(S)-(-)-2-Methyl-1-butanol

ChemicalBook > CAS DataBase List > (S)-(-)-2-Methyl-1-butanol

(S)-(-)-2-Methyl-1-butanol

Product Name: (S)-(-)-2-Methyl-1-butanol
CAS No.: 1565-80-6
Chemical Name: (S)-(-)-2-Methyl-1-butanol
Synonyms: AMYL ALCOHOL;N-PENTANOL;FUSEL OIL;N-PENTYL ALCOHOL;AMYL ALCOHOL, N-;FEMA 2056;ALCOHOL C5;L-pentanol;(s)-1-butano;BUTYLCARBINOL
CBNumber: CB7853148
Molecular Formula: C5H12O
Formula Weight: 88.15
MOL File: 1565-80-6.mol

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(S)-(-)-2-Methyl-1-butanol Property

Melting point:: -70 °C
alpha: -5.8 º (neat 23 ºC)
Boiling point:: 136-138 °C(lit.)
Density: 0.811 g/mL at 25 °C(lit.)
vapor density: 3 (vs air)
vapor pressure: 1 mm Hg ( 13.6 °C)
refractive index: n20/D 1.409(lit.)
Flash point:: 120 °F
storage temp.: 2-8°C
solubility: soluble in Chloroform, Ethanol
form: clear liquid
pka: 15.24±0.10(Predicted)
color: Colorless to Almost colorless
Odor: ethereal fresh
optical activity: [α]23/D 5.8°, neat
Water Solubility: 36 g/L (30 ºC)
Merck: 14,6030
BRN: 1718809
Dielectric constant: 15.8（20℃）
LogP: 1.223 (est)
CAS DataBase Reference: 1565-80-6(CAS DataBase Reference)
NIST Chemistry Reference: 1-Butanol, 2-methyl-, (S)-(1565-80-6)
EPA Substance Registry System: 1-Butanol, 2-methyl-, (2S)- (1565-80-6)

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Safety

Hazard Codes: Xn
Risk Statements: 10-20-37-66-2017/10/20
Safety Statements: 46-24/25
RIDADR: UN 1105 3/PG 3
WGK Germany: 1
RTECS: SB9800000
HazardClass: 3
PackingGroup: III
HS Code: 29051990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H226Flammable liquid and vapour

H332Harmful if inhaled

H335May cause respiratory irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 65980
Product name: (S)-(?)-2-Methylbutanol
Purity: ≥95.0% (sum of enantiomers, GC)
Packaging: 100ml
Price: $96.9
Updated: 2024/03/01

Sigma-Aldrich

Product number: 65980
Product name: (S)-(?)-2-Methylbutanol
Purity: ≥95.0% (sum of enantiomers, GC)
Packaging: 500ml
Price: $164.8
Updated: 2024/03/01

TCI Chemical

Product number: M0170
Product name: (S)-(-)-2-Methyl-1-butanol
Purity: >98.0%(GC)
Packaging: 25mL
Price: $98
Updated: 2024/03/01

Sigma-Aldrich

Product number: A83407
Product name: (S)-(?)-2-Methylbutanol
Purity: 99%
Packaging: 10g
Price: $119
Updated: 2024/03/01

TRC

Product number: M295215
Product name: (S)-(-)-2-Methylbutanol
Packaging: 5g
Price: $55
Updated: 2021/12/16

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(S)-(-)-2-Methyl-1-butanol Chemical Properties,Usage,Production

Chemical Properties

clear colourless liquid

Uses

(S)-(-)-2-Methylbutanol can be used as a reactant to prepare:

Methylbutyl-2-(3-thienyl)acetate (MBTA) by esterification reaction with 3-thiophene acetic acid in the presence of an acid catalyst.
(2S)-2-Methyl-1-butanesulfenyl chloride by reacting with thioacetic acid using Mitsunobu reaction conditions.
(+)-Violapyrone C and (-)-myxalamide A.

Uses

(S)-(?)-2-Methylbutanol can be used to prepare:

(S)-(?)-2-Methyl-1-butyloxy carbonyl amino hexyl isocyanate (MBI), which is used to synthesize isocyanate copolymers.
Chiral alkoxynaphathoic acid derivatives having liquid crystalline properties.
3,4-Bis[(S)-2-methylbutoxy]thiophene, a key intermediate for the synthesis of polythiophenes.

Definition

ChEBI: The (S)-enantiomer of 2-methylbutan-1-ol.

General Description

rest mainly 3-methyl-1-butanol

Purification Methods

Reflux the butanol with CaO, distil, reflux with magnesium and again fractionally distil it. A small sample of highly purified material is obtained by fractional crystallisation after conversion into a suitable ester such as the trinitrophthalate or the 3-nitrophthalate. The latter is converted to the cinchonine salt in acetone and recrystallised from CHCl3 by adding pentane. The salt is saponified, extracted with ether, and fractionally distilled. [Terry et al. J Chem Eng Data 5 403 1960, Beilstein 1 IV 1666.]

(S)-(-)-2-Methyl-1-butanol Preparation Products And Raw materials

Raw materials

(S)-(+)-2-Methylbutyric acid Sodium borohydride Tetrahydrofuran Ethyl acetate Lithium Aluminum Hydride

Preparation Products

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View Lastest Price from (S)-(-)-2-Methyl-1-butanol manufacturers

Zhuozhou Wenxi import and Export Co., Ltd

Product: (S)-(-)-2-Methylbutanol >=95.0% (sum of enantiomers, GC) 1565-80-6
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-06-27

Career Henan Chemical Co

Product: (S)-(-)-2-Methyl-1-butanol 1565-80-6
Price: US $6.60/KG
Min. Order: 1KG
Purity: 97%-99%
Supply Ability: 1kg-1000kg
Release date: 2019-12-26

1565-80-6, (S)-(-)-2-Methyl-1-butanolRelated Search:

2-Methyl-1-propanol 5-Amino-2-methylpyridine 2,6-Lutidine 2-Chloro-5-chloromethylpyridine 2,5-Dimethylpyridine Potassium tert-butoxide tert-Butanol Kresoxim-methyl Ethambutol 2,6-Dimethylphenol Methyl salicylate 1-Methylimidazole Tribenuron methyl Thiophanate-methyl 1-Butanol Methyl 3-Methyl-1-butanol Methyl bromide

(S)-2-Methyl-1-butanol,99%e.e.

(S)-(-)-2-Methylbutanol >=95.0% (suM of enantioMers, GC)

(S)-(-)-2-Methylbutanol 99%

(s)-1-butano

(S)-2-methyl-butan-1-ol

AMYL ALCOHOL, N-

AMYL ALCOHOL

AMYL ALCOHOL, NORMAL

ALCOHOL C5

1-PENTANOL ALCOHOL

1-PENTYL ALCOHOL

FUSEL OIL

FEMA 2056

BUTYLCARBINOL

PRI-N-AMYL ALCOHOL

(S)-(-)-2-Methyl-1-butanol

(S)-(-)-2-Methylbutanol

(S)-(-)-sec-Butylcarbinol

1-Butanol, 2-methyl-, (2S)-

(S)-(-)-2-Methyl-1-butanol, 98+%

(S)-(-)-2-Methyl-1-butanol, Active amyl alcohol

Active amyl alcohol, Prim. active amyl alcohol

(2S)-2-Methyl-1-butanol

(2S)-2-Methylbutane-1-ol

(S)-(-)-2-Methyl-1-butanol,99%

D-2-METHYL-1-BUTANOL, ROT.-4.5 degrees

3-(4-((S)-()-2-Methyl-1-butanol

active-Amyl Alcohol sec-Butylcarbinol

N-BUTYLCARBINOL

N-PENTYL ALCOHOL

N-PENTANOL

WATER STANDARD, AMYL ALCOHOL

L-pentanol

(S)-(-)-2-Methyl-1-butanol&gt

1565-80-6

71410

30899195

Monofunctional Alkanes

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