4,4'-Methylenebis(2-methylcyclohexylamine)

Product Name: 4,4'-Methylenebis(2-methylcyclohexylamine)
CAS No.: 6864-37-5
Chemical Name: 4,4'-Methylenebis(2-methylcyclohexylamine)
Synonyms: DMDC;MACM;DMDC/MACM;MACM 、DMDC;Dimethyldicycan;DIMETHYLDICYANE;Laromin C diamine;2'-Deoxy-2'-methylenecytidine;DMDC diaminodicyclohexylmethane;2'-C-Methylene-2'-deoxycytidine
CBNumber: CB8117052
Molecular Formula: C15H30N2
Formula Weight: 238.41
MOL File: 6864-37-5.mol

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4,4'-Methylenebis(2-methylcyclohexylamine) Property

Melting point:: -7°C
Boiling point:: 93-100 °C(lit.)
Density: 0.94 g/mL at 25 °C(lit.)
vapor pressure: 0.08Pa at 20℃
refractive index: n20/D 1.499(lit.)
Flash point:: >230 °F
storage temp.: Keep in dark place,Inert atmosphere,Room temperature
solubility: 3.6g/l
form: clear liquid
pka: 11.03±0.70(Predicted)
color: Colorless to Light yellow to Light orange
PH: 11 (3.6g/l, H2O, 20℃)
explosive limit: 0.5-2.8%(V)
Water Solubility: 2.01g/L at 20℃
InChIKey: IGSBHTZEJMPDSZ-UHFFFAOYSA-N
LogP: 2.3 at 23℃
CAS DataBase Reference: 6864-37-5(CAS DataBase Reference)
EPA Substance Registry System: Cyclohexanamine, 4,4'-methylenebis[2-methyl- (6864-37-5)

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Safety

Hazard Codes: T,C,N
Risk Statements: 22-23/24-35-51/53
Safety Statements: 26-36/37/39-45-61
RIDADR: UN 2927 6.1/PG 2
WGK Germany: 3
HazardClass: 8
PackingGroup: II
HS Code: 29213000
Toxicity: LC50 ihl-rat: 420 mg/m3/4H NTIS** OTS0539620-1

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H302Harmful if swallowed

H311Toxic in contact with skin

H314Causes severe skin burns and eye damage

H330Fatal if inhaled

H411Toxic to aquatic life with long lasting effects

Precautionary statements

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 369500
Product name: 4,4′-Methylenebis(2-methylcyclohexylamine), mixture of isomers
Purity: 99%
Packaging: 250ml
Price: $63.6
Updated: 2024/03/01

Sigma-Aldrich

Product number: 369500
Product name: 4,4′-Methylenebis(2-methylcyclohexylamine), mixture of isomers
Purity: 99%
Packaging: 1l
Price: $287
Updated: 2024/03/01

TCI Chemical

Product number: M1422
Product name: 4,4'-Methylenebis(2-methylcyclohexylamine) (mixture of isomers)
Purity: >99.0%(GC)
Packaging: 25mL
Price: $26
Updated: 2024/03/01

TCI Chemical

Product number: M1422
Product name: 4,4'-Methylenebis(2-methylcyclohexylamine) (mixture of isomers)
Purity: >99.0%(GC)
Packaging: 500mL
Price: $86
Updated: 2024/03/01

TRC

Product number: M304193
Product name: 4,4''-Methylenebis(2-methylcyclohexanamine)
Packaging: 5mL
Price: $45
Updated: 2021/12/16

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4,4'-Methylenebis(2-methylcyclohexylamine) Chemical Properties,Usage,Production

Chemical Properties

Colorless transparent viscous liquid

Chemical Properties

4,4'-Methylenebis(2-methylcyclohexylamine) (MACM) is a colorless/yellowish liquid with a water solubility of 3.6 g/l at 20°C and a vapor pressure of 0.08 Pa at 20°C. The measured log KOW is 2.51 at 25 °C. However, due to the Lewis base character of the substance, the experimental determination of the log KOW is inaccurate. The density of the substance (ca. 0.95 g/cm3 at 20°C) is virtually the same as that of water.

Uses

4,4'-Methylenebis(2-methylcyclohexylamine) can be used as epoxy curing agents.

Uses

4,4′-Methylenebis(2-methylcyclohexylamine) (MMCA) may be used:

in the synthesis of fully aliphatic polyimides
in the synthesis of fully aliphatic polyimide-siloxanes (APISiO)
to prepare epoxy resin with trimethylolpropane triglycidyl ether, used for the characterization of the structural organization in dragline silk by transmission X-ray microscopy (STXM).

General Description

4,4′-Methylenebis(2-methylcyclohexylamine) is an alicyclic diamine.

Hazard

Moderately toxic by inhalation.

Flammability and Explosibility

Non flammable

Safety Profile

Moderately toxic by inhalation.When heated to decomposition it emits toxic vapors ofNOx.

Synthesis

Add 2000kg 3,3'-dimethyl-4,4'-diaminodiphenylmethane and 2000kg tetrahydrofuran to an autoclave with a volume of 6000L. Then, 100Kg 5% Ru/Al2O3 catalyst and 100Kg aluminum ammonium sulfate will be added, and the air in the autoclave will be replaced with hydrogen after sealing. Pour in 6MPa hydrogen, heat the autoclave to 160°C, adjust the hydrogen valve to maintain the pressure at 8MPa, and stir vigorously for 4 hours. After cooling, samples were taken and detected by gas chromatography-mass spectrometry. The detection results showed that the conversion rate of 3,3'-dimethyl-4,4-diaminodicyclohexylmethane was 100%, and the 4,4'-Methylenebis(2-methylcyclohexylamine) (MACM) yield was 99.4%.

4,4'-Methylenebis(2-methylcyclohexylamine) Preparation Products And Raw materials

Raw materials

Preparation Products

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4,4'-Methylenebis(2-methylcyclohexylamine) Suppliers

Americas 1 Belgium 1 China 159 Europe 1 France 2 Germany 7 India 3 Japan 4 Switzerland 1 United Kingdom 3 United States 27 Global 209

SHENZHEN XUHUA BIOTECHNOLOGY CO., LTD.

Tel: 0755-28792436-813 15999518300
Email: szyexu@163.com
Country: China
ProdList: 5
Advantage: 58

Zhang Jia Gang YaRui Chemical co.,Ltd

Tel: 0512-58961066 18921980669
Fax: 86-0512-58961068
Email: sales@yaruichem.com
Country: China
ProdList: 35
Advantage: 64

Jiangsu Qingquan Chemical Co., Ltd.

Tel: 0571-86589382 13606766072;
Fax: 0571-86589383
Email: sales@qqpharm.com
Country: China
ProdList: 99
Advantage: 71

Tianjin Zhongxin Chemtech Co., Ltd.

Tel: 022-66880623
Fax: 86(0)22-66880086
Email: sales@tjzxchem.com
Country: China
ProdList: 613
Advantage: 60

J & K SCIENTIFIC LTD.

Tel: 010-82848833 400-666-7788
Fax: 86-10-82849933
Email: jkinfo@jkchemical.com
Country: China
ProdList: 94657
Advantage: 76

Meryer (Shanghai) Chemical Technology Co., Ltd.

Tel: 021-61259108 18621169109
Fax: 86-21-61259102
Email: market03@meryer.com
Country: China
ProdList: 40228
Advantage: 62

TCI (Shanghai) Development Co., Ltd.

Tel: 021-67121386
Fax: 021-67121385
Email: Sales-CN@TCIchemicals.com
Country: China
ProdList: 24529
Advantage: 81

Ark Pharm, Inc.

Tel: 847-367-3680
Fax: 847-367-3681
Email: sales@arkpharminc.com
Country: United States
ProdList: 1670
Advantage: 56

Shanghai Hanhong Scientific Co.,Ltd.

Tel: 021-54306202 13764082696
Email: info@hanhongsci.com
Country: China
ProdList: 42958
Advantage: 64

Beijing Isomersyn Technology CO;LTD

Tel: 010-82954736 13391601435
Email: sales@isomersyn.com
Country: China
ProdList: 3295
Advantage: 57

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View Lastest Price from 4,4'-Methylenebis(2-methylcyclohexylamine) manufacturers

Hebei Weibang Biotechnology Co., Ltd

Product: 4,4'-METHYLENEBIS(2-METHYLCYCLOHEXYLAMINE) 6864-37-5
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 500000kg
Release date: 2024-11-01

Hebei Yanxi Chemical Co., Ltd.

Product: 4,4'-METHYLENEBIS(2-METHYLCYCLOHEXYLAMINE) 6864-37-5
Price: US $30.00-11.00/kg
Min. Order: 1kg
Purity: 0.99
Supply Ability: 10 tons
Release date: 2023-11-17

Hebei Chuanghai Biotechnology Co,.LTD

Product: 4,4'-Methylenebis(2-methylcyclohexylamine) 6864-37-5
Price: US $50.00-20.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10000kg
Release date: 2024-08-23

6864-37-5, 4,4'-Methylenebis(2-methylcyclohexylamine)Related Search:

Dimethyl carbonate Dimethyl fumarate Tris(hydroxymethyl)aminomethane Dimethyl phthalate Dimethyl ether ETHANE Dimethyl sulfoxide Dimethyl sebacate 4,4'-Methylenedianiline Dicyclohexyl phthalate N,N-Dimethyl-1,4-phenylenediamine N,N-Dimethylformamide Dicyclohexylcarbodiimide 4,4'-Diaminodicyclohexyl methane 2-Methylcyclohexylamine 4-ETHYL-CYCLOHEXYLAMINE CYCLOHEXANAMINE, 4-PENTYL- 4-Methylcyclohexyl amine

3,3’-Dimethyl-4,4’-diaminodicyclohexylmethane

4,4'-DiaMino-3,3'-diMethyldicyclohexylMethane(Mixture of isoMers)

MACM

4,4’-methylenebis[2-methyl-cyclohexanamin

4,4’-methylenebis[2-methyl-Cyclohexanamine

4-[(4-amino-3-methylcyclohexyl)methyl]-2-methylcyclohexan-1-amine

3,3'-Dimethyl-4,4'-diaminodicyclohexylmethane(MACM)

4,4'-Methylenebis(2-methylcyclohexylamine), mixture of isomers 99%

3,3-Diamethyl-4,4-diaminodicyclohexylmethane

4,4'-4,4'-Methylenebis(cyclohexyl-amine) mix. Isomers

4,4'-Methylenebis(2-methylcyclohexylamine) (mixture of isomers) for synthesis

dimethyldicyane 2,2'-dimethyl-4,4'-methylenebis(cyclohexylamine)

DMDC diaminodicyclohexylmethane

Cycloaliphatic amine curing agent Chain extender DACM, MACM, 3,3'-dimethyl-4,4-diaminodicyclohexylmethane

BIS(4-AMINO-3-METHYLCYCLOHEXYL)METHANE

2,2'-DIMETHYL-4,4'-METHYLENEBIS(CYCLOHEXYLAMINE)

4,4'-DIAMINO-3,3'-DIMETHYLDICYCLOHEXYLMETHANE

4,4'-METHYLENEBIS(1-AMINO-2-METHYLCYCLOHEXANE)

4,4'-METHYLENEBIS(2-METHYLCYCLOHEXYLAMINE)

di(4-amino-3-methylcyclohexyl)methane

4,4'-METHYLENEBIS(2-METHYLCYCLOHEXYL-AMI NE), 99%, MIXTURE OF ISOMERS

4,4'-Methylenebis(2-methylcyclohexylamine)4,4'-methylenebis(2-methylcyclohexylamine)(mixtureofisomers)

Bis[3-methyl-4-aminocyclohexyl] methane

Cyclohexanamine, 4,4-methylenebis2-methyl-

4,4'-methylenebis(2-methylcyclohexylamine), mixture of isomers

Dimethyldicycan

DIMETHYLDICYANE

4,4''-METHYLENEBIS(2-METHYLCYCLOHEXYLAMINE) (MIXTURE OF ISOMERS) 98+%

DMDC

2,2'-Dimethyl[4,4'-methylenebis(cyclohexane-1-amine)]

4,4'-Methylenebis(2-methyl-1-cyclohexanamine)

Laromin C diamine

2'-C-Methylene-2'-deoxycytidine

2'-Deoxy-2'-methylenecytidine

4,4'-METHYLENEBIS(2-METHYLCYCLOHEXANEAMINE)

Bis(4-amino-3-methylcyclohexyl)methane 4,4'-Diamino-3,3'-dimethyldicyclohexylmethane 4,4'-Methylenebis(1-amino-2-methylcyclohexane)

4,4'-Methylenebis(2-MethylcyclohexylaMine)&nbsp

4,4'-DIAMINO-3,3'-DIMETHYLDICYCLOHEX

4,4'-Methylenebis(2-methylcyclohexylamine) 6864-37-5 Dimethyldicyane

6864-37-5 Dimethyldicyane DMDC

4,4'-Methylenebis(2-methylcyclohexylamine)(mixtureofisomers)&gt

DMDC/MACM

4,4′-Methylenebis(2-methylcyclohexylamine), mixture of isomers ,99%

,3-Diamethyl-4,4-diaminodicyclohexylmethane (CAS NO: 6864-37-5)

4,4'-methylenebis(2-methylcyclohexan-1-amine)

MACM/DMDC 3,3'-Dimethyl-4,4'-diaminodicyclohexylmethane

MACM 、DMDC

4,4'-METHYLENEBIS(2-METHYLCYCLOHEXYLAMINE)

4,4'-Methylenebis(2-methylcyclohexylamine) (mixture of isomers)

3,3'-Dimethyl-4,4'-diaminodicyclohexylmethane（MACM）

4,4'-Methylenebis(2-methylcyclohexanamine)

3,3'-Dimethyl-4,4'-diaminodicyclohexylmethane

6864-37-5

6868-37-5

CH2C6H9CH3NH22

Building Blocks

Organic Building Blocks

Nitrogen Compounds