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(S,S)-2,3-Butanediol

Description Reference
Product Name
(S,S)-2,3-Butanediol
CAS No.
19132-06-0
Chemical Name
(S,S)-2,3-Butanediol
Synonyms
2,3-BUTANEDIOL, [S-(R*,R*)]-;(2S,3S)-Butane-2,3-diol;(S-(R,R))-butane-2,3-diol;L-Butane-2,3-diol;L(+)-2,3-BUTANEDIOL;(S,S)-2,3-BUTANEDIOL;2S,3S-(+)-Butanediol;(S,S)-Butane-2,3-diol;(2S,3S)-2,3-BUTANEDIOL;(2S,3S)-Butan-2,3-diol
CBNumber
CB8117911
Molecular Formula
C4H10O2
Formula Weight
90.12
MOL File
19132-06-0.mol
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(S,S)-2,3-Butanediol Property

Melting point:
20°C
alpha 
13 º (c=neat)
Boiling point:
179-182 °C (lit.)
Density 
0.987 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.433
Flash point:
185 °F
storage temp. 
2-8°C
solubility 
Chloroform (Slightly), Methanol (Slightly)
pka
14.67±0.20(Predicted)
form 
Oily Liquid
color 
Slightly yellow
Specific Gravity
0.987
PH
9-10 (500g/l, H2O, 20℃)
explosive limit
3.1-11.4%(V)
optical activity
[α]20/D +13°, neat
Water Solubility 
soluble
BRN 
1718899
Stability:
hygroscopic
LogP
-0.655 (est)
CAS DataBase Reference
19132-06-0(CAS DataBase Reference)
NIST Chemistry Reference
2,3-Butanediol, [S-(R*,R*)]-(19132-06-0)
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Safety

Hazard Codes 
Xi
Safety Statements 
24/25
RIDADR 
NA 1993 / PGIII
WGK Germany 
3
HS Code 
29053995
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H227Combustible liquid

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P370+P378In case of fire: Use … for extinction.

P403+P235Store in a well-ventilated place. Keep cool.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
18967
Product name
L-(+)-2,3-Butanediol
Purity
for chiral derivatization, ≥97.0%
Packaging
1ml
Price
$232
Updated
2022/05/15
Sigma-Aldrich
Product number
18967
Product name
L-(+)-2,3-Butanediol
Purity
for chiral derivatization, ≥97.0%
Packaging
5ml
Price
$795
Updated
2022/05/15
TCI Chemical
Product number
B1343
Product name
(S,S)-(+)-2,3-Butanediol
Purity
>97.0%(GC)
Packaging
1g
Price
$123
Updated
2024/03/01
TCI Chemical
Product number
B1343
Product name
(S,S)-(+)-2,3-Butanediol
Purity
>97.0%(GC)
Packaging
100mg
Price
$22
Updated
2024/03/01
Strem Chemicals
Product number
08-0201
Product name
(2S,3S)-(+)-2,3-Butanediol, min. 97%
Packaging
100mg
Price
$31
Updated
2024/03/01
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(S,S)-2,3-Butanediol Chemical Properties,Usage,Production

Description

2, 3-Butanediol, which is very important for a variety of chemical feedstocks and liquid fuels, can be derived from the bioconversion of natural resources1-2. It may be used in the production of antifreeze solvents, extraction solvents, butadiene, polymers, polyurethane and diacetyl and may also be used as a fuel1, 2. It can be used as a precursor in the manufacture of a range of chemical products, various plastics and pesticides, including the solvents methyl ethyl ketone (MEK), gamma-butyrolactone (GBL), and 1, 3-butadiene3. Methyl ethyl ketone can be used as a liquid fuel additive. Many other derivatives for potential uses as antifreeze agent (levo-form of 2,3 BDL), solvents, and plastic can also be prepared from 2.3-BDL. Furthermore, it can be added as a flavoring agent in food products when converted to a diacetyl by dehydrogenation2. Nowadays, it has been more and more applied of microbial fermentation for the production of 2.3-BDL2,4.

Reference

  1. https://www.sigmaaldrich.com/catalog/product/sial/18967?lang=en&region=US
  2. Lee, Jinwon, et al. "Biological production of 2,3-butanediol." Applied Microbiology & Biotechnology 55.1(2001):10-8.
  3. https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3147483/
  4. Oliver, John W. K., et al. "Cyanobacterial conversion of carbon dioxide to 2, 3-butanediol. PNAS 110.4(2013):1249-1254.

Chemical Properties

SLIGHTLY YELLOW OILY LIQUID

Uses

(S,S)-2,3-Butanediol is the (S,S)-isomer of 2,3-Butanediol (B690020), a naturally occurring compound found in cocoa butter.

Definition

ChEBI: The (S,S) diastereoisomer of butane-2,3-diol.

General Description

L-(+)-2,3-Butanediol is a stereoisomer of 2,3-Butanediol (2,3-BD). 2,3-BD may be used in the production of antifreeze solvents, extraction solvents, butadiene, polymers, polyurethane and diacetyl and may also be used as a fuel.

Purification Methods

Purify it by fractional distillation. The bis-(4-nitrobenzoate) has m 141-142o and [] (-) or (+) 52o (c 4 CHCl3). [Ghirardelli & Lucas J Am Chem Soc 79 734 1957, Rubin et al. J Am Chem Soc 74 425 1952, Neish Can J Res 27 6 1949, Neish & Ledingham Can J Res 27 694 1949, Beilstein 1 IV 2524-2525.]

(S,S)-2,3-Butanediol Preparation Products And Raw materials

Raw materials

Preparation Products

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(S,S)-2,3-Butanediol Suppliers

Carbosynth
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Tokyo Chemical Industry UK Ltd.
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Manchester Organics
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Apollo Scientific Ltd.
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Fluorochem Ltd
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VWR International
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View Lastest Price from (S,S)-2,3-Butanediol manufacturers

Hebei Chuanghai Biotechnology Co,.LTD
Product
(S S) -2 3-Butanediol 19132-06-0
Price
US $5.00-2.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10000kg
Release date
2024-08-15
Hangzhou ICH Biofarm Co., Ltd
Product
(S,S)-2,3-Butanediol 19132-06-0
Price
US $0.00-0.00/g
Min. Order
0.1g
Purity
>97.0%(GC)
Supply Ability
500kg
Release date
2023-06-29
Zhuozhou Wenxi import and Export Co., Ltd
Product
L-(+)-2,3-Butanediol 19132-06-0
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-06-27

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