methyl 4-methoxy-2-methylbenzoate
- Product Name
- methyl 4-methoxy-2-methylbenzoate
- CAS No.
- 35598-05-1
- Chemical Name
- methyl 4-methoxy-2-methylbenzoate
- Synonyms
- Methyl 2-Methyl-p-anisate;Methyl 4-Methoxy-o-toluate;methyl 4-methoxy-2-methylbenzoate;2-Methyl-p-anisic Acid Methyl Ester;4-Methoxy-o-toluic Acid Methyl Ester;2-methyl-4-methoxybenzoic acid methyl ester;Benzoic acid, 4-Methoxy-2-Methyl-, Methyl ester
- CBNumber
- CB7947096
- Molecular Formula
- C10H12O3
- Formula Weight
- 180.2
- MOL File
- 35598-05-1.mol
methyl 4-methoxy-2-methylbenzoate Property
- Boiling point:
- 98°C/0.5mmHg(lit.)
- Density
- 1.075±0.06 g/cm3(Predicted)
- refractive index
- 1.5360 to 1.5400
- storage temp.
- Sealed in dry,Room Temperature
- form
- clear liquid
- color
- White to Light yellow
- InChI
- InChI=1S/C10H12O3/c1-7-6-8(12-2)4-5-9(7)10(11)13-3/h4-6H,1-3H3
- InChIKey
- OGYAVWKYDVBIMW-UHFFFAOYSA-N
- SMILES
- C(OC)(=O)C1=CC=C(OC)C=C1C
Safety
- HS Code
- 2918999090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P332+P313IF SKIN irritation occurs: Get medical advice/attention.
P337+P313IF eye irritation persists: Get medical advice/attention.
N-Bromosuccinimide Price
- Product number
- M2889
- Product name
- Methyl 4-Methoxy-2-methylbenzoate
- Purity
- >98.0%(GC)
- Packaging
- 1g
- Price
- $38
- Updated
- 2025/07/31
- Product number
- M2889
- Product name
- Methyl 4-Methoxy-2-methylbenzoate
- Purity
- >98.0%(GC)
- Packaging
- 5g
- Price
- $191
- Updated
- 2025/07/31
- Product number
- M338518
- Product name
- Methyl 4-Methoxy-2-methylbenzoate
- Packaging
- 100mg
- Price
- $60
- Updated
- 2021/12/16
- Product number
- M338518
- Product name
- Methyl 4-Methoxy-2-methylbenzoate
- Packaging
- 500mg
- Price
- $130
- Updated
- 2021/12/16
- Product number
- 7404AH
- Product name
- Methyl 4-Methoxy-2-methylbenzoate
- Packaging
- 1g
- Price
- $60
- Updated
- 2021/12/16
methyl 4-methoxy-2-methylbenzoate Chemical Properties,Usage,Production
Synthesis
67-56-1
6245-57-4
35598-05-1
Thionyl chloride (1.3 mL, 17.8 mmol) was added slowly and dropwise to a stirred mixed solution of 4-methoxy-2-methylbenzoic acid (1.0 g, 6 mmol) and methanol (50 mL) at room temperature and under nitrogen protection. The reaction mixture was heated to reflux and maintained for 3 hours. Upon completion of the reaction, the mixture was cooled to room temperature and concentrated under reduced pressure to give a light yellow crude product. The crude product was purified by silica gel column chromatography with the eluent of petroleum ether: ethyl acetate (9:1, v/v) to afford methyl 4-methoxy-2-methylbenzoate (1.11 g, 100% yield) in colorless liquid form. The product was characterized by 1H NMR (400 MHz, DMSO-d6) and ESI-MS: 1H NMR δ 7.81 (d, J = 9 Hz, 1H), 6.86 (d, J = 3 Hz, 1H), 6.83 (dd, J = 9, 3 Hz, 1H), 3.78 (s, 3H), 3.75 (s, 3H), 2.49 (s, 3H); ESI -MS m/z 181 ([M+H]+).
References
[1] Patent: WO2009/5998, 2009, A1. Location in patent: Page/Page column 214
[2] Patent: WO2004/14856, 2004, A1. Location in patent: Page 9; 14
[3] Patent: WO2008/20306, 2008, A2. Location in patent: Page/Page column 35
[4] Journal of Medicinal Chemistry, 2013, vol. 56, # 21, p. 8561 - 8578
[5] Tetrahedron, 2018, vol. 74, # 2, p. 224 - 239
methyl 4-methoxy-2-methylbenzoate Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from methyl 4-methoxy-2-methylbenzoate manufacturers
- Product
- methyl 4-methoxy-2-methylbenzoate 35598-05-1
- Price
- US $0.00/kg
- Min. Order
- 20kg
- Purity
- 99%
- Supply Ability
- 20 tons
- Release date
- 2025-05-06