ChemicalBook > CAS DataBase List > methyl-oxido-[[(2S,3R,4S,5R,6R)-3,4,5-trihydroxy-6-[[(2R,3R,4S,5R)-3,4 ,5-trihydroxyoxan-2-yl]oxymethyl]oxan-2-yl]oxymethylimino]azanium

methyl-oxido-[[(2S,3R,4S,5R,6R)-3,4,5-trihydroxy-6-[[(2R,3R,4S,5R)-3,4 ,5-trihydroxyoxan-2-yl]oxymethyl]oxan-2-yl]oxymethylimino]azanium

Product Name
methyl-oxido-[[(2S,3R,4S,5R,6R)-3,4,5-trihydroxy-6-[[(2R,3R,4S,5R)-3,4 ,5-trihydroxyoxan-2-yl]oxymethyl]oxan-2-yl]oxymethylimino]azanium
CAS No.
6327-93-1
Chemical Name
methyl-oxido-[[(2S,3R,4S,5R,6R)-3,4,5-trihydroxy-6-[[(2R,3R,4S,5R)-3,4 ,5-trihydroxyoxan-2-yl]oxymethyl]oxan-2-yl]oxymethylimino]azanium
Synonyms
Macrozemin;Macrozamin, 10 mM in DMSO;(Methyl-ONN-azoxy)methyl 6-O-β-D-xylopyranosyl-β-D-glucopyranoside;β-D-Glucopyranoside, (2-methyl-2-oxidodiazenyl)methyl 6-O-β-D-xylopyranosyl-;mutagenic,inhibit,carcinogenic,teratogenic,Macrozamin,Inhibitor,neurotoxic,Cycads;methyl-oxido-[[(2S,3R,4S,5R,6R)-3,4,5-trihydroxy-6-[[(2R,3R,4S,5R)-3,4 ,5-trihydroxyoxan-2-yl]oxymethyl]oxan-2-yl]oxymethylimino]azanium
CBNumber
CB81259779
Molecular Formula
C13H24N2O11
Formula Weight
384.34
MOL File
6327-93-1.mol
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methyl-oxido-[[(2S,3R,4S,5R,6R)-3,4,5-trihydroxy-6-[[(2R,3R,4S,5R)-3,4 ,5-trihydroxyoxan-2-yl]oxymethyl]oxan-2-yl]oxymethylimino]azanium Property

Melting point:
199-200 °C
Boiling point:
660.4±65.0 °C(Predicted)
Density 
1.86±0.1 g/cm3(Predicted)
storage temp. 
2-8°C
form 
Solid
pka
14.80±0.70(Predicted)
color 
White to off-white
SMILES
C/[N](O)=N/CO[C@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO[C@@H]2OC[C@@H](O)[C@H](O)[C@H]2O)O1
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Safety

WGK Germany 
WGK 3
Storage Class
11 - Combustible Solids
Hazard Classifications
Carc. 2
Muta. 2
Repr. 2
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H341Suspected of causing genetic defects

H351Suspected of causing cancer

Precautionary statements

P201Obtain special instructions before use.

P202Do not handle until all safety precautions have been read and understood.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P308+P313IF exposed or concerned: Get medical advice/attention.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

AvaChem
Product number
3873
Product name
Macrozamin
Packaging
5mg
Price
$125
Updated
2021/12/16
AvaChem
Product number
3873
Product name
Macrozamin
Packaging
10mg
Price
$225
Updated
2021/12/16
AvaChem
Product number
3873
Product name
Macrozamin
Packaging
25mg
Price
$425
Updated
2021/12/16
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methyl-oxido-[[(2S,3R,4S,5R,6R)-3,4,5-trihydroxy-6-[[(2R,3R,4S,5R)-3,4 ,5-trihydroxyoxan-2-yl]oxymethyl]oxan-2-yl]oxymethylimino]azanium Chemical Properties,Usage,Production

Uses

Macrozamin is a major constituent principle of Cycads. Macrozamin has carcinogenic, mutagenic, teratogenic and neurotoxic properties[1].

References

[1] Jerald J.Nair, et al. Isolation and quantification of the toxic methylazoxymethanol glycoside macrozamin in selected South African cycad species. South African Journal of Botany,Volume 82,September 2012, Pages 108-112.

methyl-oxido-[[(2S,3R,4S,5R,6R)-3,4,5-trihydroxy-6-[[(2R,3R,4S,5R)-3,4 ,5-trihydroxyoxan-2-yl]oxymethyl]oxan-2-yl]oxymethylimino]azanium Preparation Products And Raw materials

Raw materials

Preparation Products

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methyl-oxido-[[(2S,3R,4S,5R,6R)-3,4,5-trihydroxy-6-[[(2R,3R,4S,5R)-3,4 ,5-trihydroxyoxan-2-yl]oxymethyl]oxan-2-yl]oxymethylimino]azanium Suppliers

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6327-93-1, methyl-oxido-[[(2S,3R,4S,5R,6R)-3,4,5-trihydroxy-6-[[(2R,3R,4S,5R)-3,4 ,5-trihydroxyoxan-2-yl]oxymethyl]oxan-2-yl]oxymethylimino]azaniumRelated Search:


  • methyl-oxido-[[(2S,3R,4S,5R,6R)-3,4,5-trihydroxy-6-[[(2R,3R,4S,5R)-3,4 ,5-trihydroxyoxan-2-yl]oxymethyl]oxan-2-yl]oxymethylimino]azanium
  • (Methyl-ONN-azoxy)methyl 6-O-β-D-xylopyranosyl-β-D-glucopyranoside
  • β-D-Glucopyranoside, (2-methyl-2-oxidodiazenyl)methyl 6-O-β-D-xylopyranosyl-
  • mutagenic,inhibit,carcinogenic,teratogenic,Macrozamin,Inhibitor,neurotoxic,Cycads
  • Macrozamin, 10 mM in DMSO
  • Macrozemin
  • 6327-93-1
  • C13H24N2O11