ChemicalBook > CAS DataBase List > 2-Bromophenol

2-Bromophenol

Product Name
2-Bromophenol
CAS No.
95-56-7
Chemical Name
2-Bromophenol
Synonyms
O-BROMOPHENOL;Phenol, 2-bromo-;NSC 6970;2-Bromfenol;2-BROMOPHENOL;o-bromo-pheno;2-bromo-pheno;2-bromophenol-d;Phenol, o-bromo-;2- broMinephenol
CBNumber
CB7854701
Molecular Formula
C6H5BrO
Formula Weight
173.01
MOL File
95-56-7.mol
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2-Bromophenol Property

Melting point:
5 °C
Boiling point:
195 °C(lit.)
Density 
1.492 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.589(lit.)
Flash point:
108 °F
storage temp. 
Flammables area
solubility 
Chloroform (Slightly), Methanol (Slightly)
form 
Liquid
pka
8.45(at 25℃)
color 
Clear colorless to slightly yellow
Water Solubility 
soluble
Sensitive 
Light Sensitive
Merck 
14,1428
BRN 
1905115
CAS DataBase Reference
95-56-7(CAS DataBase Reference)
NIST Chemistry Reference
Phenol, 2-bromo-(95-56-7)
EPA Substance Registry System
o-Bromophenol (95-56-7)
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Safety

Hazard Codes 
Xn,F,Xi
Risk Statements 
10-22-36/37/38
Safety Statements 
16-36/37/39-37/39-26-36
RIDADR 
UN 1993 3/PG 3
WGK Germany 
3
RTECS 
SJ7875000
F 
8-10-23
Hazard Note 
Irritant
TSCA 
Yes
HazardClass 
3.2
PackingGroup 
III
HS Code 
29081000
Hazardous Substances Data
95-56-7(Hazardous Substances Data)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H226Flammable liquid and vapour

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

H400Very toxic to aquatic life

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P273Avoid release to the environment.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
130915
Product name
2-Bromophenol
Purity
98%
Packaging
10g
Price
$74.6
Updated
2024/03/01
Sigma-Aldrich
Product number
8.04166
Product name
2-Bromophenol
Purity
for synthesis
Packaging
25mL
Price
$139
Updated
2024/03/01
Sigma-Aldrich
Product number
130915
Product name
2-Bromophenol
Purity
98%
Packaging
50g
Price
$328
Updated
2024/03/01
TCI Chemical
Product number
B0630
Product name
2-Bromophenol
Purity
>98.0%(GC)(T)
Packaging
25g
Price
$36
Updated
2024/03/01
TCI Chemical
Product number
B0630
Product name
2-Bromophenol
Purity
>98.0%(GC)(T)
Packaging
100g
Price
$108
Updated
2024/03/01
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2-Bromophenol Chemical Properties,Usage,Production

Description

2-Bromophenol is an organic substance in which the C2 position of the benzene ring is replaced by a bromine, also known as o-bromophenol.

Chemical Properties

Clear colorless to slightly yellow liquid.Soluble in chloroform and ether.

Uses

2-Bromophenol is used in organic synthesis to prepare anti-benzofurandiimideand 1-bromodibenzodioxin. It can also be used as a disinfectant.

Definition

ChEBI: 2-bromophenol is a bromophenol. It has a role as a marine metabolite.

Toxicology

2-Bromophenol is moderately acutely orally toxic to mice, and it exhibits strong irritant properties.

Synthesis

To a stirred solution of appropriate organoboronic acids (0.5 mmol, 1.0 equiv.) and Et3N(1.0 mmol, 2.0 equiv.) in CH3CN(acetonitrile: 3 mL, H2O: 11μL, 0.6mmol, 1.2 equiv.), DAIB (0.75 mmol, 1.5 equiv.),dissolved in acetonitrile (2mL) was added drop wise at room temperature and the mixture was allowed to stir for 10 minutes at that temperature. After completion of the reaction indicated by TLC, the reaction mixture was washed with distilled water (3×7 mL) and extracted with CH2Cl2(3×10 mL). The combined organic phase was dried over Na2SO4 and after evaporating the solvent, the residue was purified by column chromatography over silica gel using hexane/EtOAc as eluent to provide the pure target product 2-Bromophenol.

2-Bromophenol Preparation Products And Raw materials

Raw materials

Preparation Products

2-ISOPROPOXYPHENYLBORONIC ACID 2,3-Dihydrobenzo[b]furan-5-carbaldehyde 2-Benzyloxyphenylboronic acid
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View Lastest Price from 2-Bromophenol manufacturers

Shanghai Bojing Chemical Co.,Ltd.
Product
2-Bromophenol 95-56-7
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
10ton
Release date
2024-01-05
SHAANXI LIGHTE OPTOELECTRONICS MATERIAL CO., LTD
Product
2-Bromophenol 95-56-7
Price
US $0.00-0.00/Kg
Min. Order
1Kg
Purity
98%
Supply Ability
20 tons
Release date
2023-01-13
Hebei Miaobian Biotechnology Co., Ltd
Product
2-Bromophenol 95-56-7
Price
US $10.00/KG
Min. Order
1KG
Purity
99.99
Supply Ability
10Ton
Release date
2021-03-17

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