ChemicalBook > CAS DataBase List > 1,2,4,5-Tetrachlorobenzene

1,2,4,5-Tetrachlorobenzene

Product Name
1,2,4,5-Tetrachlorobenzene
CAS No.
95-94-3
Chemical Name
1,2,4,5-Tetrachlorobenzene
Synonyms
1,2,4,5-tcb;1.2.4.5-Tetrac;TETRACHLOROBENZOL;rcrawastenumberu207;ethenyl trichloride;s-Tetrachlorobenzene;benzenetetrachloride;1,2,4,5-Tetrachlorob;Purity(GC) min. 99.0 %;Rcra waste number U207
CBNumber
CB7854716
Molecular Formula
C6H2Cl4
Formula Weight
215.89
MOL File
95-94-3.mol
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1,2,4,5-Tetrachlorobenzene Property

Melting point:
139 °C
Boiling point:
240-246 °C(lit.)
Density 
1.858
vapor pressure 
5 at 25 °C (extrapolated, Mackay et al., 1982)
refractive index 
1.5348 (estimate)
Flash point:
>230 °F
storage temp. 
0-6°C
solubility 
0.0003g/l
form 
Crystalline Solid
color 
Light pink to gray
Water Solubility 
insoluble. <0.1 g/100 mL at 21 ºC
BRN 
1618315
Henry's Law Constant
0.10 at 20 °C (gas stripping-GC, Oliver, 1985)
Stability:
Stable. Combustible. Incompatible with strong oxidizing agents. Reacts explosively with alkaline methanol solutions.
CAS DataBase Reference
95-94-3(CAS DataBase Reference)
NIST Chemistry Reference
Benzene, 1,2,4,5-tetrachloro-(95-94-3)
EPA Substance Registry System
1,2,4,5-Tetrachlorobenzene (95-94-3)
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Safety

Hazard Codes 
Xn,T,F,N
Risk Statements 
22-36/37/38-23/24/25-11-36-20/21/22-51/53
Safety Statements 
26-36-45-27-16-36/37-61
RIDADR 
UN 3077 9/PG 3
WGK Germany 
3
RTECS 
DB9450000
TSCA 
Yes
HazardClass 
9
HS Code 
29036990
Hazardous Substances Data
95-94-3(Hazardous Substances Data)
Toxicity
Acute oral LD50 for rats 1,500 mg/kg, mice 1,035 mg/kg (quoted, RTECS, 1985).
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P273Avoid release to the environment.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
131857
Product name
1,2,4,5-Tetrachlorobenzene
Purity
98%
Packaging
5g
Price
$24.6
Updated
2024/03/01
TCI Chemical
Product number
T0060
Product name
1,2,4,5-Tetrachlorobenzene
Packaging
25G
Price
$39
Updated
2024/03/01
TCI Chemical
Product number
T0060
Product name
1,2,4,5-Tetrachlorobenzene
Packaging
500G
Price
$157
Updated
2024/03/01
Alfa Aesar
Product number
A14318
Product name
1,2,4,5-Tetrachlorobenzene, 98%
Packaging
10g
Price
$29.4
Updated
2024/03/01
Alfa Aesar
Product number
A14318
Product name
1,2,4,5-Tetrachlorobenzene, 98%
Packaging
50g
Price
$100
Updated
2024/03/01
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1,2,4,5-Tetrachlorobenzene Chemical Properties,Usage,Production

Chemical Properties

white solid

Uses

Intermediate for herbicides and defoliants, insecticide, impregnant for moisture resistance, electrical insulation.

Uses

1,2,4,5-Tetrachlorobenzene was used to study the environmental behavior of hexachlorobutadiene (HCBD).

Definition

ChEBI: A tetrachlorobenzene carrying chloro groups at positions 1, 2, 4 and 5.

Environmental Fate

Biological. A mixed culture of soil bacteria or a Pseudomonas sp. transformed 1,2,4,5- tetrachlorobenzene to 2,3,5,6-tetrachlorophenol (Ballschiter and Scholz, 1980). After incubation in sewage sludge for 32 d under anaerobic conditions, 1,2,4,5-tetrachlorobenzene did not biodegrade (Kirk et al., 1989).
In an enrichment culture derived from a contaminated site in Bayou d’Inde, LA, 1,2,4,5- tetrachlorobenzene underwent reductive dechlorination to 1,2,4-trichlorobenzene. The maximum dechlorination rate, based on the recommended Michaelis-Menten model, was 5.5 nM/d (Pavlostathis and Prytula, 2000).
Photolytic. Irradiation (λ ≥285 nm) of 1,2,4,5-tetrachlorobenzene (1.1–1.2 mM/L) in an acetonitrile-water mixture containing acetone (0.553 mM) as a sensitizer gave the following products (% yield): 1,2,4-trichlorobenzene (25.3), 1,3-dichlorobenzene (8.1), 1,4-dichlorobenzene (3.6), 2,2′,3,4′,5,5′,6-heptachlorobiphenyl (4.19), four hexachlorobiphenyls (6.78), four pentachlorobiphenyls (2.33), one tetrachlorobiphenyl (0.32), 2,4,5-trichloroacetophenone, and (2,4,5- trichlorophenyl)acetonitrile (Choudhry and Hutzinger, 1984). Without acetone, the identified photolysis products (% yield) included 1,2,4-trichlorobenzene (27.7), 1,3-dichlorobenzene (0.3), 1,4-dichlorobenzene (8.5), pentachlorobenzene (trace), 1,2,3,4-tetrachlorobenzene (0.45), 1,2,3,5- tetrachlorobenzene (1.11), 2,2′,3,4′,5,5′,6-heptahlorobiphenyl (1.24), three hexachlorobiphenyls (1.19), and four pentachlorobiphenyls (0.56) (Choudhry and Hutzinger, 1984). The sunlight irradiation of 1,2,4,5-tetrachlorobenzene (20 g) in a 100-mL borosilicate glass-stoppered Erlenmeyer flask for 28 d yielded 26 ppm heptachlorobiphenyl (Uyeta et al., 1976).
Chemical/Physical. Based on an assumed base-mediated 1% disappearance after 16 d at 85 °C and pH 9.70 (pH 11.26 at °C), the hydrolysis half-life was estimated to be >900 yr (Ellington et al., 1988).

Purification Methods

Crystallise it from EtOH, ether, *benzene, *benzene/EtOH or carbon disulfide. [Beilstein 5 IV 668.]

1,2,4,5-Tetrachlorobenzene Preparation Products And Raw materials

Raw materials

Preparation Products

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1,2,4,5-Tetrachlorobenzene Suppliers

Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
Shanghai Rory Fine Chemical Co., Ltd
Tel
0086-21-50702305
Fax
0086-21-50704994
Email
rorychem@hotmail.com
Country
China
ProdList
18
Advantage
65
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44688
Advantage
61
Capot Chemical Co., Ltd
Tel
+86 (0) 571 85 58 67 18
Fax
0086-571-85864795
Email
sales@capotchem.com
Country
China
ProdList
18207
Advantage
66
Beckmann-Kenko GmbH
Tel
+49 4241 9308 88
Fax
+49 4241 9308 89
Email
info@beckmann-kenko.com
Country
Germany
ProdList
478
Advantage
62
Shandong Xiya Chemical Co., Ltd
Tel
4009903999 13355009207
Fax
0539-6365991
Email
3007715519@qq.com
Country
China
ProdList
18738
Advantage
57
Syntechem Co.,Ltd
Tel
Fax
E-Mail Inquiry
Email
info@syntechem.com
Country
China
ProdList
12984
Advantage
57
Sichuan Kulinan Technology Co., Ltd
Tel
400-1166-196 18981987031
Fax
028-84555506 800101999
Email
cdhxsj@163.com
Country
China
ProdList
11707
Advantage
57
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View Lastest Price from 1,2,4,5-Tetrachlorobenzene manufacturers

Henan Fengda Chemical Co., Ltd
Product
1,2,4,5-Tetrachlorobenzene 95-94-3
Price
US $100.00-1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2023-12-26
Career Henan Chemical Co
Product
1,2,4,5-Tetrachlorobenzene 95-94-3
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
100KG
Release date
2020-01-09

95-94-3, 1,2,4,5-Tetrachlorobenzene Related Search:


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