ChemicalBook > CAS DataBase List > (R)-1-BOC-3-DIMETHYLAMINOPYRROLIDINE

(R)-1-BOC-3-DIMETHYLAMINOPYRROLIDINE

Product Name
(R)-1-BOC-3-DIMETHYLAMINOPYRROLIDINE
CAS No.
1004538-33-3
Chemical Name
(R)-1-BOC-3-DIMETHYLAMINOPYRROLIDINE
Synonyms
-1-Boc-3-(Dimethylamino);(R)-1-BOC-3-DIMETHYLAMINOPYRROLIDINE;Tert-butyl (R)-3-(dimethylamino)pyrrolidine-1-carboxylate;(R)-tert-butyl 3-(dimethylamino)pyrrolidine-1-carboxylate;(R)-3-DIMETHYLAMINO-PYRROLIDINE-1-CARBOXYLIC ACID TERT-BUTYL ESTER;(3R)-3-(dimethylamino)-1-pyrrolidinecarboxylic acid tert-butyl ester;(3R)-3-(Dimethylamino)-1-pyrrolidinecarboxylic acid 1,1-dimethylethyl ester;3-(Dimethylamino)-1-pyrrolidinecarboxylic acid 1,1-dimethylethyl ester, (3R)-;1-Pyrrolidinecarboxylicacid, 3-(diMethylaMino)-, 1,1-diMethylethyl ester, (3R)-
CBNumber
CB81519279
Molecular Formula
C11H22N2O2
Formula Weight
214.3
MOL File
1004538-33-3.mol
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(R)-1-BOC-3-DIMETHYLAMINOPYRROLIDINE Property

storage temp. 
2-8°C
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H227Combustible liquid

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC
Product number
B201898
Product name
(R)-1-Boc-3-(dimethylamino)pyrrolidine
Packaging
10mg
Price
$45
Updated
2021/12/16
Activate Scientific
Product number
AS113983
Product name
(R)-1-Boc-3-(Dimethylamino)pyrrolidine
Purity
97+% ee
Packaging
1g
Price
$157
Updated
2021/12/16
Activate Scientific
Product number
AS113983
Product name
(R)-1-Boc-3-(Dimethylamino)pyrrolidine
Purity
97+% ee
Packaging
250mg
Price
$265
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CCH0001340
Product name
(R)-1-BOC-3-DIMETHYLAMINOPYRROLIDINE
Purity
95.00%
Packaging
250MG
Price
$326.55
Updated
2021/12/16
AK Scientific
Product number
8044DH
Product name
(R)-1-Boc-3-(dimethylamino)pyrrolidine
Packaging
500mg
Price
$401
Updated
2021/12/16
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(R)-1-BOC-3-DIMETHYLAMINOPYRROLIDINE Chemical Properties,Usage,Production

Synthesis

1004538-32-2

1004538-33-3

Step 9-2: Preparation of (R)-1-(tert-butoxycarbonyl)-3-dimethylaminopyrrolidine. 1.25 g of (R)-1-(tert-butoxycarbonyl)-3-dimethylaminopyrrolidine hydrochloride (chemical purity: 99.9 area %) was dissolved in a mixed system of 2.46 g of 23 wt% brine, 5.03 g of toluene, and 738 mg of 30 wt% aqueous sodium hydroxide, and the reaction mixture was stirred thoroughly. After completion of the reaction, liquid-liquid separation was carried out and the organic phase was collected. The organic phase was concentrated under reduced pressure to remove the solvent, followed by vacuum drying to afford 999 mg of (R)-1-Boc-3-(dimethylamino)pyrrolidine as a colorless transparent liquid (chemical purity: 99.5 area %, 95% yield). The structure of the product was confirmed by 1H-NMR (CDCl3): δ (ppm) 1.46 (s, 9H), 1.74 (m, 1H), 2.05 (m, 1H), 2.24 (s, 6H), 2.63 (m, 1H), 3.05 (m, 1H), 3.27 (m, 1H), 3.45-3.69 (m, 2H).

References

[1] Patent: EP2050735, 2009, A1. Location in patent: Page/Page column 21-22

(R)-1-BOC-3-DIMETHYLAMINOPYRROLIDINE Preparation Products And Raw materials

Raw materials

Preparation Products

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(R)-1-BOC-3-DIMETHYLAMINOPYRROLIDINE Suppliers

J & K SCIENTIFIC LTD.
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1004538-33-3, (R)-1-BOC-3-DIMETHYLAMINOPYRROLIDINERelated Search:


  • (R)-1-BOC-3-DIMETHYLAMINOPYRROLIDINE
  • (R)-3-DIMETHYLAMINO-PYRROLIDINE-1-CARBOXYLIC ACID TERT-BUTYL ESTER
  • (R)-tert-butyl 3-(dimethylamino)pyrrolidine-1-carboxylate
  • 1-Pyrrolidinecarboxylicacid, 3-(diMethylaMino)-, 1,1-diMethylethyl ester, (3R)-
  • (3R)-3-(Dimethylamino)-1-pyrrolidinecarboxylic acid 1,1-dimethylethyl ester
  • -1-Boc-3-(Dimethylamino)
  • (3R)-3-(dimethylamino)-1-pyrrolidinecarboxylic acid tert-butyl ester
  • Tert-butyl (R)-3-(dimethylamino)pyrrolidine-1-carboxylate
  • 3-(Dimethylamino)-1-pyrrolidinecarboxylic acid 1,1-dimethylethyl ester, (3R)-
  • 1004538-33-3