3-(methylaminomethyl)benzonitrile

Product Name: 3-(methylaminomethyl)benzonitrile
CAS No.: 90389-96-1
Chemical Name: 3-(methylaminomethyl)benzonitrile
Synonyms: 3-(methylaminomethyl;3-Cyano-N-methylbenzylamine;N-Methyl-N-(3-cyanobenzyl)aMine;3-(methylaminomethyl)benzonitrile;3-(Methylaminomethyl)benzonitrile,95%;Benzonitrile, 3-[(methylamino)methyl]-
CBNumber: CB81456918
Molecular Formula: C9H10N2
Formula Weight: 146.19
MOL File: 90389-96-1.mol

More

Less

3-(methylaminomethyl)benzonitrile Property

Boiling point:: 145°C/15mmHg(lit.)
refractive index: 1.5400 to 1.5440
storage temp.: Keep in dark place,Inert atmosphere,Store in freezer, under -20°C
form: clear liquid
color: Colorless to Almost colorless

More

Less

Safety

RIDADR: UN 2922 8/6.1/PG II
HazardClass: 6.1
PackingGroup: II
HS Code: 2926907090

More

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H302Harmful if swallowed

H312Harmful in contact with skin

H315Causes skin irritation

H319Causes serious eye irritation

H332Harmful if inhaled

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

More

Less

N-Bromosuccinimide Price

TCI Chemical

Product number: M2869
Product name: 3-(Methylaminomethyl)benzonitrile
Purity: >98.0%(GC)(T)
Packaging: 1g
Price: $83
Updated: 2025/07/31

TCI Chemical

Product number: M2869
Product name: 3-(Methylaminomethyl)benzonitrile
Purity: >98.0%(GC)(T)
Packaging: 5g
Price: $247
Updated: 2025/07/31

TRC

Product number: M328345
Product name: 3-[(Methylamino)methyl]benzonitrile
Packaging: 100mg
Price: $90
Updated: 2021/12/16

AK Scientific

Product number: 5045AC
Product name: 3-((Methylamino)methyl)benzonitrile
Packaging: 250mg
Price: $117
Updated: 2021/12/16

AK Scientific

Product number: 5045AC
Product name: 3-((Methylamino)methyl)benzonitrile
Packaging: 1g
Price: $184
Updated: 2021/12/16

More

Less

3-(methylaminomethyl)benzonitrile Chemical Properties,Usage,Production

Uses

3-(Methylaminomethyl)benzonitrile is used as pharmaceutical intermediate.

Synthesis

74-89-5

28188-41-2

90389-96-1

Step 1: Anhydrous THF solution (20 mL) of 3-(bromomethyl)benzonitrile (5 g, 25.5 mmol, 1 eq.) was added to a 250 mL three-necked round-bottomed flask under nitrogen protection. A THF solution of methylamine (2 M, 63.76 mL, 127.52 mmol, 5 eq.) was added dropwise to the above solution over a period of 1 hr. The reaction mixture was stirred at room temperature for 2 hours. A small amount of bisbenzylated byproduct (7%) was observed during the reaction. Upon completion of the reaction, the mixture was filtered to remove the generated salt. The filtrate was concentrated under reduced pressure and the residue was dissolved in dichloromethane and evaporated again under reduced pressure to give N-methyl-3-cyanobenzylamine as a yellow oil (3.78 g, quantitative yield). The product could be used in the next reaction without further purification.LC/MS (Method B) showed that the molecular ion peak of the target product was 146.8 (M + H)+.

References

[1] Patent: WO2012/4287, 2012, A1. Location in patent: Page/Page column 93-94
[2] Patent: WO2007/124898, 2007, A1. Location in patent: Page/Page column 44-45
[3] Patent: WO2009/43889, 2009, A2. Location in patent: Page/Page column 166
[4] Patent: WO2010/112461, 2010, A1. Location in patent: Page/Page column 67
[5] Chemische Berichte, 1937, vol. 70, p. 1241,1249

3-(methylaminomethyl)benzonitrile Preparation Products And Raw materials

Raw materials

Preparation Products

More

Less

3-(methylaminomethyl)benzonitrile Suppliers

Americas 1 China 49 Europe 1 India 3 Japan 1 Ukraine 1 United Kingdom 1 United States 10 Global 67

Creasyn Finechem(Tianjin) Co., Ltd.

Tel: 022-83946278 13820503911
Fax: 022-83945176
Email: sales@creasyn.com
Country: China
ProdList: 958
Advantage: 68

Alfa Aesar

Tel: 400-6106006
Fax: 021-67582001/03/05
Email: saleschina@alfa-asia.com
Country: China
ProdList: 30123
Advantage: 84

Shandong Xiya Chemical Co., Ltd

Tel: 4009903999 13355009207
Fax: 0539-6365991
Email: 3007715519@qq.com
Country: China
ProdList: 18729
Advantage: 57

Amber MolTech LLC

Tel: 086-010-62176588
Fax: 086-010-62117849
Email: amber@jyamber.com
Country: China
ProdList: 10151
Advantage: 56

Shenyang Yuancheng Pharmaceutical Technology Co., Ltd.

Tel: 024-31298370 15040047923
Fax: 024-62665110
Email: yuanchengchem@163.com
Country: China
ProdList: 252
Advantage: 52

Shanghai Litong Chemical Technology Co.,Ltd.

Tel: 13598610367 0373-7129549
Fax: 0373-8369699
Email: 2468833170@qq.com
Country: China
ProdList: 932
Advantage: 58

TOKYO CHEMICAL INDUSTRY CO., LTD.

Tel: 03-36680489
Fax: 03-3668-0520
Email: Sales-JP@TCIchemicals.com
Country: Japan
ProdList: 28387
Advantage: 80

TCI Europe

Tel: 320-37350700
Fax: +32 (0)37350701
Email: sales@tcieurope.eu
Country: Europe
ProdList: 23671
Advantage: 75

TCI AMERICA

Tel: 800-4238616
Fax: +1-888-520-1075 / +1-503-283-1987
Email: sales@tciamerica.com
Country: Americas
ProdList: 23653
Advantage: 75

Amatek Scientific Co. Ltd.

Tel: 0512-56316828 4008675858
Fax: +86-512-56316826
Email: sales@amateksci.com
Country: China
ProdList: 9874
Advantage: 55

More

Less

View Lastest Price from 3-(methylaminomethyl)benzonitrile manufacturers

Career Henan Chemical Co

Product: 3-(methylaminomethyl)benzonitrile 90389-96-1
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 25kg
Release date: 2019-07-12

90389-96-1, 3-(methylaminomethyl)benzonitrileRelated Search:

N-METHYL-N-(4-NITROBENZYL)AMINE HYDROCHLORIDE N-Methyl-4-bromobenzylamine Hydrochloride 4-(Methylaminomethyl)benzonitrile (4-FLUORO-BENZYL)-METHYL-AMINE N-Methyl-3,4-dimethylbenzylamine 3-METHOXY-N-METHYLBENZYLAMINE 97 N-METHYL-2-NITROBENZYLAMINE CROMAKALIM Emakalim Bimakalim LEVCROMAKALIM 7-CYANO-1,2,3,4-TETRAHYDROISOQUINOLINE N-[(1-BUTYL-2-PYRROLIDINYL)METHYL]-4-CYANO-1-METHOXY-2-NAPHTHALENECARBOXAMIDE 3-[(tert-butoxycarbonyl)amino]-3-(3-cyanophenyl)propanoic acid N-[(3S,4R)-6-CYANO-3,4-DIHYDRO-3-HYDROXY-2,2-DIMETHYL-2H-1-BENZOPYRAN-4-YL]-N-(PHENYLMETHOXY)ACETAMIDE N-[(3S,4R)-6-CYANO-3,4-DIHYDRO-3-HYDROXY-2,2-DIMETHYL-2H-1-BENZOPYRAN-4-YL]-N-HYDROXYACETAMIDE Prideperone 3-CYANO-N-[3-CYANO-4-(METHYLSULFANYL)PHENYL]BENZENECARBOXAMIDE

3-(methylaminomethyl)benzonitrile

3-Cyano-N-methylbenzylamine

3-(methylaminomethyl

N-Methyl-N-(3-cyanobenzyl)aMine

Benzonitrile, 3-[(methylamino)methyl]-

3-(Methylaminomethyl)benzonitrile,95%

90389-96-1

Polyamines