30kg/month
Release date
2023-02-17
Zibo Hangyu Biotechnology Development Co., Ltd
Product
TATM 92051-23-5
Price
US $50.00-500.00/kg
Min. Order
10kg
Purity
0.99
Supply Ability
20tons
Release date
2023-10-31
Henan Fengda Chemical Co., Ltd
Product
TATM 92051-23-5
Price
US $6.00-1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2024-03-28

92051-23-5, Mannose TriflateRelated Search:

Ethyl trifluoromethanesulfonate N-DECYL-BETA-D-GLUCOPYRANOSIDE glucosylglycerol Glabridin 1,3-BUTANEDIOL DIACETATE 2-Butoxyethyl acetate 1,6-Diacetoxyhexane L(+)-Rhamnose monohydrate D-LYXOSE Methyl trifluoromethanesulfonate 2-[(Acetyloxy)methoxy]ethyl acetate Diacetin D-Mannose 1,1,3-TRIMETHOXYBUTANE ISOPROPYL METHANESULFONATE TATM Trifluoromethane FLUOROSULFONIC ACID

  • MANNOSE TRIFLATE
  • MANNOSE TRIFLATE F
  • 1,3,4,6-Tetraacetate 2-(trifluoromethanesulfonate) -D-Mannopyranose
  • tetraacetyltrifluoromethanesulfonyl-beta-D-mannopyranose
  • Mannose triflate, TATM, 1,3,4,6-Tetra-O-acetyl-2-O-trifluoromethanesulfonyl-β-D-mannopyranose
  • 1-O,3-O,4-O,6-O-Tetraacetyl-2-O-(trifluoromethylsulfonyl)-β-D-mannopyranose
  • 1-O,3-O,4-O,6-O-Tetraacetyl-2-O-trifluoromethanesulfonyl-β-D-mannopyranose
  • β-D-Mannopyranose 1,3,4,6-tetra-O-acetate 2-O-trifluoromethanesulfonate Mannose triflate
  • 1,3,4,6-Tetra-O-acetyl-2-O-trifluoromethylsulfonyl-β-D-mannopyranose
  • β-D-Mannopyranose 1,3,4,6-tetra-O-acetate 2-O-trifluoromethanesulfonate,1,3,4,6-Tetra-O-acetyl-2-O-trifluoromethanesulfonyl-β-D-mannopyranose, Mannose triflate, TATM
  • β-D-Maopyranose 1,3,4,6-tetra-O-acetate 2-O-trifluoromethanesulfonate
  • 1,3,4,6-Tetraacetate 2-(trifluoroMethanesulfonate)
  • 1,3,4,6-Tetra-O-acetyl-2-O-trifluoroMethane
  • 1,3,4,6-Tetra-O-acetyl-2-O-[(trifluoromethyl)sulphonyl]-beta-D-mannopyranose
  • TATM, 1,3,4,6-Tetra-O-acetyl-2-O-triflyl-beta-D-mannopyranose
  • b-D-Mannopyranose,1,3,4,6-tetraacetate 2-(trifluoroMethanesulfonate)
  • beta-D-Mannopyranose 1,3,4,6-tetra-O-acetate 2-O-trifluoroMethanesulfonate 98%
  • beta-D-Mannopyranose
  • 1,3,4,6-Tetra-O-acetyl-2-O-trifluoromethanesulfonyl-
  • β-D-Mannopyranose 1,3,4,6-tetra-O-acetate 2-O-trifluoromethanesulfonate(TATM)
  • acetic acid [3,4,6-triacetyloxy-5-(trifluoromethylsulfonyloxy)-2-oxanyl]methyl ester
  • TATM,1,3,4,6-Tetra-O-acetyl-2-O-trifluoromethanesulfonyl-beta-D-mannopyranose
  • BETA-D-MANNOPYRANOSE 1,3,4,6-TETRAACETATE 2-TRIFLATE
  • BETA-D-MANNOPYRANOSE, 1,3,4,6-TETRAACETATE 2-(TRIFLUOROMETHANE-SULFONATE)
  • BETA-D-MANNOPYRANOSE 1,3,4,6-TETRA-O-ACETATE 2-O-TRIFLUOROMETHANESULFONATE
  • 1,3,4,6-TETRA-O-ACETYL-2-O-TRIFLUORO-METHANESULFONYL-BETA-D-MANNOPYRANOSE
  • 1,3,4,6-TETRA-O-ACETYL-2-O-TRIFLUOROMETHANSULFONYL-BETA-D-MANNOPYRANOSE
  • 1,3,4,6-TETRA-O-ACETYL-2-O-TRIFLUOROMETHYLSULFONYL-B-D-MANNOPYRANOSE
  • 1,3,4,6-TETRA-O-ACETYL-2-O-TRIFLUOROMETHYLSULPHONYL-B-D-MANNOPYRANOSE
  • 1,3,4,6-Tetra-O-acetyl-2-O-trifluoromethanesulfonyl-β-D-mannopyranose
  • TATM
  • β-D-Mannopyranose 1,3,4,6-tetra-O-acetate 2-O-trifluoromethanesulfonate
  • 1,3,4,6-tetra-O-acetyl-2-O-triflat-beta-D-mannopyranose
  • tetra-O-acetyl-2-O-trifluoromethane-sulfonyl-beta
  • 1,3,4,6-TETRA-O-ACETYL-2-O-TRIFLUORO-*METHANESULFONY
  • 1,3,4,6-Tetra-O-acetyl-2-O-trifluoromethanesulfonyl-b-D-mannopyranose
  • 1,3,4,6-Tetra-O-acetyl-2-O-
  • 1,3,4,6-TETRA-O-ACETYL-2-O-TRIFLUOROMETHYLSULFONYL-B-D-MANNOPYRANOSE, TATM
  • 1,3,4,6-TETRA-O-ACETYL-2-O-TRIFLUOROMETHYLSULFONYL-B-D-MANNOPYRANOSE(MANNOSE TRIFLATE)
  • TETRA-O-ACETYL-2-O-TRIFLUOROMETHANE- &
  • BETA-D-MANNOPYRANOSE 1,3,4,6-TETRA-O-AC&
  • Mannose Triflate PLUS, ultra pure
  • Mannose Triflate, ultra pure packing for GE Microlab
  • Mannose Triflate, ultra pure packing for GE TRACERlab MXFDG
  • Mannose Triflate, ultra pure
  • 1,3,4,6-Tetra-O-Acetyl-2-O-(trifluoromethanesulfonyl)-a-D-mannopyranose
  • Mannose triflate≥ 99%(GC)
  • [(2R,3R,4S,5S,6S)-3,4,6-triacetyloxy-5-(trifluoromethylsulfonyloxy)oxan-2-yl]methyl acetate
  • Mannose triflate C15H19F3O12S high quality Cas number：92051-23-5
  • Tetra-O-acetyl-mannose triflate CRS
  • β-D-Mannopyranose, 1,3,4,6-tetraacetate 2-(trifluoromethanesulfonate)
  • TATM USP/EP/BP
  • 1,3,4,6-Tetra-O-acetyl-2-O-trifluoromethanesulfonyl-β-D-mannopyranose
  • β-D-Mannopyranose1,3,4,6-tetra-O-acetate2-O-trifluoromethanesulfonate
  • 1,3,4,6-tetra-O-acetate 2-O-trifluoromethanesulfonate-β-D-Mannopyranose
  • (2S,3S,4S,5R,6R)-6-(Acetoxymethyl)-3-(((trifluoromethyl)sulfonyl)oxy)tetrahydro-2H-pyran-2,4,5-triyl triacetate
  • 1,3,4,6-Tetra-O-acetyl-2-O-trifluoromethylsulfonyl-β-D-mannopyranose
  • 1,3,4,6-tetra-O-acetyl-2-O-triflat-beta-D-mannopyr